GENERALLY

The Planet Earth or more precisely the Spacecraft EARTH, on which all of us ride, is in danger

5 of total destruction of its Biosphere and Civilization, as we know it today, through the catastrophic invasion of the worst and most dangerous enemy of Humanity, whom we call Climate Change, a very painless and complacent name for such a beastly criminal, who threatens to exterminate-murder Humanity, the Biosphere and the Civilization as we know it today, if we do not all of us mobilize in the battle against him, since "On the Spacecraft

10 EARTH, on which all of us ride, there are no Passengers. We are all Crew", Marshall McLuhan, Biography [3].

According to a US Army Secret Report [1], [2] leaked and published by The OBSERVER newspaper in London, which has also been featured in a Hollywood Science Film (funded by the US Army for Awakening of the Public Opinion), where are given in popular form the

15 catastrophic effects of Climate Change, which, according to the US Army's controversial study, entitled "The Day After Tomorrow" [4], result in an Ice Age, during which the Climate Change is predicted to exterminate-murder more than half of the Earth's population, over three and a half billion people, and those who will survive, if they survive, will have returned to the Stone Age and even to an Ice Age for the next 2,000-3,000 years, where the Pandemic

20 of Corona virus will seem like a simple cold, but maybe Corona virus will act as a spark of awakening of the Human Consciousness, in front of the Maximum Danger from the monstrous Mega-Criminal, which we wrongly call Climate Change,

The correct name of this Mega-Criminal should be Criminal-Climate Change, something that the current state of the art coyly avoids uttering, so as not to panic the Doomed Humanity,

25 since it has failed to develop weapons suitable to confront it, and it suffices in half meters, such as incentives to reduce carbon dioxide emissions to zero by 2050, which not only will not be effective but they are not observed at all, despite the (delayed) signing of the UN Resolution COP21 in Paris in December 2015 ,

Where on the one hand the US has declared that it is being released from it and on the other

30 hand the insatiable need for energy undermines it even more, with the Chinese promising to slow down the frantic growth rate of Coal-Fired Units (builds 4-5 Units of 500MW each per week), where it will reduce them to 2-3 Units of 500MW per week, until it adds about another 300GW by 2030, where it says will stop and the developing world follows with a plan to increase another 150GW by 2030, (ie more than all the US and European Union Coal-

35 Fired Units combined today), where with such developments it is not possible to defeat the Criminal-Climate Change, which is already here.

Even worse the overall increase in Carbon Dioxide in the Atmosphere instead of slowing down, in the contrary it is accelerating, with an increase in 2018-19 of about 3.0ppm / Year, when the average of the last twenty years was below 2.5ppm / Year, and is constantly

40 deteriorating , especially after the nightmare forest wild-fires on a global scale, with the latest examples.being the. nightmarish satellite-! mages of burning. Australia-from. end. to-end. . . [5], plus the Amazon [6], Siberia, California, Canada, China, etc., which by themselves account for about half of the planet's Carbon Dioxide emissions.

The latest Manifesto (11.05.2019) by more than 11,200 Environmental and Energy Scientists from 153 countries, including Greece [7], [8], declares that we no longer simply have Climate Change but an Urgent Need due to Climate Change ("Climate Change Emergency"), where Climate Change is already here, and that it does not "take" us the time to wait to react until 2050, it may be too late and with no return, we must react and fight it now, yesterday! "We are the first Generation to experience the Climate Change and the last one able to take action to address it" (Scream of Anxiety at the WWF Annual Report on 10/30/2018) [9].

Recent studies by the most reputable Internationally Recognized Research Institutions and the UN [10], [11], [12], indicate that the target of 2.0°C as a ceiling for global warming is no longer enough, but we need a new target of 1.5°C, so that we have a better chance that Climate Change will not become irreversible and that for this purpose it is not enough just to zero C02 emissions by 2050, but we also need to reduce the volume of Carbon Dioxide trapped in the Atmosphere, where Carbon Dioxide survives for over a thousand years, ie to develop Negative Carbon Dioxide Emissions Power Plants, or as they are called the proposed by the present invention Units, Negative C02 Emissions Units, for the Binding of As Much As Possible Quantities of Atmospheric Carbon Dioxide and As Soon As Possible,

Whereas with the best version of the UN 1.5°C Scenario we will achieve zero carbon dioxide emissions in 2050, since in the meantime an additional 1500 Gigatons of Carbon Dioxide will have been accumulated in the atmosphere (based on 2015), so that we have an 80% chance that Climate Change will not become Irreversible and a Criminal-Climate Change (but with a 20% chance that it will become Irreversible and a Criminal-Climate Change, with all what that entails for Human Lives, Biosphere and Civilization as we know it today),

In the contrary by the application of the Negative C02 Emissions Units, which can profitably modify the existing and currently operating Coal and Natural Gas-Fired Power Plants into Negative C02 Emissions Units, so that in 2050 instead of an increase of the accumulated in the atmosphere Carbon Dioxide by 1500 Gigatons ( based on 2015 or 1430 Gigatons based on 2020 with all the allowable margins due to recession due to the Corona Virus), instead we will have a reduction of the amount of Carbon Dioxide accumulated in the Atmosphere due to the operation of Negative C02 Emissions Units with absorption of 1430 Gigatons of Carbon Dioxide from the Atmosphere, so the increase in Carbon Dioxide in the Atmosphere compared to 2020 will be zero [13], with an incomparably better chance that the Criminal- Climate Change will be defeated and will not become Irreversible, with a fabulous business profit for the International Business Community plus the inconceivably greater value of rescuing the victims of the Criminal-Climate Change and of the Civilization as we know it today.

At the same time, among other things, it is recommended that we should protect the Forests from Wild-Fires and carry out Extensive Reforestation, with more than 30 Billion New Trees required, but with a noticeable result in 30-40 years after planting (maybe too late then!), with the first announcement from Australia for 1.0 Billion Trees (very few but it is a beginning), in ^’ contrast to the Negative C02 Emissions Units, which protect the' Forests directly by cleaning them from the Residual Biomass and Dead Trees (which it converts into Biomass Volatiles for Electricity Generation and Pyrolytic Activated Carbon) and implement the required Billions of New Trees also with profit, as Fruit Trees, where with their orgiastic growth through the Pyrolytic Activated Carbon as a Soil Conditioner, they will bring greater results, in half the time and spectacular gains for the international economy,

At the same time, a corresponding change in human behavior in energy consumption from the use of the means of transport is recommended, which today consumes more than 60% of world oil production, where the current state of the art promotes half measures, such as the Electric Car, which then only is neutral in terms of Carbon Dioxide emissions, if the electricity consumed comes 100% from RES, otherwise it is highly polluting, or very expensive solutions for Shipping and Air Transport with Green Biofuels, where all the proposed solutions at the best case emit no or a reduced percentage of Carbon Dioxide, but not the much sought after and absolutely necessary Negative Carbon Dioxide Emissions,

On the contrary the Negative C02 Emissions Units, provide immediate, cost-effective and environmentally beneficial solutions, as mentioned below, for both the Green CNG for the Automotive sector and the Shipping, Air and other Land Transport and other Means of Transportation with Virtual Green Biofuels, as follows, which arise as inexpensive byproducts of Electricity Generation with Clean Biomass Volatiles and Negative Carbon Dioxide Emissions and which not only do not emit carbon dioxide, but instead absorb carbon dioxide from the Atmosphere, benefiting the Environment and saving the existing infrastructure in the Means of Transportation, which with little or no modifications can now operate with Negative Carbon Dioxide Emissions,

In addition, the current state of the art recommends a shift to Clean Energy Sources, such as RES (clean but insufficient to cover the Load Curve and the Strategic 90 Day Reserve of Coal, in times of crisis or prolonged winter), with parallel abolition and dismantling of the entire existing gigantic infrastructure in Fossil Fuel-Fired Power Units, over 5,000GW on a global scale, with incalculable damage to the shares of the Companies operating such Units, loss of millions of jobs, risk of grid instability with operation with RES only, expensive and uncertain solutions to fill the gap, such as Hydrogen, Batteries, Nuclear Energy, etc.

Where on the contrary the Negative C02 Emissions Units of the present Invention come to cover the above deficiencies and uncertainties with the Rescue of Existing or New Fossil Fuel-Fired Power Plants, which with little or no conversions are transformed into Green Units that not only do not emit Carbon Dioxide, but in the contrary they operate with absorption and binding up to twice quantities of Atmospheric Carbon Dioxide, i.e. with the sought great Negative Carbon Dioxide Emissions, creation of millions of jobs, consolidation of the value of the shares of the Companies owning Fossil-Fuel-Fired Units transformed into Negative C02 Emissions Units, creation of Green Fuels for Transportation, more than doubling of the Agricultural Production with the use of the produced Pyrolytic Activated Carbon as Soil Conditioner and many more, as given below,

And most importantly, the Negative C02 Emissions Units Technology transforms the operation of the Existing Fossil Fuel-Fired Units from loss-making to extremely profitable, with a number of parallel beneficial effects as above and beyond, since it supplies us- not only with the missing Weapons for the fight against the Climate Change, but also the Weapons against Global Economic Regression due to Corona Virus and much more, that is, on the one hand the Heavy Artillery to Fight the Climate Change and on the other hand a Source of Great Prosperity and Wealth from the same Weapons of defending against the Climate Change, which is offered to us to implement it, even if we did not have the War of Existence Against Climate Change, simply because it dramatically improves the level of Prosperity and Wealth of Human Society and protects the Biosphere on a planetary level.

B. THE FIELD OF KNOWLEDGE TODAY Carbon dioxide capture technology has made significant progress in other applications such as the production of ammonia and fertilizers, as well as applications where the carbon dioxide produced is sold as a commercial product for various industrial uses. However, for the application in the Coal-Fired Power Plants, an even further reduction of both the investment cost of the binding of the carbon dioxide (Capex) and of the cost of the produced kilowatt-hour is needed, in order that its application becomes competitive and sustainable, as well as for the possibility of alternative storage of carbon dioxide, when it is not used as a commercial product, while the technology for sustainable Negative Carbon Dioxide Emissions is completely missing.

Internationally there is an impressive production by Patents and Papers, where suggestions are made for the solution of the problems set forth below, but despite research and demonstrations, it has not been possible to show any technology that is technically and economically viable to address them. In the European Union, the carbon dioxide tax is expected to increase from current levels of € 25 / Ton.C02 to € 30-35 / Ton.C02, the imposition of which will enhance the viability of carbon capture and storage systems but does not solve the problems set out below.

Whereas the current state of the art, despite the support, the large funding and the efforts to date, is not able to present a technically and economically viable technology for a Biosphere Protection and Rescue perspective through the absolutely necessary Negative Carbon Dioxide Emissions and which, on the other hand, can be offered by the technology of Negative C02 Emissions Units or Negative Carbon Dioxide Power Plants of the present invention,

Where with the production of Pure Biomass Volatiles in combination with Pyrolytic Activated Carbon, which are co-produced in Modified New or even Existing Electricity Generating Negative C02 Emissions Units, in Innovative Pyrolysis-Carbonation Units under Pressure, is succeeded the environmentally sought, i.e. Electricity Generating Units, which instead of emitting carbon dioxide into the Atmosphere, on the contrary, they absorb up to more than twice the amount of atmospheric carbon dioxide from the Atmosphere, in relation to the carbon dioxide emissions from the respective fossil fuels-fired units, through the coproduced Pyrolytic Activated Carbon, which constitutes at the same time an excellent Soil Conditioner, which remains permanently in the soil for hundreds or even thousands of years and doubles the agricultural production imperpetuity, The European Investment Bank, the European Union's Financing Arm, has already announced in mid-2019 that it will stop funding fossil fuel-related projects from 2021, even for Natural Gas, which was considered the fuel of the transition to the Era of Clean Fuels and was expected to cover the Load Curve, in order to secure Grid Stability due to the nature of RES, which are stochastic sizes and do not guarantee the coverage of the Load Curve, at night or when the Sun is not enough (PV) or when the Wind is not blowing (Wind), which shows recognition of the criticality of the current situation,

In addition, a very important parameter, which is introduced with the Negative C02 Emissions Units proposed in the present invention, is the survival and further operation of the existing giant infrastructure of the Coal and Natural Gas (NG)-Fired Power Plants, which with a small modification according to this Technology, are converted into Negative C02 Emissions Units, which not only do not emit carbon dioxide into the Atmosphere, but instead are transformed into Green Giant Defenders of the Environment and Biosphere and into Warriors against the Criminal-Climate Change, which are absorbing and binding up to more than double the quantities of Atmospheric Carbon Dioxide, which will thus be the Heavy Artillery in the fight against the Criminal-Climate Change, improving the environment and contributing decisively into achieving the new UN goal of reducing global warming below 1.5°C by 2050.

Where the amount of atmospheric carbon dioxide, which has already been accumulated in the Atmosphere, is estimated at 3500 Gigatonnes (2015) while the maximum allowable amount, so that Climate Change does not become Irreversible according to COP21 in Paris in 2015, is 5000 Gigatons, that is, it is allowed to emit a maximum of 1,500 Gigatons in 35 years by 2050 (based on 2015) or 1,430 Gigatons based on 2020, because despite UN appeals, carbon dioxide emissions are still rising at an alarming rate of over 3,0ppm/Year, where the concentration of carbon dioxide in the Atmosphere is dangerously close to the limit, after which Climate Change can become Irreversible,

Where, on the contrary, if the Modification of the Existing Coal- and Natural Gas-Fired Power Plants is made, according to the Technology of the Present Invention in Negative C02 Emissions Units for operation with Pure Biomass Volatiles and production of Pyrolytic Activated Carbon with up to double Negative Carbon Dioxide Emissions, as above, of all the existing today in operation Coal and Gas-Fired Power Plants, can be reversed the upward trend of Carbon Dioxide Emissions into the Atmosphere on a planetary scale and even be converted to a corresponding downward trend, resulting instead of an increase of 1,500 Gigatonnes of Carbon Dioxide by the 2050, as much as the safety margin given by the UN in 2015, to have a zero increase or even decrease in the concentration of Carbon Dioxide in the Atmosphere, resulting in a much better chance that the Criminal-Climate Change will not become Irreversible [13],

To date, the main effort to zero carbon dioxide emissions in coal and fossil fuel-fired power plants is to try to capture the carbon dioxide emitted from the exhaust gases of the respective power plants by flushing with a solution of Ammonia and subsequently compression and conducting with piping networks for permanent storage in underground geological formations. However, despite the funding and demonstration projects that have been implemented, the corresponding effort has not succeeded in developing carbon dioxide capture technologies, which are economically and environmentally sustainable, to give clean coal-fired power generation and are still under investigation and development,

Whereas, in addition, these technologies simply seek to reduce or even eliminate carbon dioxide emissions, although it is necessary not only to reduce carbon dioxide emissions from its various sources, but also to reduce Carbon Dioxide Emissions from the Atmosphere (Negative C02 Emissions), where carbon dioxide can survive for over a thousand years, and where no viable carbon dioxide emissions technology for power plants has been proposed or demonstrated to date. Also regarding the new UN 1.5°C overheating limit for 2050, it is worth noting that the commitment and reduction of large-scale Negative Carbon Dioxide Emissions will significantly contribute to the achievement of this additional goal, because the proposed modifications to the Existing Power Plants for their conversion into Negative Carbon Dioxide Emissions Units involve, on the one hand, minimal modifications to the Existing Power Plants and, on the other hand, a fabulous business profit, on the base of which they can be undertaken by the International Business Community and be realized 10-15 years earlier than the UN 2050 target, where such a saving of time can be the Regulatory Factor that will weigh on the sensitive Environmental Scales of the Planet, in order to tip it to salvation instead of the nightmare of the Climate Change. The Negative C02 Emissions Units will thus be the Vaccine against the catastrophic Climate Change Virus.

C. ADVANTAGES OF THE CURRENT INVENTION TOWARDS THE CURRENT STATE OF THE ART

The main Advantages of the Present Invention towards the Current State of the Art, are set out below in comparison with the treatment of the hot Problems in the field of Energy, the risk of Climate Change and the degradation of the Environment, in the most critical period for the future of Civilization on the Planet, which faces a unique challenge in its history due to Climate Change, which may even mean the end of Civilization as we know it today, as pointed out by all International Research Organizations and the UN, such as:

"We are the first Generation to know that we are destroying our Planet and the last one that can do something about it," the WWF points out in its Annual Report on 30.10.2018 [9], while recently (11.05.2019) the Declaration published by more by 11,250 scientists from 153 countries, including Greece, who co-sign the Declaration, warning that there is now not just Climate Change, but "Climate Change Emergency" [7], [8], where they speak together with UNCC 2018 of the UN, about "unspeakable human suffering" that will become inevitable, unless there is an immediate and lasting shift in human activities, which aggravates the climate and raises the temperature through "greenhouse gas emissions", and where perhaps the most successful incitement to mobilize in the fight against the threat of the Climate Change belongs to the weii-known Canadian sociologist Marshall McLuhan, who declared that "In the Spacecraft EARTH there are no Passengers. We Are All Crew" Marshall McLuhan, Biography [3], Whereas tackling the risk of Climate Change, in addition to reducing to zero carbon dioxide emissions by 2050, requires, according to reputable International Research Bodies, State Research Centers and the UN IPCC ([10], [11], [12]) the commitment and permanent storage of even greater quantities of Atmospheric Carbon Dioxide or Negative Carbon Dioxide Emissions, in order to achieve the new UN target of global warming below 1.5°C, in order to hope to a better chance that the Climate Change will not become Irreversible,

Where to achieve this new UN target are listed below the Advantages of the Negative C02 Emissions Units of the Present Invention, resulting from the combination of an innovative Pyrolysis Unit under Pressure in conjunction with Modified Electricity Production Systems (A.E.i), which enable the production of electricity not only with Zero Carbon Dioxide Emissions but on the contrary the production of a very large scale of Negative Carbon Dioxide Emissions, with a parallel dramatic increase in Agricultural Production through the use of the co-produced Pyrolytic Activated Carbon as an Excellent Soil Conditioner for the cultivations and where the advantages of the Negative C02 Emissions Units of the present invention in comparison to the Current State of the Art, which provide a solution to the existing Problems, are indicatively among others the following:

1) They include the Pyrolysis-Carbonation Unit (A.4.10) which is characterized by the fact that in cooperation with the Negative Carbon Dioxide Emissions Power Generation Systems (A.E.i) gives Technically and Economically Sustainable Solutions to the main problems related with Energy Production, the Degradation of the Environment and the confrontation of the Danger of Climate Change, which cannot be solved by the Current State of the Art, where through the Pyrolysis-Carbonation Unit (A.4.10) are briefly characterized, among others, by the fact that:

2) They produce Pyrolytic Biomass Volatiles (009) free from almost 100% of their Harmful Components (A.10.1) for the Boilers (012) of the Steam Power Plants (A.5.1) and for the Gas Turbines (A.6.1A) of the Single or Combined Cycle Power Generation Units (A.6.G) or (A.6.1) in Power Generation Systems (A.E.i), where i = 1 to 5 characterizes the respective versions of the Power Generation Systems with Negative C02 Emissions Units as described below,

3) The Negative C02 Emissions Units with the cooperating Power Generation Systems (A.E.i) not only do not emit Carbon Dioxide but instead operate with binding of up to more than double quantities of Atmospheric Carbon Dioxide or with Negative Carbon Dioxide Emissions.

4) They save from the devaluation and early dismantling more than 5,000GW Fossil Fuel- Fired Power Plants, which with a small modification are transformed into cooperating Negative C02 Emissions Units (A.E.i),

5) The Negative C02 Emissions Units on the one hand avoid the Charges of Purchase of Carbon Dioxide Emissions Rights and on the other hand secure an even bigger Credit due to the corresponding bigger Negative Emissions of Carbon Dioxide,

6) Where the Pyrolysis-Carbonation Unit (A.4.10) produces at the same time the Pyrolytic Activated Carbon (008 _A ) and (008 _B ), which is characterized by the fact that on the one hand it constitutes the Negative Carbon Dioxide Emissions and on the other hand it constitutes the filter that holds the harmful components (A.10.1) of the Biomass Volatiles (009) and makes them suitable for Boilers (012) and Gas Turbines (A.6.1A),

7) Also from the fact that Pyrolytic Activated Carbon (008A) and (008B), instead of being buried at high cost in underground geological formations, instead is sold at a profit in agriculture as a permanent soil conditioner that more than doubles the agricultural production, where it remains unchanged for hundreds or even thousands of years and increases agricultural production in perpetuity,

8) Where the Negative C02 Emissions Units in collaboration with the Pyrolysis-Carbonation Unit (A.4.10) and the Negative Carbon Dioxide Emissions Power Generating Systems (A.E.i), ensure the Coverage of the Load Curve and the Strategic Reserve of 90 Days in periods of Extreme Weather Phenomena or other Crises, due to long-term storage of Biomass,

9) They reduce the risk of Wild-Fires by clearing the Forests of the Residual Thin Biomass (A.2.1), which through the Pyrolysis-Carbonation Unit they transform it together with the Woody Biomass (A.2.2) of the Dry or Burnt Trees into Clean Biomass Volatiles and Pyrolytic Activated Carbon (008 _A ) and (008 _B ),

10) The Negative C02 Emissions Units with the Negative Carbon Dioxide Emissions Power Generation Systems (A.E.i), enable the Virtual Methanization of the Biomass Volatiles (009) into Green CNG (010E) for the Cars, the burning of which produces Negative Carbon Dioxide Emissions, through cooperation of the Negative C02 Emissions Units with the Natural Gas and CNG Distribution Companies such as DEPA,

11) Negative C02 Emissions Units with the Negative Carbon Dioxide Emissions Power Generation Systems (A.E.i), enable the production of Virtual Green Biofuels (010 _H ) for Shipping through the participation of Ship Owners as Strategic Investors for the investments for Negative C02 Emissions Units ,

12) Similarly to produce the Virtual Green Biofuels (010 _z ) and (010 _M ) for Air Transport and other Means of Transportation through the participation of their Owners or the Supplier Refineries of Green Biofuels (010 _z ) and (010 _M ) as Strategic Investors for Negative C02 Emissions Units as above,

13) Also in cooperation with the Negative Carbon Dioxide Emissions Power Generation Systems (A.E.i), they are replacing the planned new Coal-Fired Units in China and in the Developing World with economically competitive Negative C02 Emissions Units of Negative Carbon Dioxide Emissions,

14) They ensure the survival of Natural Gas and part of Petroleum Products in the form of Green CNG (010 _E ) and Green Biofuels (010 _H ), (010 _z ) and (010 _M ) with Negative C02 Emissions, even beyond 2050, where based on the UN COP21 Resolution they had to be nullified,

15) Through the participation of Ship-Owners and other Owners of Means of Transportation as Strategic Investors as above, they provide Funds for the necessary investments for the conversion of Existing or New Fossil Fuel-Fired Units into Negative C02 Emissions Power Generation Systems (A.E.i) with Negative C02 Emissions Units,

16) The Negative C02 Emissions Units are also characterized by the fact that because in the innovative Pyrolysis-Carbonation Unit (A.4.10) the Pyrolysis-Carbonation is carried out under pressure, indicatively above 20Bar, which is created by the released Biomass Volatiles (009,) the following additional significant advantages for the whole Biomass Pyrolysis- Carbonation process of the Biomass (A.2.2) and (A.2.1) arise, in addition to what is briefly analyzed above, i.e. they are further characterized by the fact that:

17) The Negative C02 Emissions Units with the innovative Pyrolysis-Carbonation Unit (A.4.10) Under Pressure are characterized by the fact that in Pyrolysis-Carbonation under a pressure of 20-40 atmospheres, the required thermal energy of pyrolysis-carbonation is sharply reduced, which under conditions above 20 atmospheres becomes negative [14] (Figure 1 and Table 2], i.e. the Pyrolysis-Carbonation reaction becomes exothermic, where instead of consuming energy in the form of heat, it instead gives off heat to the innovative Pyrolysis-Carbonation Units (A.4.10) and thus improves the overall efficiency of power generation, indicatively by 2-4%, in contrast to Pyrolysis-Carbonation with the current state of the art where a significant amount of energy is consumed for the Pyrolysis-Carbonation process with a corresponding deterioration of the efficiency of the respective power generation,

18) Where Negative C02 Emissions Units with the innovative Pyrolysis-Carbonation Units (A.4.10) Under Pressure are also characterized by the fact that because the Pyrolysis- Carbonation of Dry Biomass is carried out under pressure, indicatively of more than 20 Bar, which is created by the released Biomass Volatiles, the Thermal Power of the Pyrolysis- Carbonation Units is multiplied, because the released Biomass Volatiles, which create the overpressure, due to the overpressure conduct the pyrolysis-carbonation heat better to and from the Sub-Chamber Casing of the pyrolysis-carbonation inside, to and from the pyrolyzed Biomass, which is additionally stirred back and forth by the operation of the System of the Two-Direction Screws or Helixes, where on the one hand the Thermal Power of the Unit increases and on the other hand the necessary pyrolysis-carbonation time decreases,

19) Where the Negative C02 Emissions Units with the innovative Pyrolysis-Carbonation Units (A.4.10) Under Pressure are also characterized by the fact that due to the pyrolysis- carbonation under pressure, of the order of more than 20Bar, the production of high quality Pyrolytic Activated Carbon (008 _A ) kai (008 _B ) increases in an amount of up to more than 50% in relation to the corresponding production under atmospheric pressure [14] (Table 2], i.e. the production of Pyrolytic Activated Carbon (008A) and (008B) reaches indicatively up to more than 40 % of the weight of Dry Biomass (A.2.2 _A ) and (A.2.1 _a ) from which it comes, compared to 20-27% of the weight of Dry Biomass under atmospheric pressure with the present state of the art,

20) Where the Negative C02 Emissions Units with the innovative Pyrolysis-Carbonation Units (A.4.10) Under Pressure are also characterized by the fact that because the Pyrolysis- Carbonation Sub-Chamber (002A _o ) of the innovative Pyrolysis-Carbonation Units (A.4.10) remains closed for a relatively long time, relative to the time of simple passage of Biomass Volatiles (009) through the mass of Pyrolytic Activated Carbon (008 _A ) and (008 _B ) under atmospheric pressure, this results in the Biomass Volatiles (009) produced to come into a prolonged and pressurized contact with the produced Pyrolytic Activated Carbon (008 _A ) and (008 _b ), in which case occurs almost complete cleaning near to 100% of the produced Biomass Volatiles (009) from their Harmful Components (A.10.1) (i.e. Potassium, Sodium, Chlorine, Nitrogen, Sulfur, etc.), which are absorbed and retained by the huge mass of the continuously stirred Pyrolytic Activated Carbon (008 _A ) and (008 _B ) and allow the safe use of the Purified Biomass Volatiles (009) for Power Generation, as opposed to the one under the present state of the art under atmospheric pressure, where the purification of Biomass Volatiles (009) from their Harmful Components (A.10.1) is incomplete, which makes them unsuitable for combustion in the Boilers (012) of the Steam Power Units or in the Gas Turbines (A.6.1A) of the Combined Cycle Units (A.6.1), as analyzed below,

21) Where the Negative C02 Emissions Units with Innovative Pyrolysis-Carbonation Units (A.4.10) Under Pressure are also characterized by the fact that in many applications and types of Biomass this First Passage of Biomass Volatiles (009) through the mass of Pyrolytic Activated Carbon (008 _A ) and (008 _B ) and under the applied overpressure, is sufficient for a very satisfactory cleaning of the Biomass Volatiles (009), for the protection of the Boiler (012) or the Gas Turbine (A.6.1 _a ) of the respective Power Units, so either the additional Biomass Volatiles Cleaning Passages through additional Spare Sub-Chambers Pairs full with Pyrolytic Activated Carbon becomes unnecessary, or the number of required Multi- Passages of Biomass Volatiles Cleaning Passages is drastically reduced to achieve the desired level of Safe Pure or Mixed Combustion of Biomass Volatiles (009) in Boilers or in Gas Turbines of Modified Electricity Production Negative C02 Emissions Units,

22) Where the Combined Cycle Negative C02 Emissions Units with Innovative Pyrolysis- Carbonation Units (A.4.10) Under Pressure, which supply with Biomass Volatiles the Gas Turbine of the Electricity Power Generation, are also characterized by the fact that due to the production of Biomass Volatiles under pressure, indicatively above 20Bar, they can be fed directly into the Combustion Chamber of the Gas Turbine of the Combined Cycle Units (A.6.1) of the Power Generation Systems (A.E.i) with Negative C02 Emissions Units, in which case the Compressor (A.6.1 _H ) becomes obsolete, with a corresponding improvement of the degree of efficiency, otherwise as analyzed in the Power Generation System (A.E.3) below, as opposed to pyrolysis-carbonation under the present state of the art under atmospheric pressure, where Biomass Volatiles even when cleaned of their Harmful Components (A.10.1), need the Compressor (A.6.1 _H ) for the compression at a pressure above 20Bar to enter the Combustion Chamber of the Gas Turbine (A.6.1 _a ), with a worsening effect of the degree of efficiency,

23) Where the Combined Cycle Negative C02 Emissions Units with Innovative Pyrolysis- Carbonation Units (A.4.10) Under Pressure and in collaboration with the Negative C02 Emissions Units Gas Turbine, are also characterized by the fact that because the pyrolysis- carbonation process becomes exothermic, instead of consuming energy in the form of heat, on the contrary it delivers heat to the Exhaust Boiler (012B) of the cooperating Combined Cycle Unit (A.6.1), whereupon the After-Burning Chamber (A.6.1 _E ) is abolished, which was necessary when pyrolysis-carbonation is done under atmospheric pressure, otherwise as analyzed in the Power Generation System (A.E.3) below,

24) Where the super-increased Crop Production due to the use of Pyrolytic Activated Carbon (008 _a ) and (008 _B ) as Soil Conditioner of the Negative C02 Emissions Units with the innovative Pyrolysis-Carbonation (A.4.10) and the corresponding increased production of woody Biomass (A.2.2 ) increases the capture of Atmospheric Carbon Dioxide, which is even larger in size over time than the one of the Negative Carbon Dioxide Emissions of Power Generation Systems (A.E.i), D. DRAWINGS

- Drawing No.l shows the General Layout Plan of the Atmospheric Carbon Dioxide Emissions Binding System with pyrolysis-carbonation of Biomass, consisting of a number of Pairs of Pyrolysis-Carbonation Chambers (001A) and Sub-Chambers (002A) with their Peripherals in cooperation with a Modified Steam Power Plant Fired with Biomass Volatiles. - Drawing No.2 shows the General Layout Plan of the Atmospheric Carbon Dioxide Emissions

Binding System with Pyrolysis-Carbonation of Biomass, consisting of a number of Pairs of Pyrolysis-Carbonation Chambers (001A) and Sub-Chambers (002A) with their Peripherals in cooperation with a Modified Combined Cycle Power Plant Fired with Biomass Volatiles.

- Drawing No.3 shows in Side View the General Layout on three levels of the Innovative Drying-Pyroiysis-Carbonation Unit A.4.10 and A.4.1A with Spherical Valves (039), (040) in series indicatively of the Fixed Tubular Sub-Chambers (002A _OA ), (002A _o ), (002A _O B) and Sub- Chambers (002A _AA ), (002A _a ), (002A _ab ),

- Drawing No.4 shows in Section and Side View the construction of the Drying-Preheating Sub-Unit A.4.1OA, A.4.1AA, A.E.I.3 _AA of the versions of the Innovative Drying-Pyrolysis- Carbonation Unit A.4.10 and A.4.1A with Spherical Valves in series in the Fixed Tubular Sub- Chambers (002A _oa ) or (002A _aa ),

- Drawing No.5 shows in Section and Side view the construction of the Pyrolysis- Carbonation Sub-Unit A.4.1 ₀ , A.4.1 _a , A.E.1.4 _A of the versions of the Innovative Drying- Pyrolysis-Carbonation Unit A.4.10 and A.4.1A with Spherical Valves in series in the Fixed Tubular Sub-Chambers (002A _o ) or (002A _a ),

- Drawing No.6 shows in Section and Side View the construction of the Cooling-Fleat- Exchanging Sub-Unit A.4.1 ₀ B, A.4.1 _b , A.E.I.4 _AB of the versions of the Innovative Drying- Pyrolysis-Carbonation Unit A.4.10 and A.4.1A with Spherical Valves in series in the Fixed Tubular Sub-Chambers (002A _O B) or (002A _ab ), - Drawing No.7 shows in Section and Side View the construction of the Sub-Units of Drying-

Preheating A.4.1AA _aa , Pyrolysis-Carbonation A.4.1AA _A and Cooling-Fleat-Exchanging A.4.1AA _AB of the Version of the Composite Innovative Drying-Pyroiysis-Carbonation Unit A.4.1H with Spherical Valves in series in the three phases of Sub-Units resulting from the alternation of Isolation Valves and Air Ducts, with Side Valves (039), (040) and (034), (017) and (021) indicatively in the Fixed Tubular Sub-Chambers (002AA _aa ), (002AA _a ) and (002AA _ab ),

- Drawing No.8 shows in Section and Side View the Detail A1 of the Innovative Drying- Pyrolysis-Carbonation Unit A.4.10, A.4.1A, A.4.1H, with Spherical Valves in a row indicatively in the Fixed Tubular Sub-Chambers (002A _o ), (002A _a ), (002A _h ),

- Drawing No.9 shows in Section A-A' the construction of the Innovative Drying - Pyrolysis - Carbonation Unit A.4.1A with Spherical Valves in series indicatively in the Fixed Tubular Sub- Chambers (002A _aa ), (002A _a ), (002A _ab ),

- Drawing No.10 shows in Section B-B' the construction of the Support Scaffolds of the Innovative Drying - Pyrolysis - Carbonation Units A.4.10, A.4.1A, A.4.1E, A.4.1FI in the versions with Spherical or Side Valves indicatively in the Fixed or Rotating Tubular Sub- Chambers (002A _o ), (002A _a ), (002A _e ) KCU (002A _h ),

- Drawing No.11 shows the Interconnection Diagram of the Cooling-Fleat-Exchanging (002A _ab ), (002A _eb ) and (002A _hb ) and the Cooling-Heat Exchangings (002A' _ab ), (002A' _eb ) and (002A' _hb ) or (002A" _ab ), (002A" _eb ) and (002A" _HB ) via the Four Way Valves (015 _x ) or (015' _x ),

- Drawing No.12 shows in Side View the General Layout at one level of the Innovative Drying -Pyrolysis-Carbonation Units A.4.10, A.4.1A and A.4.1E with Side Valves (039), (040) and (034) , (017) and (021) indicatively in the Fixed or Rotating Tubular Sub-Chambers (002Ao), (002A _a ) and (002A _E ),

- Drawing No.13 shows in Section and Side View the construction of the Drying-Preheating Sub-Unit A.4.10A and A.4.1AA of the versions of the Innovative Drying-Pyrolysis-Carbonation Units A.4.10 and A.4.1A with Side Valves (039), (040) and (034), (017) and (021) in the Fixed Tubular Sub-Chambers (002A _oa ) and (002A _M ),

- Drawing No.14 shows in Section and Side View the construction of the Pyrolysis- Carbonation Sub-Units A.4.1 ₀ kai A.4.1 _A of the versions of the Innovative Drying-Pyrolysis- Carbonation Units A.4.10 and A.4.1A with Side Valves (039), (040) and (034), (017) and (021) in the Fixed Tubular (002A _o ) and (002A _a ),

- Drawing No.15 shows in Section and Side View the construction of the Cooling-Heat- Exchanging Sub-Units A.4.1 _O B kai A.4.1 _AB of the versions of the Innovative Drying-Pyrolysis- Carbonation Units A.4.10 and A.4.1A with Side Valves (039), (040) and (034), (017) and (021) in the Fixed Tubular Sub-Chambers (002A _OB ) kai (002A _ab ),

- Drawing No.16 shows in Section and Side View the construction of the Sub-Units Drying- Preheating A.4.1AA _aa , Pyrolysis-Carbonation A.4.1AA _A and Cooling-Heat-Exchanging A.4.1AA _AB of the Version of the Composite Innovative Drying-Pyrolysis-Carbonation Unit A.4.1H in the three phases of Sub-Units resuiting from alternation of isolation Valves and Air Ducts, with Side Valves (039), (040) and (034), (017) and (021) indicatively in the Fixed Tubular Sub-Chambers (002AA _aa ), (002AA _a ) and (002AA _ab ), - Drawing No.17 shows in Section and Side View the Detail A2 of the Innovative Drying- Pyrolysis-Carbonation Unit A.4.1E with Side Valves (039), (040) and (034), (017) and (021) indicatively of the Extreme Fixed Part (002A _M ), (002A _a ) and (002A _ab ) of the Rotating Tubular Sub-Chambers (002A _ea ), (002A _e ) and (002A _eb ), - Drawing No.18 shows in Section and Side View the construction of the Drying-Preheating

Sub-Unit A.4.1EA of the Version of the Innovative Drying-Pyrolysis-Carbonation Unit A.4.1E with Side Valves (039), (040) and (034 ), (017) and (021) in the Rotating Tubular Sub- Chambers (002A _ea ),

- Drawing No.19 shows in Section and Side View the construction of the Pyrolysis- Carbonation Sub-Unit A.4.1E of the Version of the Innovative Drying-Pyrolysis-Carbonation

Unit A.4.1E with Side Valves (039), (040) and (034 ), (017) and (021) in the Rotating Tubular Sub-Chambers (002A _E ),

- Drawing No. 20 shows in Section and Side View the construction of the Cooling-Heat- Exchanging Sub-Unit A.4.1EB of the Version of the Innovative Drying-Pyrolysis-Carbonation Unit A.4. IE with Side Valves (039), (040) and ( 034), (017) and (021) in the Rotating Tubular Sub-Chambers (002A _EB ),

- Drawing No.21 shows in Section and Side View the construction of the Drying-Preheating Sub-Units A.4.1AE _ea , Pyrolysis-Carbonation A.4.1AE _E and Cooling-Heat Exchange A.4.1AE _EB of the Version of the Composite Innovative Drying-Pyrolysis-Carbonation Unit A.4.1AE in the three phases of Sub-Units resulting from alternation of Isolation Valves and the respective Air Ducts, with Side Valves (039), (040) and (034), (017) and (021) indicatively in the Extreme Fixed Part (002AA _aa ), (002AA _a ) and (002AA _ab ) of the Rotating Tubular Sub-Chambers (002AE _ea ), (002AE _e ) and (002AE _eb ),

- Drawing No.22 shows in Section and Side View the Detail A3 of the Innovative Drying- Pyrolysis-Carbonation Unit A.4.1E with Side Valves (039), (040) and (034), (017) and (021) indicatively in the Extreme Fixed Part Sub-Chambers (002A _aa ), (002A _a ) kai (002A _ab ) of the Rotating Tubular Sub-Chambers (002A _ea ), (002A _e ) kai (002A _EB ),

- Figure No23 shows the predicted Evolution Curve of the Concentration of Emitted Carbon Dioxide in the Atmosphere without the Negative C02 Emissions Units, in contrast to the predicted Evolution Curve with the Negative Carbon Dioxide Emissions Scenario based on the Technology of Negative C02 Emissions Units of the Present Invention.

E.l. DESCRIPTION OF NEGATIVE CQ2 EMISSIONS UNITS: A CLIMATE CHANGE DEFENCE SYSTEM WITH NEGATIVE CARBON DIOXIDE EMISSIONS ELECTRICITY PRODUCTION UNITS

The Present Invention is characterized by the fact that it consists of a Power Generation System (A.E.i), with Negative C02 Emissions Units, where i = 1 to 5, is the index of the Alternative Versions of the Power Generating System (A.E.i), which consists of from a Combination of an Innovative Pyrolysis-Carbonation Unit under Pressure (A.4.10) or (A.4.1A) or (A.4. IE) or (A.4.1H) or at atmospheric pressure (A.4.1'0 ) or (A.4.1Ά) or (A.4.1Έ) or (A.4.1Ή), of Biomass (A.2.2) and (A.2.1), for the production on the one hand of Clean Biomass Volatiles (009) for Electricity generation, in combination with either a Modified Steam Electric Power Plant (A.5.1) with Pure or Mixed Combustion of Biomass Volatiles (009) with Fossil Fuels, indicatively Coal (009 _A ), or with a Modified Power Production Unit of Simple or Combined Cycle (A.6.G) or (A.6.1) with Pure or Mixed Combustion of Biomass Volatiles (009) with Liquid or Gaseous Fossil Fuels, indicatively with Natural Gas (NG) (009 _B ), and on the other hand in parallel for the production in great quantities of Pyrolytic Activated Carbon (008 _A ) and (008 _B ), which constitutes Binding of Atmospheric Carbon Dioxide, i.e. Negative Carbon Dioxide Emissions, whereas the Power Generation System (A.E.i) in combination with the Innovative Pyrolysis-Carbonation Unit as above, are characterized by the fact that they produce Electrical Energy not only without Carbon Dioxide Emissions, but on the contrary with Negative Carbon Dioxide Emissions, up to more than double the quantities compared with the Carbon Dioxide Emissions by an equivalent Electricity Production Unit Fossil-Fuels-Fired, and where the Pyrolytic Activated Carbon (008 _A ) and (008 _b ) is characterized also by the fact that it is foreseen for permanent storage, indicatively as a perfect Soil Conditioner in the Agriculture, where it more than doubles the agricultural production, and where the above mentioned Power Generation System (A.E.i) is characterized by the fact that it consists of the following Components and Alternatives of the Innovative Pyrolysis-Carbonation Unit (A.4.10) and the Power Generation System (A.E.i), namely:

A. Alternative Versions of the Innovative Pyrolysis-Carbonation Unit (A.4.10)

A.O. Pyrolysis-Carbonation Unit (A.4.10) of Biomass Under Pressure, of General Form with Fixed or Rotating Chambers and Sub-Chambers,

A.l. Pyrolysis-Carbonation Unit (A.4.1A) of Biomass Under Pressure, of One Passage of Cleaning of the Biomass Volatiles, with Fixed Chambers and Sub-Chambers,

A.2. Pyrolysis-Carbonation Unit (A.4.1E) of Biomass Under Pressure, of One Passage of Cleaning of the Biomass Volatiles, with Fixed Chambers and Rotating Sub-Chambers, A.3. Pyrolysis-Carbonation Unit (A.4.1FI) = (A.4.1FIA) or (A.4.1FIE) of the Biomass Under Pressure, of One Passage of Cleaning of the Biomass Volatiles, with Integration into one Combined Pair of Pyrolysis-Carbonation of Chambers and Sub-Chambers,

A.4. Pyrolysis-Carbonation Unit (A.4.GO) or (A.4.GA) or (A.4.1Έ) or (A.4.GH) of Biomass, Under Atmospheric Pressure, with Multiple Passages for Purification of Biomass Volatiles, B. Power Generation Systems of Negative CQ2 Emissions (A.E.i) with Negative CQ2 Emissions Units

B.l. The Power Generation System (A.E.I) as a Combination of a Unit (A.5.1) with a Pyrolysis- Carbonation Unit (A.4.10) or (A.4.1A) Under Pressure of 20-40Bar, of One Passage of Cleaning of the Biomass Volatiles,

B.2. The Power Generation System (A.E.2) as a Combination of a Unit (A.5.1) with a Pyrolysis- Carbonation Unit (A.4.10) or (A.4.1E) Under Pressure of 20-40Bar, of One Passage of Cleaning of the Biomass Volatiles,

B.3. The Power Generation System (A.E.3) as a Combination of a Unit (A.6.1) or (A.6.G) with a Pyrolysis-Carbonation Unit (A.4.10) or (A.4.1A) or (A.4.1E) Under Pressure, of One Passage of Cleaning of the Biomass Volatiles,

B.4. The Power Generation System (A.E.4) as a Combination of a Unit (A.5.1) or (A.6.1) or (A.6.G) with a Pyrolysis-Carbonation Unit (A.4.10) or (A.4.1H) Under Pressure of 20-40Bar of One Passage of Cleaning of the Biomass Volatiles,

B.5. The Power Generation System (A.E.5) as a Combination of a Unit (A.5.1) or (A.6.1) or (A.6.1') with a Pyrolysis-Carbonation Unit (A.4.1'0) or (A.4.GA) or (A.4.1Έ) or (A.4.GH), of Atmospheric Pressure,

Namely:

A. Alternative Versions of the Innovative Pyrolysis-Carbonation Unit (A.4.10), hereinafter Pyrolysis-Carbonation Unit (A.4.10), is characterized in that it consists of an Innovative Pyrolysis-Carbonation Unit (A.4.10) of General Form, Under Pressure, of Biomass (A.2.2 _A ) and (A.2.1 _a ), for the production of Clean Volatile Biomass Volatiles (009) and Pyrolytic Activated Carbon (008 _A ) and (008 _B ), which is sold for use as a Soil Conditioner in Agriculture, characterized in that it is carried out under Pressure, indicatively of 20-40Bar, in Fixed or Rotating Chambers (001A _OA ), (001A _o ) and (001A _O B) and Sub-Chambers (002A _OA ), (002A _o ) and (002A _O B) of Pyrolysis-Carbonation, indicatively with Internal Filling, Stirring Forwards - Backwards and Discharge System of the Biomass and the Pyrolytic Activated Carbon via Two-Way Screws or Helical Spiral Crowns (041 _oa ) or (041' _OA ), so there are very significant advantages both for the whole Pyrolysis-Carbonation process of the Biomass (A.2.2) and (A.2.1), as well as for the Power Generation System (A.E.i), as is analyzed in the Detailed Description below,

A.O. A Pyrolysis-Carbonation Unit (A.4.10) of Biomass Under Pressure, of General Form with Fixed or Rotating Chambers and Sub-Chambers,

In the following Pyrolysis-Carbonation Unit (A.4.10), which is characterized by the fact that it constitutes the general form of a Pyrolysis-Carbonation Unit Under Pressure, which includes all variants of the implementation of the principle of pyrolysis-carbonation under pressure, in contrast to the current state of the art where the pyrolysis-carbonation is carried out under atmospheric pressure, with indicative variations as follows, where on the one hand it produces pyrolytic Biomass Volatiles (009) almost 100% free from of their Harmful Components (A.10.1) for the Boilers (012) of the Steam-Electric Units (A.5.1) and for the Gas Turbines (A.6.1 _a ) of the Single or Combined Cycle Power Plants (A.6.G) or (A.6.1) in Power Generation Systems (A.E.i), as follows, where the Clean Biomass Volatiles (009) are intended indicatively for Generation of Electricity not only without Carbon Dioxide Emissions but on the contrary with the binding and permanent storage in the ground of up to more than double the amount of Atmospheric Carbon Dioxide, i.e. with Negative Carbon Dioxide Emissions, in relation to the relative Carbon Dioxide Emissions of corresponding Power Generation Systems fossil-fuels-fired, and on the other hand also produces Pyrolytic Activated Carbon (008 _A ) and (008 _B ) which constitutes the binding of the Atmospheric Carbon Dioxide and which is forwarded indicatively for use as a Soil Conditioner in Agriculture, where it more than doubles agricultural production, and where it is combined like all of its indicative variants as follows,

A.l. A Pyrolysis-Carbonation Unit (A.4.1A) of Biomass Under Pressure, of One Passage of Cleaning of the Biomass Volatiles, with Fixed Chambers and Sub-Chambers,

In the following Pyrolysis-Carbonation Unit (A.4.1A), which is characterized in that it consists of an innovative Pyrolysis-Carbonation Unit (A.4.1A) of Biomass (A.2.2) and (A.2.1) for the production of Clean Biomass Volatiles (009) and Pyrolytic Activated Carbon (008 _A ) and (008 _b ), which is forwarded indicatively for use as a Soil Conditioner in Agriculture, which is characterized in that it is also carried out under Pressure, indicatively 20-40Bar, in Fixed Chambers (001A _aa ), (001A _a ) and (001A _ab ) and Sub-Chambers (002A _aa ), (002A _a ) and (002A _ab ), of Drying-Preheating, Pyrolysis-Carbonation and Cooling-Heat-Exchanging respectively, with Internal Filling, Stirring Forwards-Backwards and Discharging System of the Biomass and the Pyrolytic Activated Carbon via the Two-Way Screw (041 _A ), thus resulting in very significant advantages both for the whole Pyrolysis-Carbonation process of the Biomass (A.2.2) and (A.2.1), as well as for the Power Generation System (A.E.i), as is analyzed in the Detailed Description below,

A.2. A Pyrolysis-Carbonation Unit (A.4.1E) of Biomass Under Pressure, of One Passage of Cleaning of the Biomass Volatiles, with Fixed Chambers and Rotating Sub-Chambers,

In the following Pyrolysis-Carbonation Unit (A.4.1E), which is characterized in that it consists of an innovative Pyrolysis-Carbonation Unit (A.4.1E) of Biomass (A.2.2) and (A.2.1) for the production of Clean Biomass Volatiles (009) and Pyrolytic Activated Carbon (008 _A ) and (008 _b ), as above, characterized in that it is also carried out under pressure, indicatively 20- 40Bar, in Fixed Chambers (001A _ea ), (001A _e ) and (001A _EB ) and Rotating Sub-Chambers (002A _ea ), (002 A _e ) and (002A _EB ), of Drying-Preheating, Pyrolysis-Carbonation and Cooling- Heat-Exchanging respectively, with Internal Filling, Stirring Forwards-Backwards and Discharging System of the Biomass and the Pyrolytic Activated Carbon via the Two-Way Internal Helical Spiral Crown (04G _A ), thus resulting in very significant advantages both for the whole pyrolysis-carbonation process of the Biomass (A.2.2) and (A.2.1) , as well as for the Power Generation System (A.E.i), as is analyzed in the Detailed Description below, A.3. A Pyrolysis-Carbonation Unit (A.4.1H) = (A.4.1HA) or (A.4.1HE) of Biomass Under Pressure, of One Passage of Cleaning of the Biomass Volatiles, of Integration into a Combined Pair of Pyrolysis-Carbonation Chambers and Sub-Chambers, hereinafter Pyrolysis-Carbonation Unit ( A.4.1HA) or (A.4.1FIE), characterized in that alternatively instead of three separate pairs of Chambers and Sub-Chambers (001A _aa ) - (002A _m ), (001A _a ) - (002A _a ) and (001A _ab ) - (002A _ab ) or (001A _ea ) - (002A _K ), (001A _e ) - (002A _E ) and (001A _eb ) - (002A _EB ) of Drying- Preheating, Pyrolysis-Carbonation and Cooling-Pleat- Exchanging respectively, is effected the merge of the three separate pairs of Chambers and Sub-Chambers as above in a Composite Pair of Chambers and Sub-Chambers (001AA) - (002AA) or (001AE) - (002AE) which is characterized by the fact that it begins to function as a pair of Chambers and Sub-Chambers (001AA _aa ) - (002AA _aa ) or (001AE _ea ) - (002AE _ea ) of Drying-Preheating of Biomass (A.2.2) and (A.2.1) and then after the end of the Drying- Preheating process by alternating the Gas-Ducts (022) to Gas-Ducts (010) and (015) - (015A) is converted into a pair of Chambers and Sub-Chambers (001AA _a ) - (002AA _a ) or (001AE _E ) - (002AE _e ) of Pyrolysis-Carbonation and then after the end of the pyrolysis-carbonation process by alternating the Gas-Ducts (010) and (015) - (015A) to Gas-Ducts (019) is converted into a pair of Chambers and Sub-Chambers (001AA _ab ) - (002AA _ab ) or (001AE _EB ) - (002AE _eb ) of Cooling-Fleat-Exchanging of the produced Pyrolytic Activated Carbon (008 _A ) and (008 _b ), as analyzed in the Detailed Description below,

A.4. A Pyrolysis-carbonation Unit (A.4.1'0) or (A.4.1Ά) or (A.4.1Έ) or (A.4.1ΉA) or (A.4.1ΉE) of Biomass, Under Atmospheric Pressure, of Multiple Passanges for the Purification of the Biomass Volatiles, hereinafter Pyrolysis-Carbonation Unit (A.4.1'0) or (A.4.GA) or (A.4.1Έ) or (A.4.1ΉA) or (A.4.GHE) respectively, where each is characterized from the fact that it operates under Atmospheric Pressure, for the rest as the corresponding Pyrolysis-Carbonation Unit under Pressure above, which is characterized by the fact that for the production of Clean Biomass Volatiles (009) on the one hand requires the Double, Triple or Multiple Passage through the Pyrolytic Activated Carbon of the respective Spare Sub-Chambers (002A' _ab ) or (002E' _eb ) or (002AA' _ab ) or (002EA' _eb ) and on the other hand that for the Single or Combined Cycle Power Generation Unit (A.6.G) or (A.6.1) a small modification is required for its conversion to Pure or Mixed Combustion of Biomass Volatiles (009), which consists in the addition of the Compressor (A.6.1 _z ) as well as of the After-Combustion Chamber (A.6.1 _E ), as analyzed in the Detailed Description below, B. Negative C02 Emissions Power Generation Systems (A.E.i)

B.l. The Power Generation System (A.E.l) as a Combination of a Unit (A.5.1) with a Pyrolysis-

Carbonation Unit (A.4.1A) Under Pressure of 20-40Bar, of one Cleaning Passage, hereinafter Power Generation System (A.E.l), which is characterized, however, in that it consists of a combination of a Modified Steam Power Plant (A.5.1) with Pure or Mixed Firing of Biomass Volatiles (009) with Fossil Fuels, indicatively Coal (009 _A ) and an innovative Pyrolysis-Carbonation Unit (A.4.1A) of Biomass (A.2.2) and (A.2.1) for the production of Clean Biomass Volatiles (009) and Pyrolytic Activated Carbon (008 _A ) and (008 _s ) , which is promoted for use as a Soil Conditioner in Agriculture, characterized in that the Pyrolysis- Carbonation of Biomass (A.2.2) and (A.2.1) is carried out under Pressure, indicatively 20- 40Bar, in Fixed Chambers ( 001A _aa ), (001A _a ) and (001A _ab ) and fixed Sub-Chambers (002A _aa ), (002A _a ) and (002A _ab ) of Drying-Preheating, Pyrolysis-Carbonation and Cooling-Heat- Exchanging respectively, which is created by the released Biomass Volatiles (009), thus resulting also into very significant advantages for both the whole process of Pyrolysis- Carbonation of Biomass (A.2.2) and (A.2.1), as well as for the Power Generation, as analyzed in the Detailed Description below,

B.2. The Power Generation System (A.E.2) as a Combination of a Unit (A.5.1) with Pyrolysis- Carbonation Unit (A.4.1E) Under Pressure of 20-40Bar, of one Cleaning Passage hereinafter Power Generation System (A.E.2), such as the Power Generation System (A.E.l) above, which is characterized, however, in that it consists of a combination of a Modified Steam Power Plant (A.5.1) as above and an innovative Pyrolysis-Carbonation Unit (A.4.1E) of Biomass (A.2.2) and (A.2.1) for the production of Clean Biomass Volatiles (009) and Pyrolytic Activated Carbon (008 _A ) and (008 _B ), as above, which is characterized by the fact that it is also carried out under Pressure, indicatively 20-40Bar, in Fixed Chambers (001A _ea ), (001A _e ) and (OOIAEB) and Rotating Sub-Chambers (002A _EL ), (002A _e ) and (002A _EB ) of Drying-Preheating, Pyrolysis-Carbonation and Cooiing-Heat-Exchanging respectively, so there are also very important advantages for the whole process of Pyrolysis-Carbonation of Biomass (A.2.2) and (A.2.1), as well as for the Power Generation System (A.E.2 ), as analyzed in the Detailed Description below,

B.3. The Power Generation System (A.E.3) as a Combination of a Unit (A.6.1) or (A.6.G) with a Pyrolysis-Carbonation Unit (A.4.1A) or (A.4.1E) Under Pressure, of one Cleaning Passage, hereinafter referred to as the Power Generation System (A.E.3), such as the Power Generation System (A.E.l) and (A.E.2) above, which is, however, characterized in that it consists of a combination of a Modified Simple or Combined Cycle Power Generation Unit (A.6.G) or (A.6.1) with Pure or Mixed Firing of Biomass Volatiles (009) with Fossil Fuels, indicatively of Natural Gas (009 _B ) and an innovative Pyrolysis-Carbonation Unit (A.4.1A) or (A.4.1E) Under Pressure, indicatively 20-40Bar, for the production of Clean Biomass Volatiles (009) and Pyrolytic Activated Carbon (008 _A ) and (008 _B ), resulting in multiple advantages for both the whole Pyrolysis-Carbonation process of the Biomass (A.2.2) and (A.2.1) as well as for the Power Generation, as analyzed in the Detailed Description below,

B.4. The Power Generation System (A.E.4H) as a Combination of a Unit (A.5.1) or (A.6.1) or A.6.1') with a Pyrolysis-Carbonation Unit (A.4.1HA) or (A.4.1HE) Under Pressure of 20-40 Bar, of one Cleaning Passage hereinafter referred to as the Power Generation System (A.E.4H), such as the Power Generation System (A.E.l), (A.E.2) and (A.E.3) above, which is, however, characterized in that it consists of a combination of a Modified Steam Power Plant (A.5.1) or a Modified Simple or Combined Cycle Power Plant (A.6.1') or (A.6.1). respectively and an innovative Pyrolysis-Carbonation Unit (A.4.1HA) or (A.4.1HE) Under Pressure, indicatively 20-40Bar, for the production of Clean Biomass Volatiles (009) and Pyrolytic Activated Carbon (008 _A ) and (008 _b ), SO there result multiple advantages for both the whole Pyrolysis-Carbonation process of Biomass (A.2.2) and (A.2.1) as well as for the Power Generation, as analyzed in the Detailed Description below,

B.5. The Power Plant System (A.E.5) as a combination of a Unit (A.5.1) or (A.6.1) or A.6.G) with a Pyrolysis-Carbonation Unit (A.4.1'0) or (A.4.1Ά) or (A.4.1Έ) or (A.4.1ΉA) or (A.4.GHE), of Atmospheric Pressure, hereinafter referred to as the Power Generation System (A.E.5), such as the Power Generation System (A.E.l), (A.E.2), (A.E.3) and (A.E.4) above, which is, however, characterized in that it consists of a combination of a Modified Steam Power Plant (A.5.1) or a Modified Simple or Combined Cycle Power Plant (A.6.1 ¹ ) or (A.6.1) respectively and an innovative Carbonation Unit (A.4.1'0) or (A.4.GA) or (A.4.1Έ) or (A.4.GHA) or (A.4.GHE) of Biomass (A.2.2) and (A. 2.1) under Atmospheric Pressure, characterized in that for the production of Clean Biomass Volatiles (009) on the one hand requires the Double, Triple or Multiple Passage of the Biomass Volatiles through the Pyrolytic Activated Carbon of the respective Spare Sub-Chambers (002A' _ab ) or (002A' _EB ) or (002AA' _ab ) or(002AE' _EB ) respectively and on the other hand, the Simple or Combined Cycle Power Unit (A.6.1 ¹ ) or (A.6.1) needs a small modification to be converted into Pure or Mixed Firing of Biomass Volatiles (009), which consists of the addition of the Compressor (A.6.1 _z ) as well as the After-Combustion Chamber (A.6.1 _E ), as analyzed in the Detailed Description below,

E.2. DETAILED DESCRIPTION OF THE CLIMATE CHANGE DEFENCE SYSTEM WITH NEGATIVE CARBON DIOXIDE EMISSIONS ELECTRICITY PRODUCTION UNITS The Present Invention is characterized by the fact that it consists of the Negative C02 Emissions Units i.e. an Electric Power Generation System (A.E.i), where i = 1 to 5, is the index of the Alternative Versions of the Power Generation System (A.E.i), which consists in a Combination of an Innovative Pyrolysis-Carbonation Unit Under Pressure (A.4.10) or (A.4.1A) or (A.4.1E) or (A.4.1HA) or (A.4.1HE) or even and under atmospheric pressure (A.4.1'0) or (A.4.1Ά) or (A.4.1Έ) or (A.4.1ΉA) or (A.4.1ΉE) of Biomass (A.2.2) and ( A.2.1), for the production on the one hand of Clean Biomass Volatiles (009) for Electricity Generation, in combination with either a Modified Steam Power Plant (A.5.1) with Pure or Mixed Combustion of Biomass Volatiles (009) with Fossil Fuels, indicatively Coal (009 _A ), or with a Modified Simple or Combined Cycle Power Plant (A.6.1 ¹ ) or (A.6.1) with Pure or Mixed Combustion of Biomass Volatiles (009) with Liquid or Gaseous Fossil Fuels, indicatively with Natural Gas (NG) (009 _B ), and in parallel for the production of large quantities of Pyrolytic Activated Carbon (008 _A ) and (008 _B ), which is destined for permanent sequestration, indicatively as an excellent Soil Conditioner in the Agriculture, where it more than doubles the agricultural production, where the above Electricity Production System (A.E.i) is characterized by that it consists from the following Components and Alternative Versions of the Innovative Pyrolysis-Carbonation Unit and of the Electricity Production System (A.E.i), which are described in detail below, namely: A. Alternative Versions of the Innovative Pyrolysis-Carbonation Unit (A.4.10)

A.O. Pyrolysis-Carbonation Unit (A.4.10) of Biomass Under Pressure, of General Form with Fixed or Rotating Chambers and Sub-Chambers,

A.l. Pyrolysis-Carbonation Unit (A.4.1A) of Biomass Under Pressure, of One Passage of Cleaning of the Biomass Volatiles, with Fixed Chambers and Sub-Chambers,

A.2. Pyrolysis-Carbonation Unit (A.4. IE) of Biomass Under Pressure, of One Passage of Cleaning of the Biomass Volatiles, with Fixed Chambers and Rotating Sub-Chambers ,

A.3. Pyrolysis-Carbonation Unit (A.4.1H) = (A.4.1FIA) or (A.4.1HE) of the Biomass Under Pressure, of One Passage of Cleaning of the Biomass Volatiles, with Integration into one Combined Pair of Pyrolysis-Carbonation Chambers and Sub-Chambers,

A.4. Pyrolysis-Carbonation Unit (A.4.1'0) or (A.4.1Ά) or (A.4.1Έ) or (A.4. l'H) of Biomass, Under Atmospheric Pressure, with Multiple Passages for Purification of Biomass Volatiles,

B. Power Generation Systems of Negative CQ2 Emissions (A.E.i) of Negative CQ2 Emissions Units

B.l. The Power Generation System (A.E.I) a Combination of a Unit (A.5.1) with a Pyrolysis- Carbonation Unit (A.4.10) or (A.4.1A) Under Pressure of 20-40Bar, of One Passage of Purification of the Biomass Volatiles,

B.2. The Power Generation System (A.E.2) a Combination of a Unit (A.5.1) with a Pyrolysis- Carbonation Unit (A.4.10) or (A.4. IE) Under Pressure of 20-40Bar, of One Passage of Purification of the Biomass Volatiles,

B.3. The Power Generation System (A.E.3) a Combination of a Unit (A.6.1) or (A.6.1 ') with a Pyrolysis-Carbonation Unit (A.4.10) or (A.4.1A) or (A.4. IE) Under Pressure, of One Passage of Purification of the Biomass Volatiles,

B.4. The Power Generation System (A.E.4) a Combination of a Unit (A.5.1) or (A.6.1) or (A.6.1 ¹ ) with a Pyrolysis-Carbonation Unit (A.4.10) or (A.4.1H) Under Pressure of 20 -40Bar of One Passage of Purification of the Biomass Volatiles,

B.5. The Power Generation System (A.E.5) a Combination of a Unit (A.5.1) or (A.6.1) or (A.6.1 ¹ ) with a Pyrolysis-Carbonation Unit (A.4.1'0) or (A.4.GA) or (A.4.GE) or (A.4.1Ή), of Atmospheric Pressure,

Namely:

A. Alternative Versions of the Pyrolysis-Carbonation Innovative Unit (A.4.10)

A.O. A Pyrolysis-Carbonation Unit (A.4.10) of Biomass, Under Pressure, of General Form, with Fixed or Rotating Chambers and Sub-Chambers, Hereinafter Pyrolysis-Carbonation Unit (A.4.10), characterized in that it consists of an Innovative Pyrolysis-Carbonation Unit (A.4.10) Under Pressure, of General Form, of Biomass (A.2.2) and (A.2.1 ), for the production of Clean Biomass Volatiles (009) free from almost 100% of their- Harmful Components < (A.10.1) for the Boilers (012) of the Steam Power Plants (A.5.1) and for the Gas Turbines (A.6.1 _A ) of Simple or Combined Cycle Power Units (A.6.G) or (A.6.1) in Power Generation Systems (A.E.i), as follows, where the Clean Biomass Volatiles (009) are intended indicatively for Power Generation not only without Carbon Dioxide Emissions but on the contrary with binding and permanent sequestration in the soil of up to more than twice the amount of Atmospheric Carbon Dioxide, i.e. with Negative Emissions of Carbon Dioxide, in relation to the respective Emissions of Carbon Dioxide of equivalent Fossil Fuels-Fired Electricity Production Systems, and on the other hand produces in parallel Pyrolytic Activated Carbon (008 _a ) and (008 _B ), which is the binding of Atmospheric Carbon Dioxide which is promoted for use as a Soil Conditioner in Agriculture, where it more than doubles the agricultural production,

Where the Pyrolysis-Carbonation Unit (A.4.10) is characterized by the fact that the Pyrolysis- Carbonation of Biomass is carried out under Pressure, indicatively 20-40Bar, in Fixed or Rotating Chambers and Sub-Chambers, of Drying-Preheating, not only without consumption of thermal energy, but instead is carried out with the production of thermal energy, which also increases the degree of efficiency of the cooperating Power Generation System,

Where the Pyrolysis-Carbonation Unit (A.4.10) is also characterized by the fact that in collaboration with the Negative Carbon Dioxide Emissions of Power Generation Systems (A.E.i) gives Technically and Economically Sustainable Solutions to the main Problems related to the Production of Energy through Negative Carbon Dioxide Emissions, the Degradation of the Environment and the Tackling of the Risk of Climate Change, which the current state of the art fails to address, as well as producing very significant benefits for the whole Pyrolysis- Carbonation Process of Biomass (A.2.2) and (A.2.1), as well as for the Power Generation System (A.E.i), as analyzed in Chapter C "Advantages of the Present Invention in contrast to the Current State of the Art", where the Pyrolysis-Carbonation is carried out under atmospheric pressure with the consumption of external thermal energy, thus worsening the efficiency of the cooperating Power Generation System, and does not present the significant advantages of Pyrolysis-Carbonation under pressure,

Where the Innovative Pyrolysis-Carbonation Unit (A.4.10) of General Form is characterized by the fact that it consists of the following three Cooperating Constituent Parts, namely:

- The Drying-Preheating Sub-Unit (A.4.1 _oa ), consisting of the Drying-Preheating Chambers and Sub-Chambers Pairs (001A _OA ) - (002A _oa ),

- The Pyrolysis-Carbonation Sub-Unit (A.4.1 ₀ ), consisting of the Pyrolysis-Carbonation Chambers and Sub-Chambers Pairs (001A _o ) - (002A _o ), - The Cooling-Heat-Exchanging Sub-Unit (A.4.1 _0B ), consisting of the Cooling-Heat-Exchanging

Chambers and Sub-Chambers Pairs (001A _Ob ) - (002A _O B),

As described in the following, namely:

- The Drying-Preheating Sub-Unit (A.4.1 _nA ), which is characterized by the fact that: Where the Drying-Preheating Sub-Unit (A.4.1 _oa ), is also characterized in that it consists of the pairs ' of Drying-Preheating Chambers and Sub-Chambers ^* (001Ab _A ) - (002A _OA ) of'Biomass (N.2.2)· and (A.2.1), with fixed or rotating cylindrical Drying-Preheating Chambers and Sub- Chambers, horizontal, inclined or vertical or of other form, respectively,

Where the Drying-Preheating Sub-Unit (A.4.1 _oa ) is characterized by the fact that it consists of the Pairs of Drying-Preheating Chambers and Sub-Chambers (001A _oa ) - (002A _OA ), which are supplied with the Biomass (A.2.0) of the Initial Semi-Outdoor Pre-Drying through the Loading-Unloading System (A.7.1), through the Double Isolation Valves (039 _A ), where after the Drying-Preheating they supply with the Dry and Preheated Biomass (A.2.2 _a ) and (A.2.1 _A ) the Pyrolysis-Carbonation Sub-Unit (A.4.1 ₀ ), which consists of the Pyrolysis-Carbonation Chambers and Sub-Chambers Pairs (001A _o ) - (002A _o ) via the Double Isolation Valves (040 _A ) - (039), where it after Pyrolysis-Carbonation supplies the produced Pyrolytic Activated Carbon (008 _a ) and (008 _B ) to the Cooling-Heat-Exchanging Sub-Unit (A.4.1 _0B ), which consists of the Pairs of Cooling-Heat-Exchanging Chambers and Sub-Chambers (001A _O B)-(002A _O B) through the Double Isolation Valves (040) - (039 _B ) and where from the Cooling-Heat-Exchanging Sub- Unit (A.4.1 _ob ), after the Cooling of the Pyrolytic Activated Carbon (008 _A ) and (008 _B ) through the Heat Exchanging with the Preheating of the Feed-Water (012 _A ) of the Boiler (012) of the Steam-Electric Unit (A.5.1) ) or of the Boiler (012 _B ) of the Combined Cycle Unit (A.6.1), the Pyrolytic Activated Carbon (008 _A ) and (008 _B ) exits through the Double Isolation Valves (040 _B ) and is promoted for use as a Soil Conditioner,

Wherein the Drying-Preheating Sub-Unit (A.4.1 _0A ) is characterized in that it consists of the Drying-Preheating Chambers and Sub-Chambers Pairs (001A _OA )-(002A _OA ), and then forms part of the Drying-Preheating Sub-System (A.E.1.3 ₀ ), which is characterized by the fact that it is a Component of the Power Generation Systems (A.E.i), where i = 1 to 5 is the Index of the Versions of the Power Plants with Negative Carbon Dioxide Emissions, which are implemented through the Clean Biomass Volatiles (009), which are produced by the innovative Pyrolysis-Carbonation Unit (A.4.10) of General form, of which the Drying- Preheating Sub-Unit (A.4.1 _0a ) is part,

Where the Drying-Preheating Sub-Unit (A.4.1 _0a ) is characterized by the fact that it performs Drying in the Second Stage (A.3.1) with the available Hot Flue Gases (A.1.4) from the entrance of the Chimney (A.1.5) of the Boiler (012 ) of the cooperating Steam Power Unit (A.5.1) or from the entrance of the Chimney (A.1.5) of the Boiler (012 _B ) of the cooperating Combined Cycle Unit (A.6.1), which remove the last 20% of the humidity and make a corresponding preheating of the Dry Biomass (A.2.2 _a ) and (A.2.1 _a ), where occurs a significant overall improvement of the efficiency of the respective Power Generation System (A.E.i) in average indicatively over 10%, in contrast to the degree of efficiency of electricity generation through conventional Pyrolysis-Carbonation, which is inferior than the one of the Power Generation System (A.E.i),

Contrary to the current state of the art where on the one hand the Heat of the Hot Exhaust Gases (A.1.4) is either discharged unused through the Chimneys (A.1.5) in the environment or is eliminated by cooling in the Water Scrubbers in the Desulphurization Systems, which are abolished in the collaborating (A.E.i), because the Sulfur Compounds are fully retained by the Pyrolytic Activated Carbon Filter (008 _A ) and (008 _B ), And on the other hand, with the current state of the art, useful heat is consumed by burning part or all of the Thin Biomass (A.2.1) or part of the Woody Biomass (A.2.2) for evaporation of the moisture content resulting in a poor degree of efficiency, where the Thin Biomass (A.2.1) even when pelleted, is not intended for drying and pyrolysis-carbonation for the production of Fine Pyrolytic Activated Carbon (008 _B ), but only for combustion and heat production, as above,

For the rest, it is characterized by the fact that it participates in the cooperating Power Generation Systems (A.E.i) of the Negative C02 Emissions Units, as above,

- The Sub-Units of Pyrolysis-Carbonation (A.4.1 _n ) and of Cooling-Fleat-Exchanging (A.4.1 _nR ), which are characterized in that: Where the Pyrolysis-Carbonation Sub-Unit (A.4.1 ₀ ) is characterized by the fact that it consists of the Pairs of the Pyrolysis-Carbonation Chambers and Sub-Chambers (001A _o ) - (002Ao) and the Cooling-Heat-Exchanging Sub-Unit (A.4.1 ₀ B) is characterized by the fact that it consists of the Pairs of Cooling-Heat-Exchanging Chambers and Sub-Chambers (001A _O B) - (002A _OB ) respectively, then both are characterized by the fact that they constitute the Pyrolysis-Carbonation Sub-System (A.E.I.4 ₀ ), which is characterized by the fact that it is a component of the Power Generation Systems (A.E.i), where i = 1 to 5 is the Index of the Versions of the Negative Carbon Dioxide Emissions Power Plants, and wherein the Sub-Units of Pyrolysis-Carbonation (A.4.1 ₀ ) and Cooling-Heat-Exchanging (A.4.1 _ob ) respectively are characterized in that they consist of the following, namely:

Where Pyrolysis-Carbonation (A.4.1 ₀ ) and Cooling-Heat-Exchanging (A.4.1 ₀ B) Sub-Units, respectively, are characterized in that they consist of Pairs of fixed or rotating Chambers and Sub-Chambers of Pyrolysis-Carbonation (001A _o )-(002A _o ) and Cooling-Heat-Exchanging (001A _O B)-(002AOB) respectively, in a form of indicatively cylindrical, horizontal or inclined or vertical or other form, where the Pyrolysis-Carbonation of Biomass (A.2.2 _A ) and (A.2 ,1 _A ) and Cooling-Heat-Exchanging of Pyrolytic Activated Carbon (008 _A ) and (008 _B ) are taking place, respectively,

Where the Pyrolysis-Carbonation process inside the Sub-Chambers (002A _o ) is carried out under Pressure, indicatively 20-40Bar, while all the other Chambers (001A _o ), (001A _O B) and the Sub-Chambers (002A _ob ) operate under atmospheric pressure in the Pyrolysis- Carbonation process of a Biomass Volatiles (009) Purification of One Passage, while in the process of multiple Biomass Volatiles (009) Purification Passages, then the Sub-Chambers (002A _O B) of the Cooling-Heat-Exchanging also operate under the same pressure as the Sub- Chambers (002A _o ), indicatively 20-40Bar, where the Clean Biomass Volatiles (009) and at the same time the Pyrolytic Activated Carbon (008 _A ) and (008 _B ) are produced,

Where the Cooling-Heat-Exchanging Sub-Unit (A.4.1 ₀ B) is characterized by the fact that the Pairs of Cooling-Heat-Exchanging Chambers and Sub-Chambers (001A _OB )-(002A _O B) of the Pyrolytic Activated Carbon (008 _A ) and (008 _B ), are cooling the superheated Pyrolytic Activated Carbon (008 _A ) and (008 _B ) by exchanging heat and preheating the Feed-Water (012 _A ) of the Boiler (012) or of the Exhaust Boiler (012 _B ), thus further improving the efficiency of the cooperating Power Generation System, Where the Pyrolysis-Carbonation Sub-Unit (A.4.1 ₀ ) is characterized in that the Pyrolysis- Carbonation of Biomass is carried out under Pressure, indicatively 20-40Bar, in the Pyrolysis- Carbonation Chambers and Sub-Chambers (001A _o )-(002A _o ) respectively, not only without consumption of thermal energy, but instead is carried out with the production of thermal energy, which increases the efficiency of the cooperating Power Generation System, as well as is carried out with the production of very important advantages for the whole process of Pyrolysis-Carbonation of Biomass (A.2.2) and (A.2.1), as well as for the Power Generation System (A.E.i), as analyzed in Chapter C "Advantages of the Present Invention compared to the current state of the art" above,

In contrast to the current state of the art where the Pyrolysis-Carbonation is carried out under atmospheric pressure, with consumption of external thermal energy, thus worsening the efficiency of the cooperating Power Generation System, and does not present the significant advantages of Pyrolysis-Carbonation Under Pressure, as they are analyzed in detail above in Chapter C, where it fails to provide the solutions and advantages of Pyrolysis- Carbonation Under Pressure as above, and leads to devaluation and early dismantling of more than 5,OOOGW Fossil Fuel-Fired Power Plants, which with a small conversion and in combination with the Innovative Pyrolysis-Carbonation Units (A.4.10) are converted into Power Plants with Negative Carbon Dioxide Emissions, with all the advantages as above in Chapter C,

Where the Cooling-Heat-Exchanging Sub-Unit (A.4.1 _0B ) is characterized by the fact that the Pairs of Cooling-Heat-Exchanging Chambers and Sub-Chambers (001A _O B) - (002A _O B) of the Pyrolytic Activated Carbon (008 _A ) and (008 _B ), they cool the superheated Pyrolytic Activated Carbon (008 _A ) and (008 _b ) by exchanging heat and preheating the Feed-Water (012 _A ) of the Boiler (012) or the Exhaust Boiler (012 _B ), thus further improving the efficiency of the cooperating Power Generation System,

For the rest, they are characterized by the fact that they participate in the collaborating Power Generation Systems (A.E.i) of the Negative C02 Emissions Units, as above,

Where the Pyrolysis-Carbonation Unit (A.4.10) is also characterized by the fact that the Chambers and Sub-Chambers as above are equipped with a Biomass (A.2.2) and (A.2.1) One Purification Passage System through the Chambers and Sub-Chambers of Drying-Preheating, Pyrolysis-Carbonation and Cooling-Heat-Exchanging (001A _OA )-(002A _oa ), (001A _O )-(002A _o ) and (001A _OB )-(002A _ob ) respectively or and corresponding Passages with Staying of Biomass (A.2.2) and (A.2.1) inside the Drying-Preheating, Pyrolysis-Carbonation and Cooling-Heat- Exchanging Chambers and Sub-Chambers (001A _OA )-(002A _OA ), (001A _o )-(002A _o ) and (001A _OB )- (002 A _ob ) respectively for longer time, stationary or by stirring back and forth indicatively through appropriate Filling, Stirring Back and Forth and Discharging Screw Systems as well as corresponding Isolation Valves,

Where the Pyrolysis-Carbonation Unit (A.4.10) is also characterized by the fact that the Chambers and Sub-Chambers as above are equipped with a suitable System of Filling, Forward-Back Stirring and Discharging of Biomass and Pyrolytic Activated Carbon indicatively through Internal Two-way Screw or Helical Spiral Crown (041 _OA ) or (041' _oa ), while is also foreseen the process of advancing in one direction from the entrance of Biomass to the exit- of the produced Pyrolytic Activated Carbon, if permitted by the characteristics of Biomass (A.2.2) and (A .2.1),

Where the innovative Pyrolysis-Carbonation Unit (A.4.10) of General Form is also characterized by the fact that it has the Electrostatic Filters (012 _E ) or Bag Filters (012 _z ), for retaining Microparticles from the cooling of Pyrolytic Activated Carbon (008 _A ) and (008 _B ) in the System of Cooling-Heat-Exchanging Chambers and Sub-Chambers (001A _O B)-(002A _O B) of the Pyrolytic Activated Carbon (008 _A ) and (008 _B ) or the Electrostatic Filters (012' _E ) or Bag Filters (012' _z ) for the retaining Microparticles from the Drying and Preheating of Biomass (A.2.2 _A ) and (A.2.1 _A ) in the Drying-Preheating Chambers and System (001A _oa ) and (002A _oa ) above,

A.l. A Pyrolysis-Carbonation Unit (A.4.1A) of Biomass, Under Pressure, of One Passage, hereinafter Pyrolysis-Carbonation Unit (A.4.1A), such as the Pyrolysis-Carbonation Unit (A.4.10) in Section A.0, which is characterized, however, by the fact that it is composed and operates as follows, i.e. by the fact that it produces on the one hand Clean Biomass Volatiles (009), which are intended indicatively for Production of Electricity without Carbon Dioxide Emissions and on the other hand Pyrolytic Activated Carbon (008 _A ) and (008 _B ), which constitutes the binding of Atmospheric Carbon Dioxide and is promoted for use as a Soil Conditioner in the Agriculture, Which is characterized by the fact that in collaboration with the Negative Carbon Dioxide Emissions Power Generation Systems (A.E.i) results in Technically and Financially Sustainable Solutions to the main problems related to the Production of Energy with Negative Carbon Dioxide Emissions, the Degradation of Environment and Tackling Climate Change Risk, which the current state of the art fails to address, such as the sustainable solutions and benefits 1- 24, which are detailed in Chapter C above,

Where the innovative Pyrolysis-Carbonation Unit (A.4.1A) is characterized in that it consists of the following three cooperating Constituent Parts, namely:

- The Drying-Preheating Sub-Unit (A.4.1 _m ), consisting of the Drying- Preheating Chambers and Sub-Chambers Pairs (001A _aa ) and (002A _aa ), - The Pyrolysis-Carbonation Sub-Unit (A.4.1 _a ), consisting of the Pyrolysis-Carbonation

Chambers and Sub-Chambers Pairs (001 A _a ) and (002A _a ),

- The Cooling-Heat-Exchanging Sub-Unit (A.4.1 _ab ), consisting of the Pairs of Cooling-Heat- Exchanging Chambers and Sub-Chambers (001A _AB ) - (002A _ab ), as described below, - The Drying-Preheating Sub-Unit (A,4.1 _aa ) which is characterized by the fact that: Where the Drying-Preheating Sub-Unit (A.4.1 _aa ) is characterized by the fact that it consists of the Pairs of Drying-Preheating Chambers and Sub-Chambers (001A _aa ) and (002A _M ), then as part of the Drying-Preheating Subsystem (A.1.1.3 _A ), which is characterized by the fact that it is a component of the Power Generation Systems (A.E.i) of the Negative C02 Emissions Units, where i = 1 to 5 is the Index of the Versions of the Power Plants with Negative Carbon Dioxide Emissions, which are implemented through firing of the Clean Biomass Volatiles (009) produced by the innovative Pyrolysis-Carbonation Unit (A.4.1A), of which the Drying- Preheating Sub-Unit (A.4,1 _AA ) is a part,

Where the Drying-Preheating Sub-Unit (A.4.1 _AA ) is characterized by the fact that it provides Drying in a Second Stage (A.3.1) with the available Hot Flue Gases (A.1.4) from the entrance of the Chimney (A.1.5) of the Boiler (012) of the cooperating Steam Power Unit (A.5.1) or from the entrance of the Chimney (A.1.5) of the Boiler (012 _B ) of the cooperating Combined Cycle Unit (A.6.1), which remove the last 20% of the humidity and make a corresponding preheating of the Dry Biomass (A.2.2A) and (A.2.1A), where occurs a significant overall improvement of the efficiency of the respective Power Generation System (A.E.i) in average indicatively over 10%, in contrast to the degree of efficiency of electricity generation through conventional Pyrolysis-Carbonation, which is correspondingly lower than the one of the Power Generation System (A.E.i),

Where the Drying-Preheating Sub-Unit (A.4.1 _M ) is characterized in that it consists of the pairs of Drying-Preheating Chambers and Sub-Chambers (001A _aa ) and (002A _M ) respectively of Biomass (A.2.2) and (A.2.1), where the Drying-Preheating Chamber (001A _aa ) is characterized by the fact that it is made of a steel alloy resistant to moderate temperatures, indicatively of a Fe, Ni, Cr alloy for operating temperatures of 250-400°C, with external Insulation (001 _E ) made of a Stone-wool Quilt of 10 cm thickness, with an inner diameter of approximately 2.7m, a steel plate thickness of 5.0mm and a length of 12.0m, for atmospheric pressure, for a Biomass Volatiles thermal power of approximately 63MW _th , which is a structural element for the conversion of a 660MW Lignite-Fired Unit into a Negative C02 Emissions Unit, as given below,

Where the Drying-Preheating Chamber (001A _aa ) is also characterized in that it contains the Drying-Preheating Sub-Chamber (002A _aa ), which is gas-tight to the Chamber (001A _aa ), with an inner diameter of approximately 2.4m, which is also made of steel alloy resistant to temperatures of 250-400°C, thickness of steel plate indicatively 5.0mm for atmospheric pressure and longer, approximately 14.0m, because it exits the Chamber (001A _aa ) by 1.0m on both sides for reasons of integration of the Inlet-Outlet Valves (039A ) and (040A) of the Biomass and the Inlet-Outlet Valves (034) and (034 ¹ ) of the Exhaust Gases (A.1.4), as well as of the System of Gearbox-Motor-Inverter (041 _z ) of the Double Direction Screw (041 _A ), outside the Casing (041 _K ) or (041' _K ) of the Chamber (001A _aa ) or of the Sub-Chamber (002A _aa ) respectively, for temperature and maintenance reasons,

Where the Drying-Preheating Sub-Chamber (002A _aa ) is characterized in that it is equipped with the Loading Arms (035 _a ) of Biomass (A.2.2) and (A.2.1) and the Unloading Arms (036 _A ) of the Dry and Preheated Biomass (A.2.2 _a ) and (A.2.1 _a ), which belong to the respective Loading-Unloading System (A.7.1), which are equipped 'with the Double Inlet and Exit Valves (039 _a ) and (040A), where the Loading Arms (035 _a ) per Sub-Chamber (002A _a ), are grouped indicatively every seven in the Collector-Silo (003A _a ), which is Loading with Biomass (A.2.2) and (A.2.1) the Drying-Preheating pairs (001A _aa ) and (002A _M ), where the Biomass (A.2.2) and (A.2.1) is fed to the Collector-Silo (003A _a ) from the Central Biomass Silo (004A) through the Feed Belts (037), of the respective Loading-Unloading System (A.7.1), while the Unloading Arms (036 _A ) remove the Dry and Preheated Biomass (A.2.2 _a ) and (A.2.1 _a ), through the Double Exit-Inlet Valves (040A)-(039), to the Feed Belt (037) of the Sub-System (A.E.1.4) of the Pyrolysis-Carbonation Pairs (001A _a ) - (002A _a ),

Where the Drying-Preheating Sub-Chamber (002A _aa ) is characterized by the fact that it is equipped internally with the System of the Two-way Screw (041 _A ) for the Process of Filling, Forth-Back Stirring and Evacuation of Biomass (A.2.2) and (A.2.1), characterized in that its Shaft (041 ₀ ) rests on the Bearings (041 _M ) at intervals through the Support Radii (041 _N ) inside the cylindrical Sub-Chamber (002A _aa ) by interrupting the continuation of the Two-Way Screw (041 _A ) at the level of the Support Radii (041 _N ) and repeat it immediately afterwards, which is set in rotation and reversal of its direction of rotation, through the Gear-Motor- Inverter System (041 _z ), placed outside the Casing (041' _K ) of the Sub-Chamber (002A _aa ), for temperature and maintenance reasons, as follows:

Where the pairs of Chambers and Sub-Chambers (001A _aa ) and (002A _M ) are characterized by the fact that both are connected via the Inlet-Outlet Valves (034) and (034') to the Gas-Ducts (022), which via the Depression Fan (023) suck and send part the hot Flue Gases (A.1.4) of the Chimney (A.1.5), as above, with temperatures of the order of 150°-180°C, from the entrance of the Chimney (A.1.5) inside the Drying Chambers and Sub-Chambers (001A _aa ) and (002A _M ), where they perform the drying and preheating of Biomass (A.2.2) and (A.2.1), from which they remove the last 20% of moisture that is left and at the same time preheat it to about 120°C , while the Exhaust Gases (A.1.4), which after the drying and preheating of the Biomass (A.2.2) and (A.2.1) have been reduced in temperature, are led by the Gas-Ducts (022) inside the Cooling Tower (018 _A ) of the cooperating Power Plant, where they are released into the atmosphere, drifting upstream by the upstream water vapor of the Cooling Tower (018 _a ),

Where the Double Valves (039 _A ) and (040 _a ) of the Loading Arms (035 _a ) and Unloading (036 _A ) of Inlet and Outlet respectively of the (002A _aa ) of transferring the Biomass (A.2.2) and (A.2.1) for drying, as well as the Double Valves (034) and (034') Inlet and Outlet respectively of the Gas-Ducts (022) are placed in the circumference of the front and rear cylindrical end of the respective cylindrical Chamber (001A _aa ) and the rest on the respective ends of the Sub- Chamber (002 A _aa ), where the latter do not obstruct the passage of the Shaft (041 ₀ ) and the Screw (041 _a ), while the respective Loading Arms (035A) are indicatively grouped every seven in the overhead Inlet Collectors (003A _a ), as above,

Where the Drying-Preheating Sub-Unit (A.4.1 _M ), is also characterized by having the Electrostatic Filters (012' _E ) or Bag Filters (012’ _z ), which are placed in an intermediate position from the Drying-Preheating Pairs (001A _aa ) and (002A _aa ) to the Cooling Tower (A.1,8 _A ), on the Gas-Duct Circuit (022) that discharges the cold Flue Gases (A.1.4) in the Cooling Tower (A.1.8 _a ), which retain the Microparticles (A.2.2 ¹ ) and (A.2.1 ¹ ) of Biomass (A.2.2) and (A.2.1), which are carried by the stream of Plot Exhaust Gases (A.1.4) in their passage through the Sub-Chamber ( 002A _aa ) during Drying - Preheating of Biomass (A.2.2) and (A.2.1), which are collected and returned to the Drying-Preheating Biomass Chain (A.2.2) and (A.2.1), on the one hand to avoid material losses and on the other hand not to burden the environment with Microparticles,

Where the innovative Pyrolysis-Carbonation Unit (A.4.1A) through the each time cooperating Power Generation System (A.E.i), is characterized by the fact that through the Sub-Systems (A.E.1.1), (A.E.1.2) and (A.E.1.3) relieves the Biomass from the high percentages of Moisture either by Natural Drying of Biomass (A.2.0) in the Semi-Outdoor Storage Sub- System (A.1.2) of the Subsystem (A.E.1.1) or by exploiting the Heat of the Hot Exhaust Gases (A.1.4) of the Chimneys (A.1.5) of the Boiler (012) of the Units (A.5.1) or of the Chimneys (A.1.5) of the Exhaust Gas Boiler (012 _B ) in the Subsystems (A.E.1.2) and (A.E.1.3), as above,

Where this way it is possible to exploit the very large quantities of heat of the Hot Exhaust Gases (A.1.4) of the Chimneys (A.1.5), of the order of 20-30% of the heat of the respective fuel, which give their heat for the Drying of Biomass (A.2.0), from humidity 30-50% levels to complete drying, as well as a corresponding preheating at 120°C, with a corresponding very serious improvement of more than 10% of the total efficiency of the cooperating Power Generation System (A.E.i), depending on the moisture content of the respective Biomass (A.2.0),

Contrary to the current state of the art where on the one hand the Heat of the Hot Exhaust Gases (A.1.4) is either discharged unused through the Chimneys (A.1.5) in the environment or is eliminated by cooling in the Water Scrubbers in the Desulphurization Systems, which are abolished in the cooperating (A.E.i), because the Sulfur Compounds are fully retained by the Pyrolytic Activated Carbon Filter (008 _A ) and (008 _B ), as above,

On the other hand, useful heat is consumed by burning part or all of the Fine Biomass (A.2,1) or part of the Woody Biomass (A.2.2) for evaporation of the moisture content resulting in a poor degree of efficiency, where the Fine Biomass (A.2.1) still and when pelleted, is not intended for drying and pyrolysis-carbonation for the production of Fine Pyrolytic Activated Carbon (008 _B ), except for combustion and heat production, as above,

Where alternatively the Drying-Preheating Sub-Unit (A.4.1 _aa ) is characterized in that the Drying-Preheating Chambers and Sub-Chambers Pairs (001A _aa ) and (002A _M ) can be constructed in the same shape and dimensions as the Pyrolysis-Carbonation Chambers and Sub-Chambers Pairs (001A _a ) and (002A _a ) and with the Pairs of Cooling-Heat-Exchanging Chambers and Sub-Chambers (001A _ab ) and (002A _ab ), for reasons of uniformity in their production and the availability of Spare Parts,

Otherwise it is characterized by the fact that it participates in the cooperating Power Generation System (A.E.I) of the respective Negative C02 Emissions Unit, as described in Paragraph B.l. "Power Generation System (A.E.I) as a Combination of Unit (A.5.1) with Pyrolysis-Carbonation Unit (A.4.1A) Under Pressure of 20-40Bar, of One Purification Passage",

- The Pyroiysis-Carbonation (A.4.1 _A ) and Cooling-Heat-Exchanging (A.4.1 _AB ) Sub-Units, reffered collectively as Pyrolysis Sub-Units (A.4.1 _{a r} ), are characterized in that: Where the Pyroiysis-Carbonation (A.4.1 _a ) and Cooling-Heat-Exchanging (A.4.1 _ab ) Sub-Units are characterized in that the Pyrolysis-Carbonation Sub-Units (A.4.1 _A ) are made up from the Pairs of Pyrolysis-Carbonation Chambers and Sub-Chambers (001A _a ) and (002A _a ) and the Cooling-Heat-Exchanging Sub-Units (A.4.1 _ab ) from the Pairs of Cooling-Heat-Exchanging Chambers and Sub-Chambers (001A _ab ) and (002A _ab ) respectively, hereinafter also Pyrolysis- Carbonation Sub-System (A.E.1.4 _a ), which is characterized by that it is a component of the Power Generation Systems (A.E.i), where i = l to 5 is the Index of Negative Carbon Dioxide Emissions Power Plants, where the Pyrolysis-Carbonation Sub-System (A.E.1.4 _a ) is characterized in that it consists of an equal number of Pairs of Chambers and Sub-Chambers of Pyrolysis-Carbonation (001A _a ) and (002A _a ) with the Pairs of Chambers and Sub-Chambers of Drying-Preheating (001A _aa ) and (002A _aa ) and of the Pairs of Chambers and Sub-Chambers of Cooling-Heat-Exchanging (001A _ab ) and (002A _ab ) of the Pyrolytic Activated Carbon (008 _A ) and (008 _b ),

Where the innovative Pyrolysis Sub-Unit (A.4.1 _a,b ) is characterized by the fact that the process of Pyrolysis-Carbonation and Cooling-Heat-Exchanging respectively are carried out in Fixed Chambers (001A _a ) and (001A _ab ) and Sub-Chambers (002A _a ) and (002A _ab ) of Pyrolysis- Carbonation and Cooling-Heat-Exchanging, respectively,

Where the Pyrolysis-Carbonation process inside the Sub-Chambers (002A _a ) is carried out under Pressure, indicatively 20-40Bar, while all the other Chambers (001A _a ) and (001A _ab ) and the Sub-Chambers (002A _ab ) operate under atmospheric pressure in the Pyrolysis- Carbonation process of One Purification Passage of Biomass Volatiles (009), while in the process of multiple Biomass Volatiles (009) Purification Passages, then the Cooling-Heat- Exchanging Sub-Chambers (002A _ab ) operate also under the same pressure as the Sub- Chambers (002A _a ), indicatively 20-40Bar,

Where the innovative Pyrolysis Sub-Unit (A.4.1 _a<b ) is characterized by the fact that the Sub- Chambers (002A _a ) and (002A _ab ) of Pyrolysis-Carbonation and Cooling-Heat-Exchanging respectively, are equipped with the Internal Filling, Stirring Forth and Backwards and Discharging System of the Biomass and the Pyrolytic Activated Carbon, via the Two-Way Screw (041 _a ), as described above, which ensures uniform distribution of heat absorption and dissipation in the mass of the Pyrolyzed Biomass (A.2.2 _a ) and (A.2.1 _a ), as well as maximization of the contact of the Biomass Volatiles (009) with the stirred mass of the simultaneously produced Pyrolytic Activated Carbon (008 _A ) and (008 _B ), in which case the advantages for the Power Generation System (A.E.i) arise, as described in detail above,

Where the of Pyrolysis Sub-Unit (A.4.1 _AjB ) is also characterized in that the Pyrolysis- Carbonation Chamber (001A _a ) and the Cooling-Heat Exchange Chamber (001A _ab ) are made of a Fe, Ni, Cr steel alloy of operating temperatures of 650-900°C but for atmospheric pressure, with inner lining of Firebricks (001 _B ) and outer Insulation (001 _E ) of Stone-wool Quilt with thickness of approximately 20cm, with an inner diameter of approximately 3.0m, thickness of steel sheet 5.0mm and length also indicatively of 12.0m, with a Biomass Volatiles Power of 63MWth, which is a Structural Element of conversion of a Coal-Fired Unit of 660MW into a Negative Carbon Dioxide Emissions Unit (A.5.1) of the same power, with firing by Biomass Volatiles (009), as in the following, Where the Pyrolysis Sub-Unit (A.4.1 _AjB ) is also characterized in that the Pyrolysis-Carbonation Sub-Chambers (002A _a ) are made of a high temperature resistant alloy steel plate, indicatively of a Superalloy type Ni, Cr, of a content range of 12-20%, for operating temperatures of the order of 650-900°C and thickness of approximately 15mm for pressures up to 60Bar, while the Cooling-Heat-Exchanging Sub-Chambers (002A _ab ), are made of steel sheets of alloy Fe, Ni, Cr for operating temperatures of the order of 650-900°C but for atmospheric pressure, a thickness of 5.0mm and a length of 14m per Sub-Chamber (002A _a ) or (002A _ab ) for each of Pyrolysis Sub-Unit (A.4.1 _a,b ) indicatively of 63MWth, which is a key Structural Element for the conversion of a 660MWe Lignite-Fired Unit to a Green Unit of Negative Carbon Dioxide Emissions, i.e. Replacement of the 16 Oil Burners of the 660MWe Unit into Biomass Volatiles (009) Burners with two Units (A.4.1A) per Burner,

Where the Pyrolysis Sub-Unit (A.4.1 _AjB ) is also characterized by the fact that the level of purification of Biomass Volatiles (009) from their Harmful Components (A.10.1) for Pyrolysis- Carbonation at 20-40Bar for a single Purification Passage is already sufficient for safe operation of the Boiler (012) or the Gas Turbine (A,6.1 _a ), indicatively over 97.5%, in which case a Second Purification Passage for the Purification of the Biomass Volatiles (009) from their Harmful Components (A.10.1) can be avoided or the number of Purification Passages can be drastically reduced for special cases,

Where the Pyrolysis Sub-Unit (A.4.1 _{A b} ) is also characterized in that the Pyrolysis-Carbonation Sub-Chamber (002A _a ) is characterized in that it is gas-tight to the Chamber (001A _a ), and where the Sub-Chamber (002A _a ) due to high operating pressure is constructed with smaller diameter, indicatively 800mm, so inside the Chambers (001A _a ) and (001A _ab ) is placed a set of 7 parallel Sub-Chambers of Pyrolysis-Carbonation (002A _a ) and Cooling-Heat-Exchanging (002A _ab ), where the first ones are connected via the Loading-Unloading Arms (035) and (036) respectively, on the one hand with the Drying-Preheating Sub-Chambers (002A _aa ) and on the other hand with the Cooling-Heat-Exchanging Sub-Chamber (002A _ab ) of the Pyrolytic Activated Carbon (008 _a ) and (008 _B ), where the Chambers and Sub-Chamber (001A _ab ) and (002 A _ab ) have the same shape as the Pyrolysis-Carbonation Chambers and Sub-Chamber (001A _a ) and (002A _a ), connected to them in series via the Loading-Unloading Arms (035) and (036) respectively ,

Where alternatively the Pyrolysis Sub-Unit (A.4.1 _a<b ) is also characterized by the fact that the extensions of the 7 Unloading Arms (036) of the Pyrolysis-Carbonation Sub-Chambers (002A _a ) are grouped in the Outlet Collector (003B), from which the outgoing Pyrolytic Activated Carbon (008 _A ) and (008 _b ), is picked up by the Loading Belt (037) and transferred to the Inlet Collector (003A _B ) from which the grouped Loading Arms (035 _B ) depart, which supply the Sub-Chambers (002A _ab ) of the Pairs of Chambers and Sub-Chambers of Cooling- Heat Exchangings (001 A _ab ) and (002A _ab ) respectively, with the outgoing Pyrolytic Activated Carbon (008 _a ) and (008 _b ) from the Sub-Chambers (002A _a ),

Where the ends of the Loading Arms (035) and Unloading Arms (036) bear the Double Valves (039) and (040) respectively, for the handling of feeding with Dry Biomass (A.2.2 _a ) and (A.2.1 _a ) and take-away of Pyrolytic Active Carbon (008 _A ) and (008 _b ) from the Sub-Chambers (002A _a ) and (002A _ab ) without air-inlet to the respective Sub-Chamber (002A _a ) and (002A _ab ), Where the Double Valves (039) and (040) of the Loading Arms (035) and Unloading Arms (036) of Inlet and Outlet respectively in the Sub-Chambers (002A _a ) of Biomass (A.2.2 _a ) and (A.2.1 _a ) for Pyrolysis-Carbonation, as well as the Double Valves (017) and (017Ά) Inlet and Outlet respectively of the Gas-Ducts (015) and (015A) are placed in the circumference of the front and rear cylindrical end of each Sub-Chamber (002A _a ), where they do not obstruct the passage of the Axis (041 ₀ ) and Screw (041 _a ), while the respective Loading Arms (035) are either grouped indicatively every seven in the overhead Inlet Collectors (003A _a ), as above, or are connected in series with the Unloading Arms (036 _a ) of the Sub-Chamber (002A _M ), in the alternative where the Chambers (001A _aa ) and the Sub-Chambers (002A _aa ) are constructed in the same form as the Chambers and Sub-Chamber (001A _a ) and (002A _a ) respectively for reasons of uniformity as above,

Where the Pyrolysis Sub-Unit (A.4.1 _A,B ) is also characterized by the fact that the Pyrolysis- Carbonation Chamber (001A _a ) is supplied and heated through the Recirculation Gas-Ducts (010) with the Superheated Flue-Gases (014) from the Hearth (016) of the Boiler (012) and pyrolyzes-carbonates the contained Biomass (A.2.2 _a ) and (A.2.1 _a ) in the Sub-Chamber (002A _a ), with the help of the Two-Way Screw System (041 _A ), which performs the process of filling, forwarding, stirring and discharging of the Sub-Chamber (002A _a ) by appropriate procedure as above,

Where the Pyrolysis Sub-Unit (A.4.1 _a,b ) is also characterized by the fact that the Pyrolysis- Carbonation Sub-Chambers (002A _a ) offer an outlet for the produced Biomass Volatiles (009) through the Gas-Ducts (015) to the Gas-Ducts Outlet Collector (015 _E ) and a reserve entry for the recirculation for the Double Purification from the Harmful Components (A.10.1) of the produced Biomass Volatiles (009) through the Volatiles Inlet Collector (015' _E ) that gathers the Volatile Recycling Gas-Ducts (015 _A ), where the Collectors (015 _E ) and (015' _E ) bear the Volatiles Valves (017) and (017 _A ) respectively,

Where the Pyrolysis Sub-Unit (A.4.1 _AjB ) is also characterized by the fact that the exit and possible recirculation of the produced Biomass Volatiles (009) from each cylindrical Sub- Chamber (002A _a ) is done through the Exit Gas-Ducts (015) and Inlet Gas-Ducts (015 _A ) which start at both ends of each cylindrical Sub-Chamber (002A _a ) immediately inwards the Inlet Valves (039) and Exhaust Valves (040), via the Exit Valves (017) and Inlet Valves (017 _A ) respectively, which are activated by the respective System of Gearbox-Motor-Inverter (017 _z ) and Inlet (017 _AZ ) of Volatiles, which are also located outside the Casing (04GK) of the respective Sub-Chamber (002A _a ) for temperature and maintenance reasons, as above,

Where the Volatiles Outlet Gas-Ducts (015) are characterized by the fact that they are grouped in the Volatiles Outlet Collector (015 _E ) from which the common Volatiles Outlet Gas-Duct (015') departs, which through the Four-Way Valve (015 _x ) either goes directly to the Hearth (016 ) of the Boiler (012) or in the Combustion Chamber (A.6.1 _B ) of the Gas Turbine (A.6.1 _a ) or it is diverted through the Four-Way Valve (015 _x ) for an additional Purification Passage through the Volatiles Inlet Collector (015' _AE ) of the Spare Sub-Chamber (002A' _ab ), in which the Volatiles Inlet Gas-Ducts (015' _A ) are grouped, which lead the Biomass Volatiles (009) through another set of Spare Sub-Chambers (002A" _ab ) also filled with Pyrolytic Activated Carbon (008 _A ) and (008 _B ) to a new Volatile Outlet Collector (015" _E ) from which the common Volatile Outlet Gas-Duct (015") departs,

Where the Pyrolysis Sub-Unit (A.4.1 _AjB ) is also characterized by the fact that the Intake and Recirculation Gas-Duct (010) of the Superheated Exhaust Gases (014) from the Hearth (016) of the Boiler (012) of the Steam Unit (A.5.1), transports the Superheated Exhaust Gases (014) from the Boiler (012) with temperatures indicatively above 650°C inside the Chambers (OOIA _A ) through the Depression Fan (028) and the Suction Fan (029), which depress and suck the Superheated Gas (014) respectively from the Boiler (012) to the Pyrolysis-Carbonation Chambers (001A _a ) and recycle them again in the Boiler (012), which heat and pyrolize- carbonate the already preheated Dry Biomass (A.2.2 _a ) and (A.2.1 _a ) in the Sub-Chamber (002A _a ) and are recycled in the Boiler (012),

Where the Pyrolysis Sub-Unit (A.4.1 _AjB ) is also characterized by the fact that the Chambers (OOIAAB) and Sub-Chamber (002A _ab ) are equipped with the Preheating Gas-Duct (018), which through the Suction Fans (030) and the Isolation Valves (021), recirculates the Preheating Air (019), which preheats the Supply Water (012 _A ) of the Boiler (012) of the Steam Unit (A.5.1) or the Boiler (012 _B ) of the Combined Cycle Unit (A.6.1) with the heat dissipated by the superheated Pyrolytic Activated Carbon (008 _A ) and (008 _B ) in the Sub-Chamber (002A _ab ), which has been transported from the Pyrolysis-Carbonation Sub-Chamber (002A _a ) and after cooling is to be exported for storage,

Where the Pyrolysis Sub-Unit (A.4.1 _a,b ) is also characterized by the fact that internally the Filling process of Biomass (A.2.2 _a ) and (A.2.1 _a ), the Forth-Back Stirring of the pyrolyzed Biomass (A.2.2 _a ) and (A.2.1 _a ) and the Discharging of the produced Pyrolytic Activated Carbon (008 _a ) and (008 _B ), is characterized in that it is executed by the System of the Two-Way Screw (041 _A ), which is characterized in that it is set in rotation and reversal of the direction of rotation via the Gearbox-Motor-Inverter System (041 _z ), either for each Sub-Chamber (002A _a ) or (002A _ab ) separately or via the Drive Chain (041 _H ) for common drive of all 7 Two-Way Screws (041 _A ) for each set of 7 Sub-Chambers (002A _a ) or (002A _ab ), of each Chamber (001A _a ) or (001 A _ab ) respectively,

Where the Double Valves (039) and (040) of inlet - outlet and between the Sub-Chambers (002A _a ) or (002 A _ab ) circulation of Biomass (A.2.2 _a ) and (A.2.1 _a ) for Pyrolysis-Carbonation, Cooling-Heat exchange and Exit of the Pyrolytic Activated Carbon respectively, are placed in the circumference of the front or rear cylindrical end of the respective cylindrical Sub- Chamber (002A _a ) or (002A _ab ), where they do not obstruct the passage of the Axis (041 ₀ ) of the Screw (041 _A ), while the respective Loading-Unloading Arms (035) and (036) are joined in series or grouped in groups of 7 in the Inlet (003A) and (003A _B ) or Outlet (003B _A ) and (003B _b ) Collectors, respectively, of each Sub-Chamber (002 A _a ) or (002A _ab ), as above,

Wherein the Pyrolysis Sub-Unit (A.4.1 _{A B} ) is also characterized in that the Loading of Biomass (A.2.2) and (A.2.1) towards the Biomass Inlet Collector-Silo (003A _a ) and the Unloading of the produced Pyrolytic Activated Carbon (008 _A ) and (008 _B ) from the Collector-Exit Silo (003B _b ) of the Pyrolytic Activated Carbon (008 _A ) and (008 _B ) is executed by the Loading - Unloading System (A.7.1), which through the Biomass Feed Belts (037) to the Collector Silo (003A _a ) of Biomass Inlet and Pyrolytic Activated Carbon Extraction Belts (038) from the Exit Collector- Silo (003B _b ), as well as the Double Valves-lnlet (039 _A ) and Outlet (040 _B ) for reasons of Sealing the Sub-Chambers (002A _AA ) or (002A _ab ) from air intake, with full automation of the loadingunloading process,

Where the Pyrolysis Sub-Unit (A.4.1 _A ,B) is also characterized by the fact that the number of revolutions of the System of the Two-Way Screw (041A) of the Sub-Chambers (002A _a ) and (002A _ab ) or of the Spare Sub-Chambers (002A _ab ) with Pyrolytic Activated Carbon, is regulated via the System of Gearbox-Motor-Inverter (041 _z ), as above, in order to fluctuate the speed of filling, stirring back and forth and discharging of the Sub-Chambers (002A _a ) and (002A _ab ) depending on the type and Biomass characteristics or the apparent volume of Pyrolytic Activated Carbon (008A) and (008B) for a larger contact surface with the recycled Biomass Volatiles (009) for complete purification of their Harmful Components (A.10.1),

Where the Pyrolysis Sub-Unit (A.4.1 _a,b ) is also characterized by having the Electrostatic Filters (012 _E ) or Bag Filters (012 _z ), which are placed indicatively on the Gas-Duct (015') or (015 ¹ ') or (015'") of conducting the Biomass Volatiles (009) for combustion in the Hearth (016) of the Boiler (012) or in the Combustion Chamber (A.6.1 _E ) of the GasTurbine (A.6.1 _a ) in an intermediate position from the Pairs of Chambers (001A _ab ) and (002A _ab ) with Pyrolytic Activated Carbon (008 _a ) and (008 _b ) and the Hearth (016) of the Boiler (012) or the Combustion Chamber (A.6.1 _E ) of the Gas Turbine (A.6.1 _a ), which retain the Microparticles (008’ _A ) and (008' _b ) of Pyrolytic Activated Carbon (008 _A ) and (008 _b ), which are carried by the stream of Biomass Volatiles (009) with their Single or Double or Multiple Purification Passage through the Sub-Chambers (002A _ab ) with Pyrolytic Activated Carbon (008 _a ) and (008 _b ) and which are collected and returned to the mass of Pyrolytic Activated Carbon (008 _a ) and (008 _b ), in order to avoid loss of material on the one hand, and on the other hand not to burden the environment with Microparticles (008' _A ) and (008' _b ), Where the Innovative Pyrolysis Sub-Unit (A.4.1 _A/B ) is also characterized by the fact that the Chambers (001A _a ) and Sub-Chambers (002A _A ) of Pyrolysis-Carbonation after each filling of the Sub-Chambers (002A _a ) from the Sub-Chambers (002A _aa ) with Dry Biomass (A.2.2 _a ) and (A.2.1 _a ), the Sub-Chamber (002A _a ) is sealed through the Isolation Valves (039) and (040), so because the Pyrolysis-Carbonation is carried out under pressure, indicatively 20-40Bar, which is created by the released Biomass Volatiles (009), as above, is characterized by the fact that, among other things, additional significant advantages arise for the whole process of Pyrolysis-Carbonation of Biomass (A.2.2) and (A.2.1), as discussed in detail above, in Chapter C "Advantages of the Present Invention in comparison to the state of the art" as well as in the Alternative Version A.O. Pyrolysis-Carbonation Unit (A.4.10) of Biomass Under Pressure, of General Form with Fixed or Rotating Chambers,

A.2. Pyrolysis-Carbonation Unit Under Pressure (A.4.1E) of Biomass (A.2.2) and (A.2.1), hereinafter Pyrolysis-Carbonation Unit (A.4.1E) which is constructed like the Pyrolysis- Carbonation Unit (A.4.1A) in Paragraph A.l, but is characterized by the fact that instead of Fixed Chambers (001A _aa ), (001A _a ) and (001A _ab ) and Fixed Sub-Chambers (002A _M ), (002A _a ) and (002A _ab ), it consists of Fixed Chambers (001A _ea ), (001A _e ) and (001A _EB ) and Rotating Sub- Chambers (002 A _ea ), (002A _e ) and (002A _EB ) and Internal Filling, Stirring and Discharging System of Biomass and Pyrolytic Activated Carbon via the Internal Double Direction Helical Spiral Crown (041' _A ), which is welded to the inner surface of the respective Sub-Chambers (002A _ea ), (002A _e ) and (002A _EB ),

Where the Double Direction Helical Spiral Crown (041' _A ) is characterized in that it performs the process of filling, forwarding, stirring and emptying the above Sub-Chambers, through the rotational movement of the above Rotating Sub-Chambers, which is done either through seven Internal Gearboxes per Chamber as above, which move the respective Toothed Rotation Rings (043') on the outer surface of the respective Rotating Sub-Chambers (002A _ea ), (002A _e ) and (002A _EB ), via the Rolling Bearings (041') where the rotational movement and the reversal of the direction of rotation of the Rotating Sub-Chambers as above, is done by connecting the Internal Gearboxes (045') with the respective Gearbox-Motor-Inverter Systems (042'), which are located outside the Casing (041K) of the respective Chamber (001A _ea ), (001A _e ) and (001A _EB ) or of the Casing (041' _K ) of the respective Sub-Chambers (002A _ea ), (002A _e ) and (002A _EB ) for reasons of temperature and maintenance, either in the seven-fold Sub-Chambers (002A _e ) and (002A _EB ) by coupling with a common Drive Chain (041' _H ) and the seven Toothed Rotation Rings (043') with an external Gearbox-Motor- Inverter System (042') as above, which moves ail seven Rotating Sub-Chambers (002A _E ) and (002A _EB ), in the each time Chamber (001A _E ) and (001A _EB ),

Where the respective Loading Arms (035' _A ) and Unloading Arms (036' _B ) of the Biomass (A.2.2 _a ) and (A.2.1 _a ) and the Pyrolytic Activated Carbon (008 _A ) and (008 _B ) and the Double Inlet Valves (039 ' _A ), (039') and (039' _B ) and Exhaust Valves (040Ά), (040') and (040' _B ) are located outside next to the Inlet-Outlet Rotation Sealing Rings (047') and (048') at the front and rear ends of the respective Rotation Cylinder (044') of the Rotating Sub-Chambers (002A _ea ), (002A _e ) and (002A _EB ) respectively, which are characterized by the fact that they are made indicatively like the Gas-Proofing Rings of the Large Diameter Pistons of the Low- Speed High-Power Heavy Diesel Engines, which operate at even higher temperatures and pressures and in addition retrogress, in contrast to the Inlet-Outlet Sealing Rings (047') and (048'), which simply only rotate,

It is also characterized by the fact that the ends of each pair of Chambers (001A _ea ), (001A _e ) and (001A _eb ) and Sub-Chambers (002A _Ά ), (002A _e ) and (002A _eb ) take the same shape as the ends of the respective pairs of Chambers and Sub-Chambers of the Pyrolysis Sub-Unit (A.4.1 _aa ), on the one hand to facilitate the entry - exit and the filling and discharging function of the Biomass (A.2.2 _a ) and (A.2.1 _a ) and of the Pyrolytic Activated Carbon (008 _a ) and (008 _B ) with the help of the Extreme Two-Way Screws (041 _E ), of the same construction as the Two- Way Screw (041 _a ), inside the extreme fixed sections of the Sub-Chambers (002A _ea ), (002A _e ) and (002 A _eb ) and on the other hand for the input-output of the respective pairs of Gas-Ducts entering-exiting inside the Rotating Sub-Chambers, as above, where alternatively the continuous one-way forwarding function is provided from the filling of Biomass (A.2.2) and (A.2.1) to the discharge of the Pyrolytic Activated Carbon (008 _A ) and (008 _B ), if the type and requirements of the processed Biomass allow it, otherwise as in the Sub-Unit (A.4.1 _M ) above, A.3. Pyrolysis-Carbonation Unit (A.4.1H) of Biomass. Under Pressure, of One Passage, of Integration into a Composit Pair of Pyrolysis-Carbonation Chambers and Sub-Chambers hereinafter Pyrolysis-Carbonation Unit (A.4.1H), characterized in that it consists of an innovative Pyrolysis-Carbonation Unit (A.4.1H) such as the Pyrolysis-Carbonation Units (A.4.1A) and (A.4.1E) above, which is characterized by the fact that alternatively instead of three separate pairs of Chambers and Sub-Chambers (001A _aa ) - (002A _M ), (001A _a ) - (002A _a ) and (001A _ab ) - (002A _ab ) or (001A _ea ) - (002A _EA ), (001A _E ) - (002A _e ) KCU (001A _eb ) - (002A _EB ), of Drying-Preheating, Pyrolysis-Carbonation and Cooling-Heat-Exchanging respectively, occurs the merging of the respective three separate pairs into Pairs of Chambers and Sub-Chambers (001AA) - (002AA) or (001AE) - (002AE), which is characterized by the fact that it gathers on it all the gas-ducts that belonged to each pair of Chambers and Sub-Chambers as above as well as the Input - Exit of Biomass (A.2.2) and (A.2.1) and the produced Pyrolytic Activated Carbon (008 _A ) and (008 _B ) respectively,

The resulting Composite Chamber and Sub-Chamber Pair (001AA)-(002AA) or (001AE)- (002AE) is characterized by the fact that it begins its operation as Chamber and Sub- Chamber Pair (001AA _AA )-(002AA _aa ) or (001AE _EA )-(002AE _ea ) of Drying-Preheating of Biomass (A.2.2) and (A.2.1) by activating the Drying-Preheating Gas-Duct (022) as well as the Biomass Loading System (A.2.2) and (A.2.1) as above and after the end of the Drying-Preheating process by alternating the Drying-Preheating Gas-Duct (022) with the Gas-Ducts (010) and (015)-(015A) of Pyrolysis-Carbonation, is converted into a pair of Chambers and Sub- Chambers (001AA _A )-(002AA _a ) or (001AE _E )-(002AE _e ) of Pyrolysis-Carbonation and after the end of the Pyrolysis-Carbonation process by alternating the Gas-Ducts (010) and (015)- (015A) of Pyrolysis-Carbonation with the Gas-Duct (019) of Cooling-Heat-Exchanging is converted into a pair of Chambers and Sub-Chamber (001AA _ab ) - (002AA _ab ) or (001AE _eb ) - (002AE _eb ) of Cooling-Heat-Exchangings of the produced Pyrolytic Activated Carbon (008 _a ) and (008 _b ) with activation finally and of the Unloading Subsystem of the produced Pyrolytic Activated Carbon (008 _a ) and (008 _b ),

Where it is characterized by the fact that as a result of the implementation of the Composite Pair of Chambers and Sub-Chambers (001AA) - (002AA) or (001AE) - (002AE) as above, the thermal power of the produced Biomass Volatiles is reduced to about one third of the thermal power of the three equivalent in terms of dimensions independent pairs of Chambers and Sub-Chambers as above, so that for the production of equivalent thermal power is multiplied by approximately three times the number of Composite Pairs of Chambers and Sub-Chambers (001AA) - (002AA) or (002AE) - (OOlAo) where the final choice of one or the other alternative will be judged on a case by case basis by the specific characteristics of each type of Biomass and the other techno-economic parameters of each Power Generation System (A.E.i) of Negative Carbon Dioxide Emissions with Negative C02 Emissions Units, as above,

For the rest as in Paragraphs A.0, A.l and A.2 above, A.4. Pyrolysis-Carbonation Unit (A.4.1'0) or (A.4.1Ά) or (A.4.1Έ) or (A.4.1Ή) of Biomass. Under Atmospheric Pressure, of Multiple Purification Passages of the Biomass Volatiles, hereinafter Pyrolysis-Carbonation Unit (A.4.1'0) or (A.4.1Ά) or (A.4.GE) or (A.4.GH), characterized in that it consists of an innovative Pyrolysis-Carbonation Unit (A.4.1'0) or (A.4.1Ά) or (A.4.1Έ) or (A.4.1Ή) such as the Pyrolysis-Carbonation Unit (A.4.10) or (A.4.1A) or (A.4.1E) or (A.4.1H), above, but characterized in that it consists of Chambers and Sub- Chambers Fixed or Rotating, which operate under Atmospheric Pressure,

And wherein the Pyrolysis-Carbonation Units (A.4.1'0) or (A.4.1Ά) or (A.4.1Έ) or (A.4.1Ή) are further characterized by the fact that due to possible incomplete purification of the Biomass Volatiles (009 ) from their Harmful Components (A.10.1) in a First Passage, they have the ability to submit the produced Biomass Volatiles (009) in a Double, Triple or Multiple Passage, through respective Spare Pairs of Chambers with Pyrolytic Active Carbon (008 _a ) and (008 _B ), until the purification of the Biomass Volatiles (009) reaches the desired level of purity, which is safe for the operation of the Boiler (012) or the Gas Turbine (A.6.1 _A ) respectively, otherwise as in the Pyrolysis-Carbonation Units (A.4.10) or (A.4.1A) or (A.4.1E) or (A.4.1H) above,

B.l.The Power Generation System (A.E.l) as Combination of a Unit (A.5.1) with a Pyrolysis- Carbonation Unit (A.4.1A), Under Pressure of 20-40Bar, of One Purification Passage, hereinafter Power Generation System (A.E.l), which is characterized in that it consists of the following Sub-Systems, namely: (A.E.l.1 _A ) of Storage and Drying of Biomass (A.2.0), (A.E.l.2 _A ) of Preparation and First Drying of Biomass (A.2.0), (A.E.l.3 _A ) of Drying-Preheating of Biomass (A.2.2) and (A.2.1), (A.E.1.4 _a ) of Pyrolysis-Carbonation of Biomass Under Pressure 20-40Bar, (A.E.1.5 _a ) of the Steam Power Plant (A.5.1) and (A.E.1.7 _a ) of the Transport and Storage of the produced Pyrolytic Activated Carbon (008 _A ) and (008 _e ), characterized in that they consist each of them of the following Components, namely:

- The Subsystem (A.E.l.1 _A ) for Storage and Drying of Biomass (A.2.0), as received, which is characterized by the fact that it has Storage of Biomass (A.2.0) in a Covered Semi-Outdoor Area (A.1.3) with Transparent Roof (A.1.3 _a ), indicatively of transparent Double Wall Plexiglas, for protection from rain and entry of Solar Radiation and ambient air for a First Drying (A.1.2), during the long period of seasonal storage of Biomass, which is collected on a seasonal basis and stored for up to more than six months, when its humidity is reduced indicatively from 40-50% to 30-35%, in contrast to the current state of the art, where no such drying is provided with a corresponding deterioration of the degree of efficiency, - The Subsystem (A.E.1.2 _a ) of Biomass (A.2.0) Preparation and First Drying, which is characterized by having the First Drying System (A.2.4), to which it promotes for a First Drying (A.2.4 ) a quantity of the stored Biomass (A.2.0) for operation of the Steam Power Plant (A.5.1), indicatively of 2-3 days, and then, after the First Drying (A.2.4), forwards it to the Grinding System (A.2.8 ) for partitioning up to small size of chopping chips of Woody Biomass (A.2.2) and in the Pelletizing System (A.2.9) for pelletizing of the Fine Biomass (A.2.1) in correspondingly sized pellets, indicatively of a size of 10-20mm, with intermediate storage of the mixture of chips and pellets or possibly only pellets if total Pelletizing is selected, of the Ground Woody Biomass (A.2.2) and the Pelletized Fine Biomass (A.2.1), which constituted the Biomass (A.2.0), in the Biomass Silo (A.2.3) ), for promotion to the Second Drying System (A.3.1) in the System (A.E.1.3 _a ), where the First Drying (A.2.4) of Biomass (A.2.0) takes place in an enclosed thermally insulated Drying Tunnel (A.2.7), which contains the Drying Wagons (A.2.5), in which the Biomass (A.2.2) and (A.2.1) is loaded and which are transported slowly into the Drying Tunnel (A.2.7) via the Conveyor Belt (A.2.6) or by rolling on the Railroad Tracks (A.2.6 _a ) and dried with a part of the Exhaust-Gases ( A.1.4), taken from the entrance of the Chimney (A.1.5) of the Boiler (012) of the Steam Unit (A.5.1) or from the entrance of the Chimney (A.1.5) of the Exhaust-Gases-Boiler (012 _B ) of the Combined Cycle Unit (A.6.1), which have a temperature indicatively above 150°-180°C,

Where the Subsystem (A.E.1.2 _a ) is also characterized by the fact that it includes the Gas-Duct (032) of the circulation of the Exhaust-Gases (A.1.4) of the Chimney (A.1.5) of the Power Generation Unit (A.5.1), for the First Drying (A.2.4) of Biomass (A.2.2) and (A.2.1), the Depression Fan (033), which sucks and sends part of the Exhaust -Gases (A.1.4) of the Chimney (A.1.5) of the Power Generation Unit (A.5.1), with a temperature indicatively 180°C, for the First Drying (A.2.4) of Biomass (A.2.2) and (A.2.1), while the respective Exhaust-Gases (A.1.4) of the Boiler (012) with reduced temperature, due to the First Drying (A.2.4) and preheating of the Biomass (A.2.2) and (A.2.1), is transmitted to the Cooling Tower (A.1.8 _a ) for discharge into the Atmosphere, carried away by the upstream water vapors of the Cooling Tower (A.1.8 _a ), where the Drying with the Hot Exhaust Gas (A.1.4) lowers the humidity of Biomass (A.2.2) and (A.2.1) indicatively from 30-35% to a level below 20%, in preparation for the Second Drying System (A.3.1), which takes place in the Subsystem (A.E.1.3 _a ),

Where the Subsystem (A.E.1.2 _a ) is also characterized by the fact that the Biomass (A.2.2) and (A.2.1) after the First Drying System (A.2.4) and its Grinding-Pelletizing and Storage in Biomass Silos (A.2.3), is promoted to be introduced for the Second Stage of Drying (A.3.1) in the Chambers (001A _a ) and Sub-Chambers (002A _a ) of the Subsystem (A.E.1.3 _a ) Drying and Preheating of Biomass (A.2.2) and (A.2.1), via the Subsystems of Biomass Feed Belts (037) of the Collector-Silo (003A _a ) and the Loading Arms (035 _A ) as well as the Double Inlet Valves (039 _a ) of the Loading-Unloading Systems (A.7.1), per pair of Chambers (001A _A ) and Sub- Chambers (002A _A ), with full automation of the internal continuous loading process of Biomass (A.2.2) and (A.2.1) in the Sub-Chambers (002A _A ) of the Sub-System (A.E.1.3 _a ) respectively , in contrast to our previous Application with OBI Number 20190100159, where the loading of Biomass (A.2.2) and (A.2.1) and its transport and import to the corresponding Sub-Chambers (002) of the System (A.3) is made with the discontinuous procedure and use of the abolished Wagons (003),

The Sub-System (A.E,1.3 _A ) of Drying and Preheating of the Biomass (A.2.2) and (A.2.1), hereinafter Sub-System (A.E.1.3 _A ) or Drying-Preheating Sub-Unit (A.4.1 _aa ), which is characterized by the fact that it provides Drying in a Second Stage (A.3.1) with the available Hot Exhaust-Gases (A.1.4) from the entrance of the Chimney (A.1.5) of the Boiler (012) of the Steam Unit (A.5.1), which removes the last 20% of moisture and makes a corresponding preheating of the Dry Biomass (A.2.2 _a ) and (A.2.1 _a ) and where after the recovery of heat by the Biomass (A.2.2 _a ) and (A. 2.1 _A ) due to drying and preheating by the Hot Exhaust-Gases (A.1.4), which are thus cooled and transmitted to the Cooling Tower (A.1.8 _a ) for discharge into the Atmosphere, carried away by the upstream water vapors of the Cooling Tower (A.1.8 _a ), which results in a significant overall improvement of the efficiency of the System (A.E.l) on average indicatively over 10%, in contrast to the efficiency of the power plant with conventional Pyrolysis-Carbonation, which is correspondingly smaller than the one of the Power Generation System (A.E.l),

Otherwise as described in Paragraph A.l Drying-Preheating Sub-Unit (A.4.1 _M ) of Biomass Under Pressure, of a Single Passage, above,

- The Sub-System (A.E.l.4 _A ) of Pyrolysis-Carbonation of Biomass Under Pressure, hereinafter Sub-System (A.E.l.4 _A ) or Pyrolysis-Carbonation Sub-Unit (A.4.1 _AjB ), which is characterized by the fact that it consists of an innovative Pyrolysis-Carbonation Sub-Unit (A.4.1 _AjB ) of Ground or Pelletized Dry Woody or Fine Biomass (A.2.2 _a ) and (A.2.1 _a ), consisting of the Pyrolysis- Carbonation Chambers and Sub-Chambers (001A _a ) - (002A _a ) and Cooling-Heat-Exchanging (001A _ab ) - (002A _ab ) respectively, where the Pelletized Dry Biomass (A.2.2 _a ) and (A.2.1 _a ), is heated indicatively to 550°C and Pyrolyzed and then the produced Pyrolytic Activated Carbon (008 _A ) and (008 _B ) is cooled and heat-exchanged, as described in detail in Section A.l Sub-Units of Pyrolysis-Carbonation (A.4.1 _a ) and Cooling-Heat-Exchanging (A.4.1 _ab ) Under Pressure, of a Single Passage, above,

Where the innovative Pyrolysis-Carbonation Unit (A.4.1 _AjB ) is characterized by the fact that because the Pyrolysis-Carbonation is carried out under pressure, indicatively of 20-40Bar, significant additional advantages arise for the whole process of Pyrolysis-Carbonation of Biomass (A.2.2) and (A.2.1), as described in detail above in Chapter C "Advantages of the Present Invention towards the Present State of the Art" and in Section A.l Pyrolysis- Carbonation Sub-Units (A.4.1 _a ) and Cooling-Heat-Exchanging Sub-Units (A.4.1 _AB ) of Biomass Under Pressure, of a Single Passage, above,

For the rest, as described in detail in Section A.l Pyrolysis-Carbonation (A.4.1 _a ) and Cooling- Heat-Exchanging (A.4.1 _ab ) Sub-Units, Under Pressure, of a Single Passage, above,

- The Sub-System (A.E.l.5 _A ) of the Modified Steam Electric Power Plant (A.5.1), which is characterized by the fact that the Modified Units (A.5.1) will now operate with Pure or Mixed Firing of Volatile Biomass Volatiles (009) and Coal (009A), where it is possible, in a first conversion of the Coal-Fired Power Plant to a Power Plant (A.5.1), initially for Mixed Firing, indicatively of 1/3 Coal (009 _a ) and 2/3 Biomass Volatiles (009), to zero the conversion cost of the Coal-Fired Steam Power Plant to a Power Plant (A.5.1), because the Coal-Fired Steam Power Plants can reduce their load to 1/3 without any conversion and much more effectively when the combustion in the Hearth (016) of the Boiler (012) is supported by the additional Mixed Firing of 2/3 of Biomass Volatiles (009), where the reduced to 1/3 Emissions of Carbon Dioxide are more than offset by the Negative Carbon Dioxide Emissions of the corresponding produced Pyrolytic Activated Carbon (008 _A ) and (008 _b ), where it can not only zero by offsetting the Carbon Dioxide Emissions but even to transform them by a 38-45% percentage into pure Negative Carbon Dioxide Emissions; Where remains as an investment for the entire Power Generation System (A.E.l), only the innovative Pyrolysis-Carbonation Unit (A.4.1 _a ) with its peripherals, which is amortized as an investment cost with net profits of less than two years, while now the Power Generation System (A.E.l) with the Modified Power Generation Unit (A.5.1) is very profitable, because on the one hand it avoids the cost of purchasing Carbon Dioxide Emissions Rights, while on the other hand it secures about 40% of this cost as a Credit due to the Production of Negative Carbon Dioxide Emissions, while at the same time it is credited with the sale value of the produced Pyrolytic Activated Carbon (008 _A ) and (008 _B ) as a Soil Conditioner for the Agriculture, so the result instead of losses is changed into a very valuable profitability even for the Mixed Firing as above, while with the Pure Firing, despite the increased investment for the modification of the Boiler (012) for Pure Combustion of Biomass Volatiles (009), the profitability increases by at least 40-50% while the Negative Carbon Dioxide Emissions are more than doubled,

Where the Sub-System (A.E.l.5 _A ) is characterized in that it consists of a Modified Steam Electric Power Plant (A.5.1) with initial firing of fossil fuels, indicatively Coal (009A), which has been modified for firing of the Biomass Volatiles (009) products of the Pyrolysis-Carbonation Unit (A.4.1A) in the Flearth (016) of the Steam Boiler (012), in mixed firing with Coal (009 _A ) in the percentage that is necessary up to total zeroing of the use of Coal (009 _A ) and pure combustion of exclusively Biomass Volatiles (009), in which case the C02 emissions from the Modified Steam Electric Power Plant (A.5.1) are zeroed by zeroing the Coal (009 _A ), because the minimum C02 emissions from the Biomass Volatiles (009) do not count as a greenhouse gas, because they come from Carbon Dioxide which was absorbed from the Atmosphere by the plants, while at the same time achieving Negative Emissions of Carbon Dioxide due to production of Pyrolytic Activated Carbon (008 _A ) and (008 _B ), which is equivalent to the capture of 3,667 times heavier Atmospheric Carbon Dioxide and which is promoted for use as a Soil Conditioner in Agriculture, while at the same time is abolished the Chimney (A.1.5) of the Steam Power Plant (A.5.1), which is replaced by the operation of the modified Cooling Tower (A.1.8 _a ), which promotes in the atmosphere the Exhaust Gases (A.1.4) of reduced temperature, due to drying and preheating of Biomass (A.2.2) and (A.2.1), with the upstream Water Vapors of the Cooling Tower (A.1.8 _a ), as well as are abolished the Desulphurization and Denitrification Systems, because the Sulfur and Nitrogen Compounds are retained by the Filter of Pyrolytic Activated Carbon (008 _a ) and (008 _b ), as well as the Coal Mills, the Desulfurization Ash and Gypsum Disposal Systems and the Desulphurization, Denitrification and Other Waste Treatment Systems which are retained by the Pyrolytic Activated Carbon Filter (008 _a ) and (008 _b ),

The Subsystem (A.E.l.7 _A ) for Transport and Storage of Activated Carbon (008 _A ) and (008 _r ), which is characterized by the fact that it promotes it indicatively either in Enrichment and Activation Units of Pyrolytic Activated Carbon (008 _A ) and ( 008 _B ) with chemical or organic fertilizers and then its promotion for permanent storage as a Soil Conditioner in Agriculture, where it remains unchanged for hundreds or even thousands of years, and where by creating and hosting large Colonies of Nitrogen Bacteria and other Bacteria in the soil, which provide atmospheric nitrogen and other trace elements that nourish the, plants, dramatically increases the agricultural production by 200% to 900% [15], [16], [17] in perpetuity, or in short-term storage for future use or for other uses, in contrast to the current state of the art, which simply provides for the reduction of Carbon Dioxide emissions from Fossil Fuel Power Plants, where is foreseen simply the reduction of Carbon Dioxide Emissions of the Fossil Fuels-Fired Electricity Generating Units, where there are not foreseen Negative Carbon Dioxide Emissions, neither production of Pyrolytic Activated Carbon (008 _A ) kai (008 _B ),

B.2. The Power Generation System (A.E.2) as Combination of a Unit (A.5.1) with a Pyrolysis Unit (A.4.1E) Under Pressure of 20-40Bar, of a Single Purification Passage, hereinafter Power Generation System (A.E.2), which is characterized by the fact that it consists of the following Sub-Systems, namely: (A.E.2.1 _E ) Storage and Drying of Biomass (A.2.0), (A.E.2.2 _e ) Preparation and First Drying of Biomass (A.2.0), (A.E.2.3 _e ) Drying - Preheating of Biomass (A.2.2) and (A.2.1), (A.E.2.4 _e ) Pyrolysis-Carbonation of Biomass Under Pressure of 20-40Bar and Cooling-Fleat Exchanging, (A.E.2.5 _e ) the Steam Power Plant (A.5.1) and (A.E.2.7 _e ) Transmission and Storage of the produced Pyrolytic Active Carbon (008 _A ) and (008 _b ), characterized in that they each consist of the following Components as described below, namely:

- Where Subsystems (A.E.2,1 _f ), (A.E.2.2 _f ), (A.E.2.5 _e ) and (A.E.2.7 _f, are characterized by being the same as the Subsystems (A.E.1.1 _a ), (A.E.1.2 _a ), (A.E.1.5 _a ) and (A.E.1.7 _A above in the System (A.E.l),

- The Subsystem (A.E.2.3 _F ) of Drying - Preheating of Biomass (A.2.2) and (A.2.1), hereinafter Sub-System (A.E.2.3 _e ) or Drying-Preheating Sub-Unit (A.4.1 _ea ), which is the same as the Sub- System (A. E.1.3 _a ) above, but is characterized by the fact that instead of the pair with Fixed Chamber and Sub-Chamber (001A _aa ) and (002A _M ) respectively, it consists of the pair with Fixed Chamber (001A _ea ) in conjunction with the Rotating Sub-Chamber (002A _ea ), otherwise as in the Sub-System (A.E.l.3 _a ) and in the Pyrolysis-Carbonation Unit (A.4.1 _E ) Under Pressure in Paragraphs B.l and A.2 above,

- The Subsystem (A.E.2.4 _F ) Pyrolysis-Carbonation of Biomass Under Pressure 20-40Bar, hereinafter Sub-System (A.E.2.4 _e ) or Pyrolysis-Carbonation Sub-Unit (A.4.1 _EjB ), which is the same as the Sub-System (A.E.l.4 _A ) above, however, is characterized by the fact that instead of the pairs with Fixed Chambers and Sub-Chambers (001A _AA )-(002A _AA ), (001A _A )-(002A _a ) and (001A _AB )-(002A _ab ) respectively, consists of the pairs with Fixed Chambers (001A _ea ), (001A _e ) kai (001A _eb ) in conjunction with the Rotating Sub-Chambers (002A _ea ), (002A _e ) and (002A _EB ) respectively, otherwise as in Sub-System (A.E.1.4 _a ) and in the Pyrolysis-Carbonation Unit (A.4.1 _e ) Under Pressure in Paragraphs B.l and A.2 above,

B.3. The Power Generation System (A.E.3) as a Combination of the Unit (A.6.1) or (A.6.G) with a Pyrolysis-Carbonation Unit (A.4.1A) or (A.4.1E) Under Pressure, of One Cleaning

Passage , hereinafter Power Generation System (A.E.3), characterized in that it consists of the following Subsystems, namely: (A.E.3.1 _A ) or (A.E.3.1 _e ) of Biomass (A.2.0) Storage and Drying, (A.E.3.2 _a ) or (A.E.3.2 _e ) Preparation and First Drying of Biomass (A.2.0), (A.E.3.3 _a ) or (A.E.3.3 _e ) Drying-Preheating of Biomass (A.2.2) and (A.2.1), (A.E.3.4 _a ) or (A.E.3.4 _e ) Pyrolysis- Carbonation and Cooling-Heat-Exchanging of Biomass Under Pressure 20-40Bar, (A.E.3.6 _a ) or (A.E.3.6 _e ) of the Simple or Combined Cycle Unit (A.6.G) or (A.6.1), (A.E.3.7 _a ) or (A.E. 3.7 _E ) Transport and Storage of the produced Pyrolytic Activated Carbon (008 _A ) and (008 _B ), which are characterized in that they consist of the following Components as follows, namely:

- Where the Subsystems (A.E.3.1 _{a e} ) or (A.E.3.1 _{a e} ), (A.E.3.2 _{A F} ) or (A.E.3.2 _{a e} ), (A.E.3.3 _{A F} ) or (A.E.3.3A and (A.E.3.7 _{a e} ) or (A.E.3.7 _{A F} ), are characterized in that they are the same as Sub- Systems (A.E.I.I _A ), (A.E.1.2 _a ), (A.E.1.3 _A ) and (A.E.1.7 _a ) and (A.E.1.1 _e ), (A.E.1.2 _e ), (A.E.1.3 _e ) and (A.E.1.7 _e ) above in System (A.E.l) and (A.E.2),

- The Sub-System (A.E.3.4 _a ) or (A.E.3.4 _e ) Pyrolysis-Carbonation of Biomass Under Pressure 20-40Bar, hereinafter Sub-System (A.E.3.4 _a,e ) or Pyrolysis-Carbonation Sub-Unit (A.4.1 _AjB ) or (A.4.1 _EjB ), characterized in that it is the same as the Sub-Systems (A.E.1.4 _a ) and (A.E.2.4 _e ) above, i.e. each as an innovative Pyrolysis-Carbonation Unit (A.4.1 _A,B ) or (A.4.1 _E(B ) Under Pressure, indicatively 20-40Bar, for the production of Clean Biomass Volatiles (009) and Pyrolytic Activated Carbon (008 _A ) and (008 _B ), but are characterized by the fact that the Superheated Flue Gas (014) for Pyrolysis-Carbonation in the Sub-Chambers (002A _a ) and (002A _e ) are taken from the exit of the Gas Turbine (A.6.1 _a ) and after the Pyrolysis- Carbonation are forwarded to the Exhaust Gas Boiler (012 _B ) of the Combined Cycle Unit (A.6.1), otherwise as in Subsystem (A.E.1.4 _a ) and (A.E.2.4 _e ) above,

- The Subsystem (A.E.3.6 _{A F} ) of the Simple or Combined Cycle Unit (A.6.1') or (A.6.1) hereinafter Sub-System (A.E.3.6 _a<e ), characterized in that it consists of a combination from a Modified Simple or Combined Cycle Power Plant (A.6.1 ¹ ) or (A.6.1) with Pure or Mixed Firing of Biomass Volatiles (009) with Fossil Fuels, indicatively Natural Gas (NG) (009 _B ) and an innovative Pyrolysis-Carbonation Sub-Unit (A.4.1 _A ,B) or (A.4.1 _E,B ) Under Pressure, indicatively 20-40Bar, for the production of Clean Biomass Volatiles (009) and Pyrolytic Activated Carbon (008 _A ) and (008 _B ), thus yielding multiple advantages for both the total process of Pyrolysis- Carbonation of Biomass (A.2.2) and (A.2.1) as well as for the Power Generation, as analyzed in the Detailed Description below, For the rest as in Paragraphs B.l, B.2 and A.l, A.2 above,

B.4. The Power Generation System (A.E.4) as a Combination of the Unit (A.5.1) or (A.6.1) or (A.6.1 ¹ ) with a Pyrolysis-Carbonation Unit (A.4.1HA) or (A.4.1HE) Under Pressure 20-40Bar, of One Purification Passage. hereinafter Power Generation System (A.E.4), which is characterized in that it consists of the following Subsystems, namely: (A.E.4.1 _H ) Storage and Drying of Biomass (A.2.0), (A.E.4.2 _H ) Preparation and First Drying of Biomass (A.2.0), (A.E.4.3 _H ) Drying-Preheating of Biomass (A.2.2) and (A.2.1), (A.E.4.4 _H ) Pyrolysis-Carbonation of Biomass, Under Pressure 20-40Bar and Cooling-Heat Exchanging, (A.E.4.5 _H ) of the Power Generation Unit (A.5.1) or (A.6.1) or A.6.1'), (A.E.4.7 _H ) Transport and Storage of the produced Pyrolytic Activated Carbon (008 _A ) and (008 _b ), which are characterized in that they consist of the following Components as described in the following, namely:

- Where the Sub-Systems (A.E.4.1 _H ), (A.E.4.2 _H ), (A.E.4.3 _H ) and (A.E.4.7 _h ) are characterized by the fact that they are the same as the Sub-Systems (A.E.l.1 _A ), (A.E.l.2 _A ), (A.E.l.3 _a ) KCU (A.E.l.7 _a ) kai (A.E.l.1 _E ), (A.E.l.2 _E ), (A.E.1.3 _e ) KOU (A.E.l.7 _e ) above in the System (A.E.l) and

(A.E.2),

- The Sub-System (A.E.4.4 _H ) Pyrolysis-Carbonation of Biomass Under Pressure 20-40Bar, hereinafter Sub-System (A.E.4.4 _H ) or Pyrolysis-Carbonation Unit (A.4.1 _H ), which is characterized by that it is the same as the Pyrolysis-Carbonation Sub-Unit (A.4.1 _H ) of Biomass, Under Pressure, of Single Passage, Integration into a Composite Pair of Pyrolysis- Carbonation Chambers and Sub-Chambers, otherwise as in Section A.3 above,

- The Sub-System (A.E.4.5 _H ) of the Power Generation Unit (A.5.1) or (A.6.1) or A.6.1 ¹ ), hereinafter Sub-System (A.E.4.5 _H ), which is characterized in that it consists of a combination of a Modified Power Generation Unit (A.5.1) or (A.6.1) or (A.6.1') as in Sub-Systems (A.E.1.5 _a ) and (A.E.3.5 _e ) and an innovative Pyrolysis-Carbonation Unit (A.4.1 _H ) Under

Pressure, indicatively 20-40Bar, for the production of Clean Biomass Volatiles (009) and Pyrolytic Activated Carbon (008 _a ) and (008 _b ), thus resulting in multiple advantages for the whole process of Pyrolysis-Carbonation of Biomass (A.2.2) and (A.2.1) as well as for the Power Generation, as analyzed in the Detailed Description above, For the rest as in Paragraphs B.l, B.2, B.3 and A.l, A.3 above,

B.5. The Power Generation System (A.E.5) Combination of Unit (A.5.1) or (A.6.1) or A.6.G) with a Pyrolysis-Carbonation Unit (A.4.1'0) or (A.4.1Ά) or (A.4.1Έ) or (A.4.1Ή) of

Atmospheric Pressure, hereinafter Power Generation System (A.E.5), characterized in that it consists of the following Sub-Systems, namely: (A.E.5.G) Storage and Drying of Biomass (A.2.0), (A.E.5.2') Preparation and First Drying of Biomass (A.2.0), (A.E.5.3 ¹ ) Drying- Preheating of Biomass (A.2.2 ) and (A.2.1), (A.E.5.4') Pyroiysis-Carbonation (A.4.1'0) or (A.4.GA) or (A.4.GE) or (A.4.GH) of Atmospheric Pressure, (A.E.5.5') of the Power Generation Unit (A.5.1) or (A.6.1) or A.6.1'), (A.E.5.7') Transport and Storage of the produced Pyrolytic Activated Carbon (008 _A ) and (008 _B ), characterized in that they consist of the following Components as described below, namely:

- Where the Sub-Systems (A.E.5.1 ¹ ), (A.E.5.2'), (A.E.5.3') and (A.E.5.7'), are characterized by the fact that they are the same as the Sub-Systems (A.E.1.1 _a ), (A.E.1.2 _a ), (A.E.1.3 _a ) and (A.E.1.7 _a ) above in the System (A.E.l), - The Sub-System (A.E.5.4 ¹ ) with Pyrolysis-Carbonation Units (A.4.1' _n ) or (A.4.G _a ) or (A.4.G _E ) or (A,4.1' _H ) of Atmospheric Pressure, hereinafter Sub-System (A.E.5.4 ¹ ) or Pyrolysis- Carbonation Unit (A.4.1'o) or (A.4.1' _A ) or (A.4.1' _EB ) or (A.4.1' _HB ), characterized by that it is the same as the Pyrolysis-Carbonation Sub-Units (A.4.1' ₀ ) or (A.4. l' _A ) or (A.4.1' _E ) or (A.4.G _H ) of Atmospheric Pressure in Section A.4 above, - The Sub-System (A.E.5.5 ¹ ) of the Power Generation Units (A.5.1) or (A.6.1) or A.6.1'), hereinafter Sub-System (A.E.4.5 ¹ ), is characterized in that it consists of a combination of a Modified Power Plant (A.5.1) or (A.6.1 ') or (A.6.1) as in Sub-Systems (A.E.1.5 _a ) and (A.E.3.6 _a ) and an innovative Pyrolysis-Carbonation Unit (A.4.1’ ₀ ) or (A.4.1' _a ) or (A.4.1' _E ) or (A.4.1' _H ) of Atmospheric Pressure, for the production of Clean Biomass Volatiles (009) and Pyrolytic Active Carbon (008 _A ) and (008 _B ), in which case the need arises for Double or Triple or Multiple Biomass Volatiles Purification Passage as in Paragraph A.4 above,

For the rest as in Paragraphs B.l, B.2, B.3, B.4 and A.l, A.2, A.3 and A.4 above,

REFERENCES

[1] Leaked Pentagon Report Warns Climate Change May Bring Famine, War

[2] Secret Study of the US Army Leaked and published by The OBSERVER in London "An Abrupt Climate Change Scenario and Its Implications for United States National Security"

[3] "There are no passengers on Spaceship Earth. We are all crew" Marshall McLuhan, Biography.

[4] "The Day After Tomorrow" (A Hollywood Movie with financing by the American Army), Available in all Video Shops. [5] A shocking Picture : Australia in flames from a satellite - An untold catastrophe

[6] The blazes in the Amazon are so big they can be seen from space. One map shows the alarming scale of the fires.

[7] World Alarm: The Planet in Climate Emergency

[8] biz088 (World Scientists' Warning of a Climate Emergency) [9] "Dramatic Warning from WWF: This is the last Generation which can save the Planet"

[10] Lord Stern: we need negative emissions to avoid 2,0°C warming

[11] Research Funded By Leonardo DiCaprio Foundation Under One Earth Initiative Claims World Can Stay Below 1,5°C With 100% Renewable Energy Achieved By 2050

[12] UN COP21 Agreement in Paris in 2015 on Climate Change [13] Drawing No 23, where is given graphically that the increase of Carbon Dioxide in the

Atmosphere in relation to 2020 will be zero, provided that the Technology of the Negative C02 Emissions Units will be adopted by the existing today Fossil-Fuels-Fired Power Plant Units.

[14] ) 076 (The Role of Pressure in the Heat of of a Lignocellulosic Biomass) [15] agronomy-03-00404 [The Impact of Biochar Application on Soil Properties and Plant

Growth of Pot Grown Lettuce ( Lactuca sativa) and Cabbage ( Brassica chinensis)] (till 900%).

[16] Terra-preta

[17] 442-311_pdf (Virginia Tech. University)