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Title:
PRODUCTION OF POLYESTER
Document Type and Number:
Japanese Patent JPH1129632
Kind Code:
A
Abstract:

To produce a polyester excellent in transparency and color tone by a method using antimony trioxide as a polycondensation catalyst and simultaneously using a phosphorous compound.

Polyethylene terephthalate or a polyester consisting mainly of the polyethylene terephthalate is produced. Therein, the polycondensation reaction is carried out by adding antimony trioxide in an amount of 1×10-4 to 4×10-4 mole/mole of an acid component to the polyester oligomer and further adding the below-described phosphorous compound solution in an amount of ≥0.5 fold-mole that of the antimony trioxide to the polyester oligomer. The phosphorous compound solution has a water fraction of ≤1000 ppm and is obtained by dissolving phosphoric acid in a 2-10C alkylene glycol so as to give a concentration of 1-10 wt.%, and subsequently subjecting the solution to a reaction at a temperature of 150-200°C, until at least the reaction solution does not exhibit the second equivalent point on a potentiometric titration, while by-produced water is distilled out.


Inventors:
TANEDA YUJI
KINUGAWA MASAYUKI
Application Number:
JP18480297A
Publication Date:
February 02, 1999
Filing Date:
July 10, 1997
Export Citation:
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Assignee:
NIPPON ESTER CO LTD
International Classes:
B29D22/00; C08G63/80; C08G63/86; B29K67/00; (IPC1-7): C08G63/86; B29D22/00; C08G63/80



 
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