Title:
TRACERS FOR PETROLEUM RESERVOIRS
Document Type and Number:
WIPO Patent Application WO/2019/143917
Kind Code:
A3
Abstract:
The disclosure features methods of analyzing a fluid extracted from a reservoir, the methods including introducing a first composition featuring a first complexing agent into a reservoir at a first location, extracting a fluid from the reservoir at a second location different from the first location, combining the fluid with a second composition featuring a concentration of a lanthanide ion to form a third composition featuring a concentration of a complex formed by the first complexing agent and the lanthanide ion, exposing a quantity of the complex to electromagnetic radiation for a first time period ending at a time t0, detecting fluorescence emission from the quantity of the complex for a second time period starting at a time t1 > t0, where t1-t0 is greater than 2 microseconds, and determining information about a fluid flow path between the first location and the second location.
Inventors:
OW HOOISWENG (US)
SHI RENA (US)
COX JASON R (US)
CHANG SEHOON (US)
SHI RENA (US)
COX JASON R (US)
CHANG SEHOON (US)
Application Number:
PCT/US2019/014166
Publication Date:
September 26, 2019
Filing Date:
January 18, 2019
Export Citation:
Assignee:
SAUDI ARABIAN OIL CO (SA)
ARAMCO SERVICES CO (US)
ARAMCO SERVICES CO (US)
International Classes:
C09K8/03; C07D213/00; C07D471/02
Foreign References:
| US20170199124A1 | 2017-07-13 | |||
| US6691780B2 | 2004-02-17 |
Other References:
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RUI-REN TANG ET AL: "Synthesis of Novel Derivatives of Pyridine-2,6-dicarboxylic Acid", SYNTHETIC COMMUNICATIONS, vol. 36, no. 14, 1 June 2006 (2006-06-01), PHILADELPHIA, PA; US, pages 2027 - 2034, XP055574128, ISSN: 0039-7911, DOI: 10.1080/00397910600634381
AMANDA L. JENKINS ET AL: "Ultratrace Determination of Selected Lanthanides by Luminescence Enhancement", ANALYTICAL CHEMISTRY, vol. 68, no. 17, 1 January 1996 (1996-01-01), US, pages 2974 - 2980, XP055574089, ISSN: 0003-2700, DOI: 10.1021/ac9603800
MICHAEL R. GEORGE ET AL: "Modified Dipicolinic Acid Ligands for Sensitization of Europium(III) Luminescence", INORGANIC CHEMISTRY, vol. 45, no. 4, 1 February 2006 (2006-02-01), EASTON, US, pages 1739 - 1744, XP055574111, ISSN: 0020-1669, DOI: 10.1021/ic051461u
JOHN COATES ET.AL.: "Enhancement of luminescence of europium(m) ions in water by use of synergistic chelation. Part 1.1 : 1 and 2 : 1 complexes", J. CHEM. SOC., PERKIN TRANS., 1 January 1996 (1996-01-01), pages 1275 - 1282, XP055609105, Retrieved from the Internet [retrieved on 20190726]
MARK D. OGDEN ET AL: "Complexation of Am(III) and Nd(III) by 1,10-Phenanthroline-2,9-Dicarboxylic Acid", JOURNAL OF SOLUTION CHEMISTRY, vol. 42, no. 1, 27 December 2012 (2012-12-27), US, pages 211 - 225, XP055609011, ISSN: 0095-9782, DOI: 10.1007/s10953-012-9940-2
DEBASHREE MANNA ET AL: "Complexation behavior of trivalent actinides and lanthanides with 1,10-phenanthroline-2,9-dicarboxylic acid based ligands: insight from density functional theory", PHYSICAL CHEMISTRY CHEMICAL PHYSICS, vol. 14, no. 31, 1 January 2012 (2012-01-01), pages 11060, XP055609006, ISSN: 1463-9076, DOI: 10.1039/c2cp40083a
DARREN L. MELTON ET AL: "Complexes of Greatly Enhanced Thermodynamic Stability and Metal Ion Size-Based Selectivity, Formed by the Highly Preorganized Non-Macrocyclic Ligand 1,10-Phenanthroline-2,9-dicarboxylic Acid. A Thermodynamic and Crystallographic Study", INORGANIC CHEMISTRY, vol. 45, no. 23, 1 November 2006 (2006-11-01), EASTON, US, pages 9306 - 9314, XP055609003, ISSN: 0020-1669, DOI: 10.1021/ic061010p
ANDERS FOLLER LARSEN ET AL: "Efficient Synthesis of 4,7-Diamino Substituted 1,10-Phenanthroline-2,9-dicarboxamides", ORGANIC LETTERS, vol. 13, no. 13, 1 July 2011 (2011-07-01), US, pages 3546 - 3548, XP055609101, ISSN: 1523-7060, DOI: 10.1021/ol201321z
RUI-REN TANG ET AL: "Synthesis of Novel Derivatives of Pyridine-2,6-dicarboxylic Acid", SYNTHETIC COMMUNICATIONS, vol. 36, no. 14, 1 June 2006 (2006-06-01), PHILADELPHIA, PA; US, pages 2027 - 2034, XP055574128, ISSN: 0039-7911, DOI: 10.1080/00397910600634381
AMANDA L. JENKINS ET AL: "Ultratrace Determination of Selected Lanthanides by Luminescence Enhancement", ANALYTICAL CHEMISTRY, vol. 68, no. 17, 1 January 1996 (1996-01-01), US, pages 2974 - 2980, XP055574089, ISSN: 0003-2700, DOI: 10.1021/ac9603800
MICHAEL R. GEORGE ET AL: "Modified Dipicolinic Acid Ligands for Sensitization of Europium(III) Luminescence", INORGANIC CHEMISTRY, vol. 45, no. 4, 1 February 2006 (2006-02-01), EASTON, US, pages 1739 - 1744, XP055574111, ISSN: 0020-1669, DOI: 10.1021/ic051461u
JOHN COATES ET.AL.: "Enhancement of luminescence of europium(m) ions in water by use of synergistic chelation. Part 1.1 : 1 and 2 : 1 complexes", J. CHEM. SOC., PERKIN TRANS., 1 January 1996 (1996-01-01), pages 1275 - 1282, XP055609105, Retrieved from the Internet
MARK D. OGDEN ET AL: "Complexation of Am(III) and Nd(III) by 1,10-Phenanthroline-2,9-Dicarboxylic Acid", JOURNAL OF SOLUTION CHEMISTRY, vol. 42, no. 1, 27 December 2012 (2012-12-27), US, pages 211 - 225, XP055609011, ISSN: 0095-9782, DOI: 10.1007/s10953-012-9940-2
DEBASHREE MANNA ET AL: "Complexation behavior of trivalent actinides and lanthanides with 1,10-phenanthroline-2,9-dicarboxylic acid based ligands: insight from density functional theory", PHYSICAL CHEMISTRY CHEMICAL PHYSICS, vol. 14, no. 31, 1 January 2012 (2012-01-01), pages 11060, XP055609006, ISSN: 1463-9076, DOI: 10.1039/c2cp40083a
DARREN L. MELTON ET AL: "Complexes of Greatly Enhanced Thermodynamic Stability and Metal Ion Size-Based Selectivity, Formed by the Highly Preorganized Non-Macrocyclic Ligand 1,10-Phenanthroline-2,9-dicarboxylic Acid. A Thermodynamic and Crystallographic Study", INORGANIC CHEMISTRY, vol. 45, no. 23, 1 November 2006 (2006-11-01), EASTON, US, pages 9306 - 9314, XP055609003, ISSN: 0020-1669, DOI: 10.1021/ic061010p
ANDERS FOLLER LARSEN ET AL: "Efficient Synthesis of 4,7-Diamino Substituted 1,10-Phenanthroline-2,9-dicarboxamides", ORGANIC LETTERS, vol. 13, no. 13, 1 July 2011 (2011-07-01), US, pages 3546 - 3548, XP055609101, ISSN: 1523-7060, DOI: 10.1021/ol201321z
Attorney, Agent or Firm:
BRUCE, Carl E. et al. (US)
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