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Title:
4-HALOGENOBENZYL 4'-(TRANS-4"-ALKYLCYCLOHEXYL)PHENYL ESTER
Document Type and Number:
Japanese Patent JPS5731631
Kind Code:
A
Abstract:

NEW MATERIAL:The compound of formula I (R is 1W10C alkyl; X is F or Cl).

EXAMPLE: 4-Fluorobenzyl 4'-(trans-4"-propylcyclohexyl)phenyl ether.

USE: A liquid crystal compound. Since the compound has a dielectric anisotropy (Δ) of about +0.5, it can be used for suppressing the Δ of a liquid crystal composition as a whole. There is no increase of the threshold voltage and saturation voltage, and the power consumption of the display element can be minimized. The N-I point of the composition can also be improved.

PROCESS: The compound of formula I can be prepared by (1) reducing 4'-alkyl-1'- cyclohexen-1'-yl-4-methoxybenzene in ethanol in the presence of a Pd/C catalyst under atmospheric pressure at 50°C, (2) reacting the product with boron tribromide to eliminate the methoxy group to obtain the compound of formula II, and (3) reacting the compound of formula II with 4-halogeno-benzyl chloride in acetone in the presence of anhydrous potassium carbonate.


Inventors:
SUGIMORI SHIGERU
Application Number:
JP10700480A
Publication Date:
February 20, 1982
Filing Date:
August 04, 1980
Export Citation:
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Assignee:
CHISSO CORP
International Classes:
C07C43/225; C07C41/00; C07C67/00; C09K19/30; (IPC1-7): C07C43/225; C09K3/34