CONDENSATE

BACKGROUND OF THE INVENTION

Field of the Invention

[OOOI3 The present invention relates to a system and method for determining the phase envelope of a gas condensate.

Description of Related Art

[0002] Phase behavior studies of lean gas condensates are of growing importance in petroleum reservoir analysis. The dropout of condensate near a wellborn can significantly iimit the recovery efficiency of hydrocarbons from the reservoir. Moreover, condensate yield at the surface of a well is a key parameter for determining the size of a liquid management system at the well. The dew point of a gas condensate is one of the most important thermo-physicaS properties of such fluids. However, the measurement of the dew point of a gas condensate is typically difficult to perform in conventional pressure-volume-temperature (PVT) systems. In such conventional systems, the subject fluid is injected into a pressure-balanced glass chamber. The dew point is detected by visually observing the formation of mist in the chamber as the pressure and temperature of the fluid are closely monitored. While improvements have been made to this basic PVT system, challenges stem from the difficulty in detecting and quantifying very small volumes of liquid in the gas. For example, dew point measurements become increasingly difficult as the liquid content of a gas decreases and other problems, such as liquid holdup on the chamber wails, occur. Conventional methods using PVT cells become chaiienged when measuring the dew point of fluids with less than about 1 -2 percent liquid content by volume. Furthermore, conventional techniques often suffer from poor repeatability, poor reproducibiiity, and poor accuracy. [0003] There are devices and methods for making measurements related to determining the phase envelope of a gas condensate that are we!i known in the art, however, considerable shortcomings remain,

BRIEF SUMMARY OF THE INVENTION

[0004] In one aspect, the present invention provides a system for determining the phase envelope of a gas condensate. The system comprises a microfiuidic device defining an entrance passageway, an exit passageway, and a microchannel in fluid communication with the entrance passageway and the exit passageway. The system further comprises an input sample bottle in fluid communication with the entrance of the microfiuidic device and a first pump operably associated with the input sample bottle for urging the gas condensate, disposed in the input sample bottle, into the entrance of the microfiuidic device. The system further comprises an output sample bott!e in fluid communication with the exit of the microfiuidic device and a second pump operably associated with the output sample bottle for controlling the pressure of the gas condensate, disposed in the output sample bottle, in opposition to the first pump. The first pump and the second pump are operable to provide a desired pressure drop across the microchannel of the microfiuidic device. The system yet further comprises a temperature control device to control the temperature of the gas condensate in the microchannel,

[0005] in another aspect, the present invention provides a method for determining the phase envelope of a gas condensate. The method comprises injecting a gas condensate into a microchannel of a microfiuidic device at a pressure above the expected dew point of the gas condensate and monitoring the gas condensate in the microchannel for an indication of a phase change of the gas condensate.

[0006] The present invention provides significant advantages, including (1 ) providing a way to measure the dew point of a gas condensate in much less time than required by conventional techniques; (2) providing a way to measure the dew point of a gas condensate that is much less labor intensive than by conventional techniques; and (3) providing a way to measure the dew point of a flammable gas condensate that is safer than by conventional techniques, as much less gas condensate is required.

[0007] Additional objectives, features and advantages will be apparent in the written description which follows

BRIEF DESCRIPTION OF THE DRAWINGS

[00083 The novel features characteristic of the invention are set forth in the appended claims. However, the invention itself, as well as a preferred mode of use, and further objectives and advantages thereof, will best be understood by reference to the following detailed description when read in conjunction with the accompanying drawings, in which the leftmost significant digit(s) in the reference numerals denote(s) the first figure in which the respective reference numerals appear, wherein:

[0009] Figure 1 is a graphical representation of the phase behavior of one particular, typical, gas condensate;

[0010] Figure 2 is a schematic representation of an exemplary system for detecting the phase envelope of a gas condensate;

[0011] Figure 3 is an exploded, perspective view of an illustrative embodiment of a microfiuidic device;

[0012] Figure 4 is a top, pian view of the microfiuidic device embodiment of Figure 3;

[0013] Figure 5 is a side, elevattonal view of the microfiuidic device embodiment of Figure 3;

[0014] Figure 6 is a photograph illustrating condensation phenomenon in a top, plan view of an exemplary embodiment of a microfiuidic device in use in conjunction with the present invention; [0015] Figure 7 is a graphical representation of the resuiis of a series of determinations of the dew points of a gas condensate; and

[0016] Figure 8 is a graphical representation of the results of a series of determinations of the dew points of a lean gas condensate.

[0017] While the invention is susceptible to various modifications and alternative forms, specific embodiments thereof have been shown by way of example in the drawings and are herein described in detail, it should be understood, however, that the description herein of specific embodiments is not intended to limit the invention to the particular forms disclosed, but, on the contrary, the intention is to cover all modifications, equivalents, and alternatives falling within the scope of the invention as defined by the appended claims.

DETAILED DESCRIPTION OF THE INVENTION

[0018] Illustrative embodiments of the invention are described below. In the interest of clarity, not all features of an actual implementation are described in this specification. If will, of course, be appreciated thai in the development of any such actual embodiment, numerous implementation-specific decisions must be made to achieve the developer's specific goals, such as compliance with system-related and business-related constraints, which will vary from one implementation to another. Moreover, it will be appreciated that such a development effort might be complex and time-consuming but would nevertheless b a routine undertaking for those of ordinary skill in the art having the benefit of this disclosure.

[0019] The present invention relates to a system and method for determining the phase envelope of a gas condensate. A gas condensate is injected into a microchannel. The injection pressure is above the expected dew point of the gas condensate, while the exit pressure is maintained below the expected dew point of the gas condensate. As the gas travels through the microchannel, the local pressure drops to the dew point at some location along the microchannel. Once the pressure crosses the phase boundary, a liquid phase is formed within the microchanne!. The liquid is detected as a thin, liquid fiim that is condensed on the wall of the microchanneL Although the amount of liquid is small, the change in refractive index of the wet surface is substantial While the scope of the present invention is not so limited, the dew point can be detected accurately for gas condensates as lean as, for example, less than one percent liquid by volume.

[0020] For the purposes of this disclosure, a gas condensate is defined as a low density mixture of liquid constituents that are present as gaseous components. One type of gas condensate is defined as a low density mixture of liquid hydrocarbons that are present as gaseous components in a natural gas field. Figure 1 provides a graphical representation of the phase behavior of one particular, typical, gas condensate. The fluid is in gaseous form above the solid curve and to the right of the critical point, while at least a portion of the fiuid is in liquid form once the pressure of the fluid drops below the solid curve. For example,, point 101 in Figure 1 represents the gaseous state of the fluid at a given temperature. As the pressure drops at a constant temperature along the lin 103, the fluid crosses the dew point curve, i.e., the solid curve, and a liquid phase forms. Point 105 in Figure 1 represents a two-phase state of the fluid, exhibiting between 10 and 15 percent liquid by volume. Formation of a liquid constituent within the pores of a gas field formation can severely restrict gas production flow, resulting in reservoir impairment. Accordingly, it is of prime importance to measure the dew points of reservoir gases so that gas production can be operated efficiently.

[0021] Figure 2 provides a schematic representation of an exemplary system 201 for determining the phase envelope of a gas condensate. System 201 comprises a microfluidic device 203, a temperature control device 204, a first pump 205, a second pump 207, an inlet pressure sensor 209, an outlet pressure sensor 21 1 , a camera 213, a light source 215, and a compuier 217, an input sample bottle 219, an output sample bottle 221 , a sample inlet valve 223, and a sample outlet valve 225. Note that a side, elevafsonat view of microfluidic device 203 is shown in Figure 2. In one embodiment, temperature control device 204 is a Peltier device, such as those avaiiable from Custom Thermoelectric, inc. of Btshopville, Maryland, USA. In one embodiment, first and second pumps 205 and 207 are high pressure syringe pumps, such as those available from Teiedyne Isco, Inc. of Lincoln, Nebraska, USA. In!et and outlet pressure sensors 209 and 211 are, in one embodiment, pressure sensors such as those available from Sensotreme GmbH of Ramsen, Germany. In one embodiment, camera 213 is a CCD camera, such as those available from Basler AG of Ahrensburg, Germany.

[0022] An entrance passageway 301 (shown in Figure 3) of microfluidic device 203 is in fluid communication via an inlet Sine 231 with input sample bottle 219. Fluid communication from input sample bottle 219 to microfluidic device 203 is selectively allowed by sample inlet valve 223. An exit passageway 303 (shown in Figure 3) of microfluidic device 203 is in fluid communication via an outlet line 233 with output sample bottle 221. Fluid communication from microfluidic device 203 to output sample bottle 221 is selectively allowed by sample outlet valve 225. First pump 205 pressurizes input sample bottle 219 with pressurizing fluid from first fluid reservoir 206 to provide a motive force that urges a first portion 227 of a sample fluid, disposed in input sample bottle 219, into microfluidic device 203. Second pump 207 pressurizes a second portion 229 of the sample fluid disposed in output sample bottle 221 with pressurizing fluid from second fluid reservoir 208 to control the pressure in output sample bottle 221 in opposition to a portion of the motive force provided by first pump 205. In other words, first pump 205 and second pump 207 are operated to provide desired absolute pressures and a desired pressure drop between entrance passageway 301 and exit passageway 303 (each shown in Figure 3} of microfluidic device 203. Temperature control device 204 controls the temperature of the sample fluid in microfluidic device 203.

[0023] Still referring to Figure 2, computer 217 comprises hardware and software that allows computer 217 to receive inputs, such as sensory inputs, image data, and the like; and to control various elements of system 201. Specifically, in the illustrated embodiment, computer 217 receives sensory inputs from inlet pressure sensor 209 and outlet pressure sensor 21 1 . Inlet pressure sensor 209 is in fluid communication with iniet line 231 and senses the pressure of first potion 227 of the sampie fluid in iniet Sine 231 , Outlet pressure sensor 2 1 is in fluid communication with outlet line 233 and senses the pressure of second portion 229 of the sampie fluid in outlet line 233. Based on at least the sensory inputs received from inlet pressure senso 209 and out!et pressure sensor 21 , computer 217 controis first pump 205 and second pump 207 to contro! the pressure drop between entrance passageway 301 and exit passageway 303 (each shown in Figure 3) of microfluidic device 203. Computer 217 further receives temperature inputs from temperature control device 204 and controis temperature control device 204 based on such inputs. As is discussed in greater detaii herein, light source 215 illuminates a substantially transparent, major surface of microfluidic device 203. Light reflected from the substantially transparent major surface of microfluidic device 203 is captured as an image by camera 213. The image is transmitted to computer 217, where it is analyzed.

[00243 It should be noted, however, that while the embodiment illustrated in Figure 2 is controlled by computer 217, the scope of the present invention is not so limited. Rather, elements of system 201 may be controlled by a device other than computer 217, Moreover, system 201 , in certain embodiments, may omit computer 217, whereby system 201 is manually controiled by human means.

[0025] Figures 3-5 depict views of an illustrative embodiment of microfiuidic device 203. In particular, Figure 3 depicts an exemplary stylized, exploded, perspective view of microfluidic device 203. Figure 4 depicts a top, plan view of the embodiment of microfluidic device 203 shown in Figure 2, Figure 5 depicts a side, elevational view of the embodiment of microfluidic device 203 shown in Figure 2. in the illustrated embodiment, microfluidic device 203 comprises a first substrate 305 defining a microchannef 307, an entrance well 309 and an exit well 3 1. MicroChannel 307 extends between and is in fluid communication with entrance well 309 and exit well 31 1. MicroChannel 307 forms a serpentine pattern in first substrate 305, thus allowing microchannet 307 to extend a significant length but occupy a relatively small area, in one embodiment, microchannei 307 exhibits a length of one or more meters, a width of about 100 micrometers, and a depth of about 50 micrometers, although the present invention contemplates other dimensions for microchannei 307. Microfluidic device 203 further comprises a second substrate 313 having a lower surface 317 that is bonded to an upper surface 315 of first substrate 305. When second substrate 313 is bonded to first substrate 305, microchannei 307 is sealed except for an inlet 319 at entrance well 309 and an outlet 327 at exit well 311. Second substrate 313 defines entrance passageway 301 and exit passageway 303 therethrough, which are in fluid communication with entrance well 309 and exit welt 311 , respectively, of first substrate 305.

[0026] In the embodiment depicted in Figure 3, first substrate 305 is made from silicon, glass, or sapphire, and second substrate 313 is also made from silicon, glass, such as borosiiicate glass, or sapphire, although the present invention contemplates other materials. Exemplary borosiiicate glasses are manufactured by Schott North America, inc. of Elmsford, New York, USA, and by Corning Incorporated of Corning, New York, USA. MicroChannel 307, entrance well 309, and exit well 31 1 are, in one embodiment, first patterned onto first substrat 305 using a photolithography technique and then etched into first substrate 305 using a deep reactive ion etching technique, in one embodiment, entrance passageway 301 and exit passageway 303 are generated in second substrate 313 using a water jet or abrasive drilling technique. First substrate 305 and second substrate 313 are preferably fused to one another using an anodic bonding method after careful cleaning of the bonding surfaces of substrates 305 and 313, e.g., upper surface 315 of first substrate 305 and lower surface 317 of second substrate 313. The present invention contemplates microftuidic device 203 having any suitable size and/or shape needed for a particular implementation, in one embodiment, microfluidic device 203 exhibits an overall length A of about 80 millimeters and an overall width 8 of about 15 millimeters. In such an embodiment, passageways 301 and 303 are spaced apart a distance C of about 72 millimeters. In an alternative embodiment, microfluidic device 203 may comprise a capillary tube. [00273 Referring now to Figures 2 and 3, a method of determining the phase envelope of a gas condensate comprises injecting the gas condensate into microchannet 307, via entrance passageway 301 , at a pressure higher than the dew point of the gas condensate. As the gas condensate flows through nicrochanne! 307, the pressure of the gas condensate drops below the condensation point of the gas condensate. This pressure drop results in a phase change of the gas condensate, i.e., a change from a gaseous state to a two-phase, gaseous and iiquid state, within rnicrochannel 307. The liquid portion of the gas condensate when in the two-phase state condenses on a portion of the surfaces of microfiuidic device 203 that define rnicrochannel 307. Figure 6 depicts a photograph of a portion of an exemplary microfiuidic device 203, into which a gas condensate has been injected at high pressure, as indicated by arrow 601. The gas condensate is moving in a direction generally corresponding to arrow 603, although in a serpentine fashion, through rnicrochannel 307 and the gas condensate exhibits a progressively lower pressure as it travels through rnicrochannel 307. Within a region 605, the gas condensate is at a pressure above its dew point. Within a region 607, however, the gas condensate exhibits a pressure at or below its dew point. A portion of the gas condensate is condensed on the surfaces of microfiuidic device 203 generally within region 607. MicroChannel 307 within region 607, in which some portion of the gas condensate has condensed within rnicrochannel 307, appears lighter than the appearance of rnicrochannel 307 within region 605 due to the difference in refractive indices of the gaseous gas condensate/substrate interface and the iiquid gas condensate/substrate interface. In the illustrated example, the exemplary gas condensate has a molar composition of about 82 percent C _? , about 8.95 percent 0 _4: about 5 percent n-C _S; about 1.99 percent n-Cio, and about 2.01 percent n-Cie

[00283 Referring again to Figure 2, the dew point of a fluid at a given temperature is determined by adjusting the pressures exerted onto the gas condensate by first pump 205 and second pump 207 until the gas condensate condenses within rnicrochannel 307, By reducing the pressure differential between first pump 205 and second pump 207 until condensation appears in a portion of rnicrochannel 307, the dew point of the gas condensate, i.e., the pressure at which the gas condensate condenses, can be determined for a given temperature. In one embodiment, system 201 can determine the dew point of a gas condensate within about 10 pounds per square inch. Multiple iterations can be performed to determine the dew point of the gas condensate for multiple corresponding temperatures to determine the phase envelope of the gas condensate, it should be noted that the present method may be performed in certain embodiments by system 201 controiied by computer 2 7 or the present method may be performed by human means.

[0029] Figure 7 graphically depicts the results of a series of determinations of the dew points of a gas condensate having a molar composition of about 82 percent C _{¾ s} about 8.95 percent C4 , about 5 percent n-Cs, about 1.99 percent n-C o, and about 2.01 percent n-Cie at various temperatures, in Figure 7, a comparison is made among pressure-voiume-temperature (PVT) measurements using conventional PVT cells, a conventional tuned equation of state, and microfluidic determination utilizing the system and/or method of the present invention. Excellent agreement among the determination methods is evident throughout the entire temperature range. The maximum deviation of the dew point pressure determined by the present invention from the conventional determinations in this example is about 30 pounds per square inch, which is within the accuracy of the pressure sensors, such as inlet pressure sensor 209 and outlet pressure sensor 21 1 of Figure 2, employed in the system used in the example.

[00301 Figure 8 graphically depicts the results of a plurality of determinations of the dew points of a lean gas condensate at various temperatures to illustrate the repeatability of the present microfluidic technique. A lean gas condensate is commonly characterized as a gas condensate having only a small amount of liquid dropout, generally less than about one percent by volume. Error bars are shown at each measurement point and show that the standard deviation is iess than about eight pounds per square inch in the example.

[00313 Dew point measurements using conventional determination means require about one-half day to complete for each temperature of interest. For each series of conventional determinations corresponding to those shown in Figure 7, at least about three days of testing is required.. Conversely, the time required to perform dew point measurements using the present microfiuidic technique is iess than about one-half hour. This substantia! improvement in productivity is due, at ieast in part, to the short equiiibrium time resulting from the relatively small sample volumes utilized by the present microfiuidic technique. in addition to the substantial improvement in productivity, the present microfiuidic technique is much iess labor intensive as compared to conventional techniques. Furthermore, the present microfiuidic technique provides improved safety for personnel as compared to conventional techniques when such techniques are used to make determinations of dew points of flammable gas condensates. Conventional techniques require liters of such gas condensates, white the present microfiuidic technique requires only a few milliliters of gas condensate. Finally, because of the compactness of the system of the present invention, it can readily be installed in a downhofe tool.

[0032] The particular embodiments disclosed above are illustrative only, as the invention may be modified and practiced in different but equivalent manners apparent to those skilled in the art having the benefit of the teachings herein. Furthermore, no limitations are intended to the details of construction or design herein shown, other than as described in the claims below. It is therefore evident that the particular embodiments disclosed above may be altered or modified and all such variations are considered within the scope of the invention. Accordingly, the protection sought herein is as set forth in the claims below. Although the present invention is shown in a limited number of forms, it is not limited to just these forms, but is amenable to various changes and modifications.