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Title:
THERMALLY SWITCHABLE RUTHENIUM INITIATORS
Document Type and Number:
WIPO Patent Application WO/2010/096445
Kind Code:
A3
Abstract:
This invention relates to ruthenium initiators for the ring-opening metathesis polymerization (ROMP) of cyclic olefins that are inactive at room temperature but activatable at elevated temperature (referred to as ("thermally switchable"). In general, these are compounds of ruthenium metal to which are bonded four or five ligands, in which one ligand is a pyridine ring in which the nitrogen is chelated to the ruthenium, or a five or six membered ring incorporating nitrogen and the ruthenium in which the nitrogen is chelated to the ruthenium.

Inventors:
KHOSRAVI EZAT (GB)
MUSA OSAMA M (US)
Application Number:
PCT/US2010/024423
Publication Date:
March 24, 2011
Filing Date:
February 17, 2010
Export Citation:
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Assignee:
HENKEL CORP (US)
KHOSRAVI EZAT (GB)
MUSA OSAMA M (US)
International Classes:
C07F19/00; C07F17/02; C08F4/60; C08F10/00
Domestic Patent References:
WO2005028402A22005-03-31
WO1999000397A11999-01-07
Foreign References:
US20060058476A12006-03-16
Other References:
STEFAN JUNG ET AL.: "A Series of Vinylidene-, Vinyl-, Carbene- and Carbyne ruthenium(II) Complexes with [Ru(PCy3)2] and [Ru(PiPr3)2] as Molecular Building Blocks", EUR. J. INORG. CHEM., 2004, pages 469 - 480, XP002456012
See also references of EP 2398814A4
Attorney, Agent or Firm:
GENNARO, Jane, E. (Inc.10 Finderne Avenu, Bridgewater NJ, US)
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