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Title:
PROPYLENE-BASED RANDAM COPOLYEMER AND ITS PRODUCTION
Document Type and Number:
Japanese Patent JPH0952909
Kind Code:
A
Abstract:

To obtain the subject copolymer hardly having a content soluble in toluene at a low temperature and catalyst residue remaining in the polymer, having wide molecular weight distribution and useful as a material for various kinds of stretched films by carrying out random copolymerization of propylene with ethylene in the presence of a catalyst comprising a solid titanium com pound, etc.

This copolymer has 0.1-30g/10min melt flow rate and is composed of 0.1-15mol% monomer unit based on ethylene and 85-99. 9% monomer unit based on propylene and has a relationship between monomer unit E based on ethylene and a content S (wt.%) soluble in toluene at a low temperature satisfying the formula S≤0.37×E+1.5 and has a ratio of weight average molecular weight to number average molecular weight measured by gel permeation chromatography of ≥6, ≤3ppm titanium atom and ≤30ppm chlorine atom. The copolymer is obtained by carrying out random copolymerization of propylene with ethylene in the presence of a solid catalyst comprising (A) a solid titanium compound consisting essentially of Mg, Ti and a halogen, (B) an organoaluminium compound and (C) dicyclopentyldimethoxysilane.


Inventors:
KAMINAKA MANABU
KITAJIMA YOSHIYUKI
ITO JUNICHI
Application Number:
JP20363695A
Publication Date:
February 25, 1997
Filing Date:
August 09, 1995
Export Citation:
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Assignee:
TOKUYAMA CORP
International Classes:
C08J5/18; C08F4/60; C08F4/654; C08F210/16; (IPC1-7): C08F4/654; C08F210/16; C08J5/18



 
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