Title:
TWO-DIMENSIONAL SUPRAMOLECULAR COMPOUND SYNTHESIZED ON THE BASIS OF 1,3,5-TRI(4-CARBONYLPHENYLOXY)BENZENE, METHOD THEREFOR, AND APPLICATION THEREOF
Document Type and Number:
WIPO Patent Application WO/2023/005143
Kind Code:
A1
Abstract:
The present invention provides a two-dimensional supramolecular compound synthesized on the basis of 1,3,5-tri(4-carbonylphenyloxy)benzene, a preparation method therefor, and an application thereof. The method comprises adding 1,3,5-tri(4-carbonylphenyloxy)benzene, phen, and Cu(NO3)2·3H2O into an aqueous solution of acetonitrile, uniformly stirring and mixing, transferring the formed mixture into a reaction kettle having a polytetrafluoroethylene lining, performing heating to 110-130°C, maintaining the temperature for 60-84 hours, and performing cooling to 20-30°C at a speed of 3-8°C/h to obtain the two-dimensional supramolecular compound. Compared with the prior art, the present invention provides a relatively simple method for synthesizing the two-dimensional supramolecular compound, and the two-dimensional supramolecular compound synthesized by the method has relatively good degradation efficiency on dyes in water; and in addition, tests show that the two-dimensional supramolecular compound synthesized by the present invention is a stable and recoverable photocatalyst.
Inventors:
JIN JUNCHENG (CN)
WU HONGMIN (CN)
JIANG PEIPEI (CN)
SUN CHUANBO (CN)
XIE CHENGGEN (CN)
LIU ZHEN (CN)
CAI XUN (CN)
WU HONGMIN (CN)
JIANG PEIPEI (CN)
SUN CHUANBO (CN)
XIE CHENGGEN (CN)
LIU ZHEN (CN)
CAI XUN (CN)
Application Number:
PCT/CN2021/142808
Publication Date:
February 02, 2023
Filing Date:
December 30, 2021
Export Citation:
Assignee:
WANXI COLLEGE (CN)
International Classes:
B01J31/22; C07F1/08; B01J35/00; C02F1/30; C02F101/30; C08G83/00
Foreign References:
CN113583029A | 2021-11-02 | |||
CN110628037A | 2019-12-31 | |||
CN103990493A | 2014-08-20 | |||
CN106749349A | 2017-05-31 | |||
CN103739632A | 2014-04-23 |
Other References:
GU JIN-ZHONG, LIANG XIAO-XIAO, CUI YAN-HUI, WU JIANG, SHI ZI-FA, KIRILLOV ALEXANDER M.: "Introducing 2-(2-carboxyphenoxy)terephthalic acid as a new versatile building block for design of diverse coordination polymers: synthesis, structural features, luminescence sensing, and magnetism", CRYSTENGCOMM, vol. 19, no. 18, 1 January 2017 (2017-01-01), pages 2570 - 2588, XP093030455, DOI: 10.1039/C7CE00219J
ZHANG JIE, HUO LIANGQIN, WANG XIAOQING, FANG KEGONG, FAN LIMING, HU TUOPING: "Structural Diversity, Magnetic Properties, and Luminescent Sensing of the Flexible Tripodal Ligand of 1,3,5-Tris(4-carbonylphenyloxy)benzene Based Mn(II)/Cd(II) Coordination Polymers", CRYSTAL GROWTH & DESIGN, ASC WASHINGTON DC, US, vol. 17, no. 11, 1 November 2017 (2017-11-01), US , pages 5887 - 5897, XP093030459, ISSN: 1528-7483, DOI: 10.1021/acs.cgd.7b00986
ZHANG JIE, HUO LIANGQIN, WANG XIAOQING, FANG KEGONG, FAN LIMING, HU TUOPING: "Structural Diversity, Magnetic Properties, and Luminescent Sensing of the Flexible Tripodal Ligand of 1,3,5-Tris(4-carbonylphenyloxy)benzene Based Mn(II)/Cd(II) Coordination Polymers", CRYSTAL GROWTH & DESIGN, ASC WASHINGTON DC, US, vol. 17, no. 11, 1 November 2017 (2017-11-01), US , pages 5887 - 5897, XP093030459, ISSN: 1528-7483, DOI: 10.1021/acs.cgd.7b00986
Attorney, Agent or Firm:
HEFEI ZHONG BO ZHIXIN INTELLECTUAL PROPERTY AGENCY CO., LTD. (CN)
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