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Title:
TRANSITION METAL COMPLEX, PROCESS FOR THE PREPARATION THEREOF, POLYMERIZATION CATALYST FOR OLEFINS CONTAINING THE COMPLEX, AND PROCESS FOR PRODUCING OLEFIN POLYMERS
Document Type and Number:
WIPO Patent Application WO/1997/003992
Kind Code:
A1
Abstract:
A transition metal complex represented by general formula (1) (wherein M1 is a Group 4 transition metal of the periodic table; A is a Group 16 element of the periodic table; B is a Group 14 element of the periodic table; Cp1 is a group having a cyclopentadiene-type anionic skeleton; X1, X2, R1, R2, R3, R4, R5 and R6 are each independently hydrogen, halogeno, optionally halogenated C1-C20 alkyl, optionally halogenated C1-C20 substituted silyl or the like, or alternatively R1, R2, R3, R4, R5 and R6 may be united arbitrarily to form a ring); a process for the preparation thereof; an intermediate of the transition metal complex; a process for the preparation of the intermediate; a polymerization catalyst for olefins containing the transition metal complex; and a process for producing olefin polymers.

Inventors:
KATAYAMA HIROAKI (JP)
NABIKA MASAAKI (JP)
IMAI AKIO (JP)
MIYASHITA AKIRA (JP)
WATANABE TSUYOSHI (JP)
JOHOHJI HIROFUMI (JP)
ODA YOSHIAKI (JP)
HANAOKA HIDENORI (JP)
Application Number:
PCT/JP1996/001975
Publication Date:
February 06, 1997
Filing Date:
July 15, 1996
Export Citation:
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Assignee:
SUMITOMO CHEMICAL CO (JP)
KATAYAMA HIROAKI (JP)
NABIKA MASAAKI (JP)
IMAI AKIO (JP)
MIYASHITA AKIRA (JP)
WATANABE TSUYOSHI (JP)
JOHOHJI HIROFUMI (JP)
ODA YOSHIAKI (JP)
HANAOKA HIDENORI (JP)
International Classes:
B01J31/22; C07F5/00; C07F17/00; C08F4/16; C08F4/642; C08F10/00; C08F10/02; C08F4/659; C08F4/6592; C08F210/16; (IPC1-7): C07F7/28; B01J31/22; C07B61/00; C07C41/30; C07C43/215; C07F7/08; C07F7/12; C07F17/00; C08F4/642; C08F10/00
Foreign References:
JPH0680683A1994-03-22
JPH01236205A1989-09-21
JPS62106050A1987-05-16
JPS6168435A1986-04-08
Other References:
CHEMICAL ABSTRACTS, Vol. 112, No. 5, 29 January 1990 (Columbus, OH, USA), page 529, Abstract No. 35314p, LIU, YULONG et al., "Synthesis and Proton NMR Spectra of Substituted Cyclopentadienes"; & GAODENG ZUEXIAO HUAXUE XUEBAO 1989, 10(5), 546-8 (Ch).
CHEMICAL ABSTRACTS, Vol. 102, No. 3, 21 January 1985 (Columbus, OH, USA), page 703, Abstract No. 23703g, LAPKIN, I.I. et al., "Chemical Activity and Spatial Accessibility. XVII. Reaction of Arylchlorosilanes with O-Alkoxyphenylmangesium Bromides"; & ZH. OBSHCH. KHIM. 1984, 54(9), 2039-42 (Russ).
See also references of EP 0842939A4
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