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Title:
TRANSITION METAL-NITROGEN/SULFUR/SELENIUM DOPED POROUS CARBON CATALYST AND NEUTRAL ZINC-AIR BATTERY
Document Type and Number:
WIPO Patent Application WO/2023/246000
Kind Code:
A1
Abstract:
The present invention relates to a transition metal-nitrogen/sulfur/selenium doped porous carbon catalyst and a neutral zinc-air battery. In the neutral zinc-air battery, the transition metal-nitrogen/sulfur/selenium doped porous carbon catalyst is used as an air catalytic electrode, an aqueous solution containing a large-size hydrophobic anion zinc salt is used as an electrolyte, and a zinc material is used as a negative electrode. The transition metal-nitrogen/sulfur/selenium doped porous carbon catalyst comprises a transition metal element, an inorganic doping element, and a porous carbon substrate. Compared with the prior art, the present invention has excellent electronic conductivity and ionic conductivity, and can further reduce the activation energy of ORR/OER reactions, thereby improving the energy density and energy efficiency of neutral zinc-air batteries using the material as an air electrode catalyst.

Inventors:
WANG FEI (CN)
WANG FENGMEI (CN)
SUN DALIN (CN)
Application Number:
PCT/CN2022/136885
Publication Date:
December 28, 2023
Filing Date:
December 06, 2022
Export Citation:
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Assignee:
UNIV FUDAN (CN)
International Classes:
H01M12/06; H01M4/90
Foreign References:
CN115241577A2022-10-25
CN114744220A2022-07-12
CN105304913A2016-02-03
CN108554431A2018-09-21
CN114188557A2022-03-15
CN109686988A2019-04-26
CN106602092A2017-04-26
JP2018067494A2018-04-26
Other References:
SUN WEI, WANG FEI, ZHANG BAO, ZHANG MENGYI, KÜPERS VERENA, JI XIAO, THEILE CLAUDIA, BIEKER PETER, XU KANG, WANG CHUNSHENG, WINTER : "A rechargeable zinc-air battery based on zinc peroxide chemistry", SCIENCE, AMERICAN ASSOCIATION FOR THE ADVANCEMENT OF SCIENCE, US, vol. 371, no. 6524, 17 January 2024 (2024-01-17), US , pages 46 - 51, XP093120841, ISSN: 0036-8075, DOI: 10.1126/science.abb9554
ZHANG HONGWEI, ZHAO MEIQI, LIU HAORAN, SHI SHUANGRUI, WANG ZHENHUA, ZHANG BIAO, SONG LIN, SHANG JINGZHI, YANG YONG, MA CHAO, ZHENG: "Ultrastable FeCo Bifunctional Electrocatalyst on Se-Doped CNTs for Liquid and Flexible All-Solid-State Rechargeable Zn–Air Batteries", NANO LETTERS, AMERICAN CHEMICAL SOCIETY, US, vol. 21, no. 5, 10 March 2021 (2021-03-10), US , pages 2255 - 2264, XP093120842, ISSN: 1530-6984, DOI: 10.1021/acs.nanolett.1c00077
Attorney, Agent or Firm:
SHANGHAI KESHENG INTELLECTUAL PROPERTY AGENCY LTD. (CN)
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