Title:
OXIDATION OF ALKANE
Document Type and Number:
Japanese Patent JP3208852
Kind Code:
B2
Abstract:
PURPOSE: To obtain an alcohol or a ketone under mild condition at a low cost by oxidizing the corresponding alkane with oxygen in the presence of a transition metal catalyst and an aldehyde.
CONSTITUTION: A 1-20C straight, branched or cyclic alkane is made to react with oxygen in the presence or absence of a proton source (preferably acetic acid or benzoic acid) and in the presence of a transition metal catalyst selected from chromium, manganese, iron, cobalt, nickel, copper, ruthenium and osmium- based catalysts, preferably iron-based catalyst or copper-based catalyst causing little environmental pollution and an aldehyde (preferably acetaldehyde, propionaldehyde, butanal or heptanal) to obtain an alcohol or ketone corresponding to the alkane.
Inventors:
Shunichi Murahashi
Yoshiaki Oda
Yoshiaki Oda
Application Number:
JP20887892A
Publication Date:
September 17, 2001
Filing Date:
August 05, 1992
Export Citation:
Assignee:
Sumitomo Chemical Co., Ltd.
International Classes:
B01J23/26; B01J23/34; B01J23/46; B01J23/72; B01J23/74; B01J31/04; B01J31/22; C07B33/00; C07B41/02; C07B41/06; C07B61/00; C07C27/12; C07C29/50; C07C35/37; C07C45/27; (IPC1-7): C07B41/02; B01J23/26; B01J23/34; B01J23/46; B01J23/72; B01J23/74; B01J31/04; B01J31/22; C07B33/00; C07B41/06; C07C27/12; C07C29/50; C07C35/37; C07C45/27
Domestic Patent References:
| JP6045538A |
Attorney, Agent or Firm:
Takashi Kuboyama (1 person outside)
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