Title:
THERMOELECTRIC CONVERSION MATERIAL
Document Type and Number:
WIPO Patent Application WO/2017/072982
Kind Code:
A1
Abstract:
The present invention provides a thermoelectric conversion material represented by Mg3+mAaBbD2-eEe. Element A represents at least one element selected from the group consisting of Ca, Sr, Ba, and Yb. Element B represents at least one element selected from the group consisting of Mn and Zn. m is −0.39 to 0.42. The value of a is 0 to 0.12. The value of b is 0 to 0.48. Element D represents at least one element selected from the group consisting of Sb and Bi. Element E represents at least one element selected from the group consisting of Se and Te. The value of e is 0.001 to 0.06. The thermoelectric conversion material has a La2O3-type crystal structure, and the thermoelectric conversion material is of an n-type.
Inventors:
TAMAKI HIROMASA
KANNO TSUTOMU
SATO HIROKI
SAKAI AKIHIRO
TAKAHASHI KOHEI
KANNO TSUTOMU
SATO HIROKI
SAKAI AKIHIRO
TAKAHASHI KOHEI
Application Number:
PCT/JP2016/000811
Publication Date:
May 04, 2017
Filing Date:
February 17, 2016
Export Citation:
Assignee:
PANASONIC IP MAN CO LTD (JP)
International Classes:
H01L35/16; C22C12/00; C22C30/00; C22C30/06; H02N3/00
Domestic Patent References:
| WO2005114757A2 | 2005-12-01 |
Foreign References:
| US6225550B1 | 2001-05-01 | |||
| US201514847321A | 2015-09-08 | |||
| US201514847362A | 2015-09-08 | |||
| US201514718491A | 2015-05-21 |
Other References:
AHMADPOUR ET AL.: "Structural and physical properties of Mg3-xZnxSb2(x=0-1.34", JOURNAL OF SOLID STATE CHEMISTRY, vol. 180, no. 9, September 2007 (2007-09-01), pages 2420 - 2428, XP022234064
XIN ET AL.: "Electrical and thermoelectric properties of nanocrystal substitutional semiconductor alloys Mg3(BixSbl-x)2 prepared by mechanical alloying", JOURNAL OF PHYSICS D, vol. 39, no. 24, December 2006 (2006-12-01), pages 5331 - 5337, XP020094976
SHUAI ET AL.: "Thermoelectric properties of Na-doped Zintl compound: Mg3-xNaxSb2", ACTA MATERIALIA, vol. 93, July 2015 (2015-07-01), pages 187 - 193, XP055379177
V. PONNAMBALAM: "On the Thermoelectric Properties of Zintl Compounds Mg Bi Pn (Pn = P and Sb", JOURNAL OF ELECTRONIC MATERIALS, vol. 42, no. 7, 2013, pages 1307 - 1312
A. BHARDWAJ: "Mg Sb -based Zintl compound: a non-toxic, inexpensive and abundant thermoelectric material for power generation", RSC ADVANCES, vol. 3, 2013, pages 8504 - 8516
SOOHYUN KIM: "Thermoelectric properties of Mn-doped Mg-Sb single crystals", JOURNAL OF MATERIALS CHEMISTRY, vol. 2, 2014, pages 12311 - 12316
See also references of EP 3179526A4
XIN ET AL.: "Electrical and thermoelectric properties of nanocrystal substitutional semiconductor alloys Mg3(BixSbl-x)2 prepared by mechanical alloying", JOURNAL OF PHYSICS D, vol. 39, no. 24, December 2006 (2006-12-01), pages 5331 - 5337, XP020094976
SHUAI ET AL.: "Thermoelectric properties of Na-doped Zintl compound: Mg3-xNaxSb2", ACTA MATERIALIA, vol. 93, July 2015 (2015-07-01), pages 187 - 193, XP055379177
V. PONNAMBALAM: "On the Thermoelectric Properties of Zintl Compounds Mg Bi Pn (Pn = P and Sb", JOURNAL OF ELECTRONIC MATERIALS, vol. 42, no. 7, 2013, pages 1307 - 1312
A. BHARDWAJ: "Mg Sb -based Zintl compound: a non-toxic, inexpensive and abundant thermoelectric material for power generation", RSC ADVANCES, vol. 3, 2013, pages 8504 - 8516
SOOHYUN KIM: "Thermoelectric properties of Mn-doped Mg-Sb single crystals", JOURNAL OF MATERIALS CHEMISTRY, vol. 2, 2014, pages 12311 - 12316
See also references of EP 3179526A4
Attorney, Agent or Firm:
KAMATA, Kenji et al. (JP)
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