Title:
PRODUCTION OF ESTER
Document Type and Number:
Japanese Patent JP3489592
Kind Code:
B2
Abstract:
PURPOSE: To provide a process for producing an ester capable of obtaining in high yield by reacting an olefin with carbon monoxide and an alcohol at a low temperature for a short time and recovering hydrogen fluoride working as a catalyst to recycle.
CONSTITUTION: An acyl fluoride is synthesized by reacting an olefin with carbon monoxide in the presence of hydrogen fluoride and the obtained acyl fluoride is made to react with an alcohol. The obtained reaction solution of esterification is distilled under recycling an inactive saturated hydrocarbon having a higher boiling point than the acyl fluoride to recover hydrogen fluoride which is recycled to the reaction.
Inventors:
Yoshihiro Shiokawa
Haruichi Matsumoto
Haruichi Matsumoto
Application Number:
JP3024394A
Publication Date:
January 19, 2004
Filing Date:
February 28, 1994
Export Citation:
Assignee:
Mitsubishi Gas Chemical Co., Ltd.
International Classes:
B01J27/12; C07B41/12; C07B61/00; C07C51/58; C07C53/42; C07C67/14; C07C67/38; C07C69/24; C07C69/28; (IPC1-7): C07C67/14; C07C69/24; C07C69/28
Domestic Patent References:
JP5810538A | ||||
JP5896039A | ||||
JP7224001A | ||||
JP6176435A | ||||
JP60224653A | ||||
JP4635722A |