Title:

**【発明の名称】不均一触媒成分及びα-オレフィンの重合方法**

Document Type and Number:

Japanese Patent JP3382882

Kind Code:

B2

Abstract:

Heterogeneous catalytic component obtainable by reacting a porous inorganic support with a metallocene compound characterized in that the metallocene compound is defined by the following general formulas: wherein: L, equal to or different from each other, is selected from the group comprising: cyclopentadienyl, indenyl, tetrahydroindenyl, fluorenyl, octahydrofluorenyl or benzoindenyl; each R is independently selected from hydrogen, C1-C20 alkyl, C3-C20 cycloalkyl, C6-C20 aryl, C3-C20 alkenyl, C7-C20 arylalkyl, C7-C20 alkylaryl, C8-20 arylalkenyl, linear or branched, optionally substituted by 1 to 10 halogen atoms, or a group SiR3; each R

*equal to or different from each other is a divalent aliphatic or aromatic hydrocarbon group containing from 1 to 20 carbon atoms, optionally containing from 1 to 5 heteroatoms of groups 14 to 16 of the periodic table of the elements and boron; each Q is independently selected from B, C, Si, Ge, Sn; M is a metal of group 3, 4 or 10 of the Periodic Table, Lanthanide or Actinide; each X is independently selected from: hydrogen, chlorine, bromine, OR*, NR2, C1-C20 alkyl or C6-C20 aryl; each Ris independently selected from C1-C20 alkyl , C3-C20 cycloalkyl, C6-C20 aryl, C3-C20 alkenyl C7-C20 arylalkyl, C7-C20 arylalkenyl or alkylaryl, linear or branched; Ris methyl, ethyl isopropyl; L' is N or O; when L is cyclopentadienyl k is equal to 5, when L is indenyl k is equal to 7, when L is fluorenyl or benzoindenyl k is equal to 9, when L is tetrahydroindenyl k is equal to 11 and when L is octahydrofluorenyl, k is equal to 17; z is equal to 0, 1 or 2; x is equal to 1, 2 or 3; y is equal to 1, 2 or 3; x+y+z is equal to the valence of M; m is an integer which can assume the values 1, 2, 3 or 4; a and b are integers whose value ranges from 0 to k-1; f is an integer whose value ranges from 1 to k; g is 0 or 1; c and e are equal to 0 or 1; a+b+c is at least 1; a+g+c is at least 1; d is equal to 0, 1 or 2; when Q is B, then c+d=1; when Q is C, Si, Ge or Sn, then c+d=2; when L' is N, then g+e=1; when L' is O, then g=0 and e=0.

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Inventors:

The Herald Hidalgo Linus

Antonio Munos-Escalona La Fuente

Antonio Munos-Escalona La Fuente

Application Number:

JP12513699A

Publication Date:

March 04, 2003

Filing Date:

April 30, 1999

Export Citation:

Assignee:

Repsol, Chemica, Sociedad, Anonima

International Classes:

*;*

**C08F2/02***;*

**C08F2/04***;*

**C08F2/18***;*

**C08F2/34***;*

**C08F4/64***;*

**C08F4/65***;*

**C08F4/6592***;*

**C08F10/00***C08F4/619*;

*C08F4/6192*;

*C08F10/02*;

*C08F110/02*;

*C08F210/16*; (IPC1-7): C08F4/65; C08F2/02; C08F2/04; C08F2/18; C08F2/34; C08F10/00

Domestic Patent References:

JP10226709A | ||||

JP2000136209A | ||||

JP20007692A |

Attorney, Agent or Firm:

Shigeru Yagita (2 outside)