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Title:
beta-Ga2O3 SINGLE CRYSTAL GROWING METHOD, THIN-FILM SINGLE CRYSTAL GROWING METHOD, Ga2O3 LIGHT-EMITTING DEVICE, AND ITS MANUFACTURING METHOD
Document Type and Number:
WIPO Patent Application WO2004074556
Kind Code:
A3
Abstract:
A method for growing a beta-Ga2O3 single crystal hardly cracking and having a weakened twinning tendency and an improved crystallinity, a method for growing a thin-film single crystal with high quality, a Ga2O3 light-emitting device capable of emitting light in the ultraviolet region, and its manufacturing method are disclosed. In an infrared-heating single crystal manufacturing system, a seed crystal and a polycrystalline material are rotated in mutually opposite directions and heated, and a beta-Ga2O3 single crystal is grown in one direction selected from among the a-axis <100> direction, the b-axis <010> direction, and c-axis <001> direction. A thin film of a beta-Ga2O3 single crystal is formed by PLD. A laser beam is applied to a target to excite atoms constituting the target. Ga atoms are released from the target by a thermal and photochemical action. The free Ga atoms are bonded to radicals in the atmosphere in the chamber. Thus, a thin-film of a beta-Ga2O3 single crystal is grown on a substrate of a beta-Ga2O3 single crystal. A light-emitting device comprises an n-type substrate produced by doping a beta-Ga2O3 single crystal with an n-type dopant and a p-type layer produced by doping the beta-Ga2O3 single crystal with a p-type dopant and junctioned to the top of the n-type substrate. The light-emitting device emits light from the junction portion.

Inventors:
ICHINOSE NOBORU (JP)
SHIMAMURA KIYOSHI (JP)
AOKI KAZUO (JP)
GARCIA VILLORA ENCARNACION ANT (JP)
Application Number:
PCT/JP2004/001653
Publication Date:
November 11, 2004
Filing Date:
February 16, 2004
Export Citation:
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Assignee:
UNIV WASEDA (JP)
ICHINOSE NOBORU (JP)
SHIMAMURA KIYOSHI (JP)
AOKI KAZUO (JP)
GARCIA VILLORA ENCARNACION ANT (JP)
International Classes:
C30B23/02; H01L33/02; H01L33/26; (IPC1-7): C30B29/16; C30B13/34; H01L33/00; H01S5/323
Domestic Patent References:
WO2002089223A12002-11-07
Foreign References:
JP2002068889A2002-03-08
Other References:
VILLORA E.G. ET AL: "Cathodoluminescence of undoped Beta-Ga2O3 single crystals", SOLID STATE COMMUNICATIONS, vol. 120, 2001, pages 455 - 458, XP002981301
DINESCU M. ET AL: "ZnO thin film deposition by laser ablation of Zn target in oxygen reactive atmosphere", APPLIED SURFACE SCIENCE, vol. 106, 1996, pages 149 - 153, XP000856181
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