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Patent Searching and Data


Title:
SILICONE-BASED CINNAMIC ACID DERIVATIVE, PRODUCTION THEREOF AND ULTRAVIOLET LIGHT ABSORBER
Document Type and Number:
Japanese Patent JPH02167291
Kind Code:
A
Abstract:

NEW MATERIAL:A compound which is a siloxane having a unit shown by formula I [R1 is 1-4C alkyl, phenyl or trimethylsiloxy; R2 is bifunctional hydro carbon (hydrocarbon containing plural oxygen atoms is included) containing at least two carbons; X is alkoxy; n is 0-3; a is 2 or 3; R3 is 1-4C alkyl, phenyl or trimethylsiloxy; m is 0-3] and has another unit shown by formula II existing in the siloxane.

EXAMPLE: [3-Bis(trimethylsiloxy)methylsilyl-1-methylpropyl]-3,4,5-trimethoxy cinnamate shown by formula III.

USE: An ultraviolet light absorber soluble in silicone oil, having excellent water resistance and oil resistance.

PREPARATION: A cinnamic ester shown by formula IV [Y is monofunctional hydrocarbon containing at least two carbons and olefinic unsaturated bond (hydrocarbon containing plural oxygen atoms is included)] is reacted with a siloxane containing units shown by formula V and VI in an organic solvent in the presence of a flux.


Inventors:
YOSHIDA MASASHI
NANBA TOMIYUKI
UEHARA KEIICHI
Application Number:
JP17479989A
Publication Date:
June 27, 1990
Filing Date:
July 06, 1989
Export Citation:
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Assignee:
SHISEIDO CO LTD
International Classes:
C09K3/00; C07F7/18; (IPC1-7): C07F7/18
Attorney, Agent or Firm:
Yuji Iwahashi