Title:
飽和アルコール、ケトン、アルデヒド及びカルボン酸の製造法
Document Type and Number:
Japanese Patent JP2004533477
Kind Code:
A
Abstract:
The invention relates to a method for catalytically oxidizing unsaturated hydrocarbons to form oxidation products, and to the production of saturated alcohols, ketones, aldehydes or carboxylic acids by subsequently hydrogenating the oxidation product. A compound of formula (I) is used as a catalyst during oxidizing in which: R1, R2=H, an aliphatic or aromatic alkoxy radical, carboxyl radical, alkoxycarbonyl radical or hydrocarbon radical, each having 1 to 20 carbon atoms, SO3H, NH2, OH, F, Cl, Br, I and/or NO2, whereby R1 and R2 signify identical or different radicals or R1 and R2 can be coupled to one another via a covalent bond, with Q1, Q2=the same or different, C, CH, N; X, Z=C, S or CH2; Y=O or OH; k=0, 1 or 2; 1=0, 1 or 2; m=1 to 100 in the presence of a radical initiator. Peroxy compounds or azo compounds can be used as radical initiators. Preferred substrates are cyclic aliphatic or aromatic compounds.
Inventors:
Adolf Künle
Karlsten Yost
Roger Arthur Sheldon
Sandrine M M Chatel
Isabella Wee Tse Alenz
Karlsten Yost
Roger Arthur Sheldon
Sandrine M M Chatel
Isabella Wee Tse Alenz
Application Number:
JP2003510415A
Publication Date:
November 04, 2004
Filing Date:
June 12, 2002
Export Citation:
Assignee:
Degussa AG
International Classes:
C07B41/00; C07B61/00; C07C29/17; C07C29/50; C07C31/02; C07C31/133; C07C45/34; C07C47/02; C07C47/28; C07C49/04; C07C49/29; C07C51/25; C07C53/00; C07C53/134; (IPC1-7): C07C29/50; C07C31/02; C07C31/133; C07C45/34; C07C47/02; C07C47/28; C07C49/04; C07C49/29; C07C51/25; C07C53/00; C07C53/134
Attorney, Agent or Firm:
Toshio Yano
Toshiomi Yamazaki
Takuya Kuno
Einzel Felix-Reinhard
Reinhard Einsel
Toshiomi Yamazaki
Takuya Kuno
Einzel Felix-Reinhard
Reinhard Einsel