Title:
【発明の名称】ヘテロ原子機能化ポルフィラジンおよびそらから誘導された多金属錯体およびポリマー
Document Type and Number:
Japanese Patent JPH10500706
Kind Code:
A
Abstract:
Porphyrazine compounds having moieties substituted at the eight peripheral beta -pyrrole positions are disclosed. The porphyrazine compounds have the general structural formula: wherein M is H2 or a metal capable of complexing with the pyrrole nitrogen atoms, and A, B, C and D are independently selected from the group consisting of a thio moiety, an amino moiety, an oxo moiety, a phospho moiety, a seleno moiety, a telluro moiety and a non-coordinating moiety, like a hydrocarbon moiety, with the proviso that not all of A, B, C and D are a thio moiety and that not all of A, B, C, and D are a hydrocarbon moiety. The porphyrazine compounds, depending on the identity of A, B, C and D, are capable of complexing one to four metal ions to the periphery of the porphyrazine to form a multimetallic porphyrazine. Multimetallic porphyrazine compounds can be linked by the peripherally-complexed metal ions to form a linear, i.e., ribbon, polymer or a two-dimension, i.e., sheet polymer. The porphyrazine compounds, and the multimetallic complexes and polymers derived therefrom, are useful in, or as, magnet materials, molecular metal conductors, pharmaceuticals, imaging agents, and dyes.
Inventors:
Hoffman, Brian, M.
Burlet, Anthony, G., M.
Burlet, Anthony, G., M.
Application Number:
JP52783796A
Publication Date:
January 20, 1998
Filing Date:
March 11, 1996
Export Citation:
Assignee:
Hoffman/Barrett, Limited Liability Company
International Classes:
C07D487/22; C07D491/22; C07D495/22; C07D497/22; C07D498/22; C07F1/00; C07F1/08; C07F3/00; C07F5/00; C07F5/06; C07F7/22; C07F7/24; C07F7/30; C07F9/6561; C07F9/6564; C07F15/00; C07F15/04; (IPC1-7): C07D487/22; C07D491/22; C07D495/22; C07D497/22; C07D498/22; C07F1/00; C07F1/08; C07F3/00; C07F5/00; C07F5/06; C07F7/22; C07F7/24; C07F7/30; C07F9/6564; C07F15/00; C07F15/04
Attorney, Agent or Firm:
Yoshihiro Tsunoda