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Title:
APPARATUS AND METHOD FOR TUNING A PLASMA PROFILE USING A TUNING ELECTRODE IN A PROCESSING CHAMBER
Document Type and Number:
WIPO Patent Application WO/2014/149258
Kind Code:
A1
Abstract:
Embodiments of the present invention relate to apparatus for enhancing deposition rate and improving a plasma profile during plasma processing of a substrate. According to embodiments, the apparatus includes a tuning electrode disposed in a substrate support pedestal and electrically coupled to a variable capacitor. The capacitance is controlled to control the RF and resulting plasma coupling to the tuning electrode. The plasma profile and the resulting deposition rate and deposited film thickness across the substrate are correspondingly controlled by adjusting the capacitance and impedance at the tuning electrode.

Inventors:
AYOUB MOHAMAD A (US)
CHEN JIAN J (US)
BANSAL AMIT KUMAR (US)
Application Number:
PCT/US2014/016098
Publication Date:
September 25, 2014
Filing Date:
February 12, 2014
Export Citation:
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Assignee:
APPLIED MATERIALS INC (US)
International Classes:
H01L21/205
Foreign References:
US20100213047A12010-08-26
US7004107B12006-02-28
JP2004193567A2004-07-08
US20100018648A12010-01-28
US20070006972A12007-01-11
Attorney, Agent or Firm:
PATTERSON, Todd, B. et al. (LLP24 Greenway Plaza, Suite 160, Houston TX, US)
Download PDF:
Claims:
Claims:

1 . A plasma processing apparatus, comprising:

a chamber body and a powered gas distribution manifold enclosing a process volume;

a pedestal disposed in the process volume for supporting a substrate; and a tuning electrode disposed within the pedestal and electrically coupled to a variable capacitor.

2. The plasma processing apparatus of claim 1 , wherein the variable capacitor is coupled to a sensor and a controller configured to control the capacitance of the variable capacitor.

3. The plasma processing apparatus of claim 1 , wherein the variable capacitor is coupled to a sensor and a controller configured to control the current flowing through the variable capacitor.

4. The plasma processing apparatus of claim 1 , wherein the tuning electrode comprises a conductive mesh.

5. The plasma processing apparatus of claim 1 , wherein the variable capacitor is a variable vacuum capacitor.

6. A method for processing a substrate, comprising:

powering a gas distribution manifold using an RF source while flowing one or more process gases into a plasma chamber to form a plasma within a process volume of the chamber; and

controlling the plasma by varying a capacitance of a tuning electrode disposed within a substrate support pedestal within a chamber body of the chamber.

7. The method of claim 6, further comprising controlling an impedance to the tuning electrode by varying the capacitance of the tuning electrode.

8. The method of claim 7, further comprising tuning the impedance to the tuning electrode to a minimum value by varying the capacitance of the tuning electrode.

9. The method of claim 6, further comprising controlling a current to the tuning electrode by varying the capacitance of the tuning electrode.

10. The method of claim 9, further comprising tuning the current to the tuning electrode to a maximum value by varying the capacitance of the tuning electrode.

1 1 . The method of claim 6, further comprising decreasing the plasma density at the edge of the substrate by increasing the capacitance of the tuning electrode.

12. A substrate support assembly for use in a plasma processing apparatus, comprising:

a substrate support pedestal;

a tuning electrode disposed within the substrate support pedestal; and a variable capacitor electrically coupled to the tuning electrode.

13. The substrate support assembly of claim 12, further comprising a sensor coupled to the tuning electrode.

14. The substrate support assembly of claim 12, wherein the tuning electrode comprises a conductive mesh.

Description:
APPARATUS AND METHOD FOR TUNING A PLASMA PROFILE USING A TUNING ELECTRODE IN A PROCESSING CHAMBER

BACKGROUND OF THE INVENTION

Field of the Invention

[0001] Embodiments of the present invention generally relate to an apparatus and method for processing substrates. More particularly, embodiments of the present invention relate to a plasma processing chamber with a tuning electrode disposed in a substrate support pedestal for enhanced processing rate and improved center to edge plasma profile uniformity.

Description of the Related Art

[0002] Plasma processing, such as plasma enhanced chemical vapor deposition (PECVD), is used to deposit materials, such as blanket dielectric films on substrates, such as semiconductor wafers. A challenge for current plasma processing chambers and processes includes controlling critical dimension uniformity during plasma deposition processes. A particular challenge includes substrate center to edge thickness uniformity in films deposited using current plasma processing chambers and techniques.

[0003] Accordingly, it is desirable to develop an apparatus and process for enhancing deposition rate and improving the center to edge thickness uniformity of films deposited during plasma processing.

SUMMARY OF THE INVENTION

[0004] In one embodiment of the present invention, a plasma processing apparatus comprises a chamber body and a powered gas distribution manifold enclosing a process volume, a pedestal disposed in the process volume for supporting a substrate, and a tuning electrode disposed within the pedestal and electrically coupled to a variable capacitor. [0005] In another embodiment, a method for processing a substrate comprises powering a gas distribution manifold using an RF source while flowing one or more process gases into a plasma chamber to form a plasma within a process volume of the chamber and controlling the plasma by varying a capacitance of a tuning electrode disposed within a substrate support pedestal within a chamber body of the chamber.

[0006] In yet another embodiment, a substrate support assembly for use in a plasma processing apparatus comprises a substrate support pedestal, a tuning electrode disposed within the substrate support pedestal, and a variable capacitor electrically coupled to the tuning electrode.

BRIEF DESCRIPTION OF THE DRAWINGS

[0007] So that the manner in which the above recited features of the present invention can be understood in detail, a more particular description of the invention, briefly summarized above, may be had by reference to embodiments, some of which are illustrated in the appended drawings. It is to be noted, however, that the appended drawings illustrate only typical embodiments of this invention and are therefore not to be considered limiting of its scope, for the invention may admit to other equally effective embodiments.

[0008] Figure 1 is a schematic, cross-sectional view of a plasma processing apparatus according to one embodiment of the present invention.

[0009] Figure 2 is an exemplary depiction of the total current and the total impedance of the tuning electrode of Figure 1 , plotted as a function of the percentage of capacitance of the total capacitance at the variable capacitor.

[0010] Figures 3A-3C are exemplary depictions of the electric field magnitude distribution across the substrate and the pedestal according to varying capacitances applied to the tuning electrode in the chamber of Figure 1 . [0011] Figures 4A-4D are exemplary depictions of the resulting film thickness distribution across the substrate, processed in the chamber in Figure 1 , using varying capacitances applied to the tuning electrode during plasma deposition processing.

DETAILED DESCRIPTION

[0012] Embodiments of the present invention relate to apparatus for enhancing deposition rate and improving a plasma profile during plasma processing of a substrate. According to embodiments, the apparatus includes a tuning electrode disposed in a substrate support pedestal and electrically coupled to a variable capacitor. The capacitance is controlled to control the RF and resulting plasma coupling to the tuning electrode. The plasma profile and the resulting deposition film thickness across the substrate are correspondingly controlled by adjusting the capacitance and impedance at the tuning electrode.

[0013] Figure 1 is a schematic, cross-sectional view of a plasma processing apparatus according to one embodiment of the present invention. The apparatus includes a chamber 100 in which one or more films may be deposited on a substrate 1 10. The chamber includes a chamber body 102 and a gas distribution assembly 104, which distributes gases uniformly a process volume 106. A pedestal 108 is disposed within the process volume and supports the substrate 1 10. The pedestal 108 includes a heating element (not shown). The pedestal 108 is movably disposed in the process volume by a stem 1 14 that extends through the chamber body 102, where it is connected to a drive system 103 for raising, lowering, and/or rotating the pedestal 108.

[0014] The gas distribution assembly 104 includes a gas inlet passage 1 16, which delivers gas from a gas flow controller 120 into a gas distribution manifold 1 18. The gas distribution manifold 1 18 includes a plurality of nozzles (not shown) through which gaseous mixtures are injected during processing. [0015] An RF (radio frequency) power source 126 provides electromagnetic energy to power the gas distribution manifold 1 18, which acts as a powered electrode, to facilitate generation of a plasma between the gas distribution manifold 1 18 and the pedestal 108. The pedestal 108 includes a tuning electrode 1 12, which is electrically grounded through an RF rod 122 such that an electric field is generated in the chamber 100 between the powered gas distribution manifold 1 18 and the tuning electrode 1 12. In one embodiment, the tuning electrode 1 12 comprises a conductive mesh, such as an aluminum or molybdenum mesh.

[0016] The tuning electrode 1 12 is electrically coupled to a variable capacitor 128, such as a variable vacuum capacitor, and terminated to ground through an inductor L1 . A second inductor L2 is electrically coupled in parallel to the variable capacitor 128 to provide a path for low frequency RF to ground. In addition, a sensor 130, such as a VI sensor, is positioned between the tuning electrode 1 12 and the variable capacitor 128 for use in controlling the current flow through the tuning electrode 1 12 and the variable capacitor 128. A system controller 134 controls the functions of the various components, such as the RF power source 126, the drive system 103, and the variable capacitor 128. The system controller 134 executes system control software stored in a memory 138.

[0017] Thus, an RF path is established between the powered gas distribution manifold 1 18 and the tuning electrode 1 12 via plasma. Further, by changing the capacitance of the variable capacitor 128, the impedance for the RF path through the tuning electrode 1 12 changes, in turn, causing a change in the RF field coupled to the tuning electrode 1 12. Therefore, the plasma in the process volume 106 may be modulated across the surface of the substrate 1 10 during plasma processing.

[0018] Figure 2 is an exemplary depiction of the total current 210 and the total impedance 220, of the tuning electrode 1 12 of Figure 1 , plotted as a function of the percentage of capacitance of the total capacitance at the variable capacitor 128. As can be seen in this example, the maximum current 212 and corresponding minimum impedance 222 of the tuning electrode 1 12 (i.e., resonance) is achieved at between about 40% and 50% of the total capacitance of the variable capacitor 128. This is due to the resonance of a series LC circuit formed by the inductive RF rod 122, the inductor L1 , and the capacitor 128. By tuning the capacitor 128 to the resonance, the inductive impedance of the RF rod 122 can be canceled, and the overall impedance for this RF return path (i.e., from the top surface of the pedestal 108, through the tuning electrode 1 12, and through the RF rod 122) is minimized, resulting in the maximum possible current flowing through the tuning electrode 1 12, and thereby enhancing deposition rate. At lower and higher percentages of the total capacitance of the variable capacitor 128, the total current 210 decreases, while the corresponding total impedance 220 increases. Accordingly, a desired current and total impedance of the tuning electrode 1 12 can be modulated by controlling the total capacitance at the variable capacitor 128.

[0019] Figures 3A-3C are exemplary depictions of the electric field magnitude distribution across the substrate 1 10 and the pedestal 108 according to varying capacitances applied to the tuning electrode 1 12 in the chamber 100 of Figure 1 . Figure 3A depicts the electric field distribution 300A across the substrate 1 10 and the pedestal 108 with a capacitance of between about 50 pF and about 200 pF (i.e., high impedance) at the variable capacitor 128 coupled to the tuning electrode 1 12. As can be seen from this example, the electric field is fairly flat across the substrate 1 10 and the surface of the pedestal 108. This is because, at a high impedance (on capacitive side), the impedance of the substrate 1 10 has relatively little effect on the total impedance across the tuning electrode 1 12.

[0020] Figure 3B depicts the electric field distribution 300B across the substrate 1 10 and the pedestal 108 with a capacitance between about 1000 pF and about 2500 pF at the variable capacitor 128 coupled to the tuning electrode 1 12. As can be seen from this example, the electric field is lowered at the edge of the substrate 1 10 and the edge of the pedestal 108 as compared to the example in Figure 3A because the capacitance is increased and the impedance to the tuning electrode 1 12 (still on capacitive side) is lowered, and the relative impact of the substrate 1 10 on the total impedance across the tuning electrode 1 12 is increased.

[0021] Figure 3C depicts the electric field distribution 300C across the substrate 1 10 and the pedestal 108 with a capacitance between about 50 nF and about 150 nF (i.e., low impedance) at the variable capacitor 128 coupled to the tuning electrode 1 12. As can be seen from this example, the electric field is significantly lower at the edge of the substrate 1 10 and the edge of the pedestal 108 as compared to the examples in Figures 3A-3B. This is because at very low impedance in the pedestal 108 due to the tuning electrode 1 12, the impedance of the substrate 1 10 has a significantly greater effect on the total impedance than when the tuning electrode has a significantly higher impedance.

[0022] From the examples shown in Figures 3A-3C, it is clear that varying the capacitance in the variable capacitor 128 electrically coupled to the tuning electrode 1 12 results in a corresponding variation in the electric field across the surface of the substrate 1 10 and the pedestal 108. In particular, increasing the capacitance in the variable capacitor 128, and the corresponding decrease in the impedance through the tuning electrode 1 12, results in a decreased magnitude of the electric field at the edge of the substrate 1 10 and the edge of the pedestal 108 due to the RF coupling between the gas distribution manifold 1 18 and the tuning electrode 1 12 and the effect of the impedance of the substrate 1 10 relative to the overall impedance of the tuning electrode 1 12. Further, since the electric field is the power driver for generating the plasma in the chamber 100, it follows that increasing the magnitude of the electric field at the edge of the substrate 1 10 also increases the plasma density at the edge of the substrate 1 10. As a result, not only is the electric field across the surface of the substrate 1 10 being processed varied, but the plasma profile across the surface of the substrate 1 10 is correspondingly varied by varying the capacitance in the variable capacitor 128 electrically coupled to the tuning electrode 1 12. Correspondingly, the resulting film thickness profile deposited on the substrate 1 10 correlates with the plasma profile, resulting in the capability of varying the deposition film thickness profile by varying the capacitance in the variable capacitor 128 electrically coupled to the tuning electrode 1 12.

[0023] Figures 4A-4D are exemplary depictions of the resulting film thickness distribution across the substrate 1 10, processed in the chamber 100, using varying capacitances applied to the tuning electrode 1 12 during plasma deposition processing. Figure 4A depicts the film thickness distribution across the substrate 1 10 with the variable capacitor 128 set at 22% of its maximum capacitance. As can be seen from this example, the film thickness 400A is high near the edge of the substrate 1 10 as compared to the film thickness at the center of the substrate 1 10, and then abruptly drops to the minimum level before reaching the very edge.

[0024] Figure 4B depicts the film thickness distribution across the substrate 1 10 with the variable capacitor 128 set at 28% of its maximum capacitance. As can be seen from this example, by increasing the capacitance in the variable capacitor 128 (i.e., decreasing impedance), the film thickness 400B is lowered at the edge of the substrate 1 10 with respect to the film thickness at the center of the substrate 1 10 as compared to the example in Figure 4A, and then stretched out towards the edge of the substrate 1 10.

[0025] Figure 4C depicts the film thickness distribution across the substrate 1 10 with the variable capacitor 128 set at 32% of its maximum capacitance. As can be seen from this example, by further increasing the capacitance in the variable capacitor 128, the film thickness 400C is further lowered at the edge of the substrate 1 10 with respect to the film thickness at the center of the substrate 1 10 as compared to the example in Figure 4B, and further stretched out towards the edge of the substrate 1 10. As a result, the film thickness 400C is relatively uniform across the surface of the substrate 1 10.

[0026] Figure 4D depicts the film thickness distribution across the substrate 1 10 with the variable capacitor 128 set at 36% of its maximum capacitance. As can be seen from this example, by further increasing the capacitance in the variable capacitor 128, the film thickness 400C is substantially lowered at the edge of the substrate 1 10 with respect to the film thickness at the center of the substrate 1 10 as compared to the example in Figure 4C. As a result, the profile of the film thickness 400D is flipped over to the edge-low, center-high profile from the edge-high, center-low profile of the film thickness 400A shown in Figure 4A.

[0027] From the examples shown in Figures 4A-4D, it is clear that varying the capacitance in the variable capacitor 128 electrically coupled to the tuning electrode 1 12 results in a corresponding variation in the deposited film thickness across the surface of the substrate 1 10. In particular, increasing the capacitance in the variable capacitor 128, and correspondingly decreasing the impedance at the tuning electrode 1 12 and decreasing the electric field magnitude at the edge of the substrate 1 10 with respect to the center as shown in Figures 3A-3C, results in a decrease in the corresponding edge film thickness with respect to the center film thickness of the substrate 1 10. Thus, the varying the capacitance in the variable capacitor 128 coupled to the tuning electrode 1 12 allows for control of the film thickness profile (center to edge) across the surface of the substrate 1 10 being processed.

[0028] While the foregoing is directed to embodiments of the present invention, other and further embodiments of the invention may be devised without departing from the basic scope thereof, and the scope thereof is determined by the claims that follow.