| WO2018170115A1 | 2018-09-20 | |||
| WO2011019478A1 | 2011-02-17 |
| Claims. 1.- Composition of an adhesive water- and steam-tight barrier layer (4), characterised in that it consists of an acoustically insulating polyamide layer (5) which along one side is provided with: - a first water- and steam-tight polymer layer or copolymer layer (6) composed of a polyethylene layer or, abbreviated, a PE layer, being LDPE or HDPE, or a copolymer layer composed of 0 ethylene / vinyl acetate , or 0 ethylene / 1-octene, or 0 ethylene / 1-hexene, or 0 ethylene / 1-propene; or a polypropylene layer, or abbreviated, a PP layer, said first water- and steam-tight polymer layer or copolymer layer (6) having a melting point between 75°C and 165°C; and said acoustically insulating polyamide layer (5) being provided along the opposite side with - an optional second water- and steam-tight polymer layer (7), - a third water- and steam-tight polymer layer (8) composed of either o PE, being LDPE or HDPE, possibly copolymerised with 0-25 weight% vinyl acetate to polyethylene vinyl acetate with a melting point between 70 °C and 95 °C, or o ethylene, copolymerised with 1-octene, or with 1-hexene, or with 1-propene, with a melting point between 70 °C and 95 °C, bordering the second polyethylene layer (7) or, if the latter is missing, bordering the acoustically insulating polyamide layer (5). 2.- Composition of an adhesive water- and steam-tight barrier layer (4) according to claim 1, characterised in that - the first water- and steam-tight polymer layer or copolymer layer (6) consists of polyethylene copolymerised with 0-25 weight% ethylene vinyl acetate and has a melting point between 70 °C and 110°C; and along the opposite side is provided with an optional second water- and steam-tight and pure polyethylene layer (7), - the third water- and steam-tight polymer layer consists of polyethylene copolymerised with 15-25 weight% ethylene vinyl acetate with a melting point between 70 °C and 95 °C bordering the second and pure polyethylene layer (7) or, if the latter is missing, bordering the acoustically insulating polyamide layer (5) itself. 3.- Composition of an adhesive water- and steam-tight barrier layer (4) according to claim 2, characterised in that it consists of an acoustically insulating polyamide layer (5) which along one side is provided with: - a first water- and steam-tight polymer layer or copolymer layer (6) of polyethylene copolymerised with 5 weight% ethylene vinyl acetate and with a melting point of 109°C; and along the opposite side is provided with - an optional second water- and steam-tight pure polyethylene layer (7), a third water- and steam-tight polymer layer of polyethylene copolymerised with 22.5 weight% ethylene vinyl acetate with a melting point of 73°C bordering the second water- and steam-tight and pure polyethylene layer (7) or, if the latter is missing, bordering the acoustically insulating polyamide layer (5) itself. 4.- Composition of an adhesive water- and steam-tight barrier layer (4) according to claim 1, 2 or 3, characterised in that it is part of a layer package (1), whereby the adhesive water- and steam-tight barrier layer (4) is located between a first non-woven material (2) and a second but different non-woven material (9) which is thermoformable. 5.- Composition of an adhesive water- and steam-tight barrier layer (4) according to claim 4, characterised in that the layer package (1), of which the adhesive barrier layer (4) is a part, consists of: - a first non-woven material (2) with a back layer (3) of polyethylene-terephthalate; - an adhesive water- and steam-tight barrier layer (4) according to the invention, composed of . an acoustically insulating barrier layer of polyamide (5), with . a first water- and steam-tight copolymer layer (6) consisting of polyethylene with 5 weight% ethylene vinyl acetate and with a melting point of 109°C along the upperside of the polyamide layer (5); . an optional second and pure polyethylene layer (7) along the underside of the polyamide layer (5); . a third copolymer layer consisting of polyethylene polymerised (8) with 22.5 weight% ethylene-vinyl acetate with a melting point of 73°C along the underside of the optional second and pure polyethylene layer (7) or if this is missing, along the underside of the polyamide layer (5) itself. - a second non-woven material 9 which is thermoformable 6. Composition of an adhesive water- and steam-tight barrier layer (4) according to claim 4, characterised in that the back layer (3) of polyethylene-terephthalate of the first non-woven material (2) is perforated by means of a treatment with needles. 7. Composition of an adhesive water- and steam-tight barrier layer (4) according to claim 2 or 3, characterised in that the total thickness of the adhesive water- and steam-tight barrier layer (4) itself is between 40 micrometers and 250 micrometers . 8. Composition of an adhesive barrier layer (4) according to claim 2 or 3, characterised in that the acoustically insulating polyamide barrier layer (5) along one side is provided with a tie layer consisting of a terpolymere of ethylene, butylacrylate and maleic anhydride with a melting point of 91°C for tying the first water- and steam-tight polyethylene/ethylene vinyl acetate copolymer layer (6) with 5 weight% ethylene vinyl acetate and with a melting point of 109°C and that the acoustically insulating polyamide barrier layer (5) along the other side is provided with a similar tie layer with an adjusted melting point for tying the second water- and steam-tight and pure polyethylene layer (7) or the third water- and steam-tight polyethylene/ethylene vinyl acetate copolymer layer (8) with 22.5 weight% ethylene vinyl acetate with a melting point of 73°C. |
The present invention relates to a composition of an adhesive barrier layer between a non-woven material and another non- woven material for processing at higher temperatures.
In particular, the invention is intended for binding several layers of non-woven material under the influence of steam and pressure whereby a water- and steam-tight barrier layer is formed between the layers of non-woven material.
It is known that non-woven material can be used for a lining instead of a woven carpet. The application of non-woven material as interior lining for vehicles, whereby the non- woven material is applied as a non-flat lining against the roof or the floor of the vehicle is already known.
Traditionally the non-woven material is moulded into the desired form under the influence of pressure and/or temperature, such that it can be fittingly mounted in a particular vehicle. It is known that a heating process with steam can be used for this (e.g. US2015/0118437).
WO 2018/170115 A1 describes a laminate of two non-woven materials between which one polymer sheet of a polymer such as polyethylene, polyamide, or another thermoplastic polymer is located. The laminate is used as interior lining for a vehicle. WO 2011/019478 Al describes a laminate for protective apparel, with a non-woven layer, to which a breathable layer is bound consisting of a first and second microporous film between which a monolithic layer of copolyether ester, copolyether amide or urethane polymer is located. The laminate is used as protective apparel in hospitals.
There is a problem when several and different layers of a non-woven material need to be bound to each other and moulded in the desired form, whereby the different layers of non- woven material have to remain firmly bound to each other everywhere while in addition a water- and steam-tight barrier has to be formed between both layers to limit the penetration of steam up to this steam-tight barrier, such that the non- woven material on the opposite side of the steam-tight barrier cannot be thermally degraded by the presence of steam. The purpose of the present invention is to offer a solution to said requirements by providing in a multi-layer adhesive water- and steam-tight barrier layer with which two different non-woven materials can be and remain bound to each other, also after a thermal and/or pressure treatment with steam to give a desired form to the layer package, and this without thermal degradation of the non-woven material that faces the interior of the vehicle and therefore the passengers.
To this end, the invention relates to a composition of an adhesive water- and steam-tight barrier layer, consisting of an acoustically insulating polyamide layer which along one side is provided with:
- a first water- and steam-tight polymer layer or copolymer layer composed of a polyethylene layer or, abbreviated, a PE layer, being LDPE or HDPE, or a copolymer layer composed of
0 ethylene / vinyl acetate (22.5 weight%), or 0 ethylene / 1-octene, or 0 ethylene / 1-hexene, or 0 ethylene / 1-propene; or a polypropylene layer, or abbreviated, a PP layer, said first water- and steam-tight polymer layer or copolymer layer being characterised by a melting point between 75 °C and 165°C; and said acoustically insulating polyamide layer being provided along the opposite side with
- an optional second water- and steam-tight polymer layer, - a third water- and steam-tight polymer layer composed of either o PE, being LDPE or HDPE, possibly copolymerised with 0-25 weight% vinyl acetate to polyethylene vinyl acetate with a melting point between 70 °C and 95 °C, or o ethylene, copolymerised with 1-octene, or with 1-hexene, or with 1-propene, with a melting point between 70 °C and 95 °C, bordering the second polyethylene layer or, if the latter is missing, bordering the acoustically insulating polyamide layer .
An advantage of the above layer structure is that the central acoustically insulating polyamide layer is flanked on both sides with a water- and steam-tight polymer layer or copolymer layer, a first layer on the side facing the car passengers with a melting point between 75 °C and 165 °C, and a second layer on the side facing the car bodywork with a lower melting point between 70 °C and 95 °C.
The production process for forming a ready-made vehicle carpet lining in one step, whereby two non-woven materials are bound together by an intermediate barrier layer according to the invention, is done in a mould, while heat is supplied in the form of steam from under the thermoformable non-woven material facing the bodywork, after which the heat penetrates up to the first side of the polyamide layer facing the passengers .
A problem observed is that if during the heating process steam penetrates the non-woven material facing the passengers, i.e. the carpet layer on which passengers sit, said carpet layer is unacceptably degraded by the combination of moisture and heat. However, because of the layer structure according to the invention, the supplied steam will now first hit the second polymer layer or copolymer layer which melts at a lower temperature, and thus forming a water- and steam-tight barrier, which prevents steam penetrating into the carpet layer, but allows the first polymer layer or copolymer layer to be heated to its melting point in a dry way, such that both non-woven materials are firmly bound to the acoustically insulating polyamide layer, but without thermal degradation of the carpet layer for the passengers.
In a preferred embodiment of the adhesive water- and steam- tight barrier layer - the first water- and steam-tight polymer layer or copolymer layer consists of polyethylene, possibly copolymerised with 0-25 weight% ethylene vinyl acetate with a melting point between 70 °C and 110°C; along the opposite side provided with
- an optional second water- and steam-tight polyethylene layer,
- the third water- and steam-tight polymer layer consists of polyethylene copolymerised with 15-25 weight% ethylene vinyl acetate with a melting point between 70 °C and 95 °C bordering the second polyethylene layer or, if the latter is missing, bordering the acoustically insulating polyamide layer itself. In yet another embodiment of this invention, the water- and steam-tight barrier layer consists of an acoustically insulating polyamide layer which along one side is provided with:
- a first water- and steam-tight polymer layer or copolymer layer of polyethylene copolymerised with 5 weight% ethylene vinyl acetate and with a melting point of 109°C; and along the opposite side is provided with:
- an optional second water- and steam-tight pure polyethylene layer, which in turn borders: a third water- and steam-tight polymer layer of polyethylene copolymerised with 22.5 weight! ethylene vinyl acetate and with a melting point of 73°C bordering the second water- and steam-tight and pure polyethylene layer or, if this is missing, bordering the acoustically insulating polyamide layer itself.
An advantage of such adhesive barrier layer is that the polyethylene layer with a melting point of 109°C can fuse with a polyethylene-terephthalate back layer of a first non- woven material such that an adhesion with the first non- woven material can be created.
Preferably the back layer of polyethylene-terephthalate of the first non-woven material is perforated by means of a treatment with needles, such that the adjoining first polyethylene layer with a melting point of 109°C can penetrate it. Another advantage of such adhesive barrier layer is that the second and pure polyethylene layer on the opposite side of the polyamide layer prevents tearing of the polyamide barrier layer in case of mechanical deformation.
An added advantage of such an adhesive barrier layer is that the third polyethylene layer with a melting point of 73°C can fuse with a second non-woven material which is thermoformable and in turn consists of
- an insulation layer of PET/coPET fibres.
All this ensures that the first non-woven material which is in contact with the passengers of the vehicle is separated by an adhesive water- and steam-tight barrier layer from the second non-woven material which is in contact with the bodywork of the vehicle. The acoustically insulating barrier layer also ensures a sound insulating effect for the passengers and a permanent watertight seal between the two non-woven materials.
Preferably, the acoustically insulating polyamide barrier layer is provided along one side with a tie layer consisting of a terpolymere of ethylene, butylacrylate and maleic anhydride with a melting point of 91°C for tying the first water- and steam-tight polyethylene/ethylene vinyl acetate copolymer layer with 5 weight% ethylene vinyl acetate and with a melting point of 109°C and the acoustically insulating polyamide barrier layer is provided along the opposite side with a similar tie layer with an adjusted melting point for tying the second water- and steam-tight and pure polyethylene layer, or the third polyethylene/ethylene vinyl acetate copolymer layer with 22.5 weight% ethylene vinyl acetate and with a melting point of 73°C.
The adhesive water- and steam-tight barrier layer allows the properties of the first non-woven material to be optimally aligned with passenger comfort, in terms of thickness, comfort and look of the carpeting with which the passenger comes into contact, and the properties of the second non- woven material to be optimally aligned with its function as basis of the floor lining which comes into contact with the bodywork and must be fittingly mounted to the form of the bodywork.
With the intention of better showing the characteristics of the invention, a preferred embodiment of an adhesive water and steam-tight barrier layer is described hereinafter, by way of an example without any limiting nature, with reference to the accompanying drawings wherein: figure 1 schematically and in cross-section shows a layer package with an adhesive water- and steam-tight barrier layer according to the invention; figure 2 shows a variant of figure 1.
Figure 1 schematically shows a cross-section, perpendicular to the surface of a layer package 1 with an adhesive water- and steam-tight barrier layer according to the invention, whereby the layer package consists of a first non-woven material 2, a back layer 3 of polyethylene-terephthalate for the first non-woven material 2, and an adhesive water- and steam-tight barrier layer 4 according to the invention under it, consisting of an acoustically insulating barrier layer of polyamide 5 with a first polyethylene/ethylene vinyl acetate copolymer layer 6 with five weight% ethylene vinyl acetate and with a melting point of 109°C along the upperside of the polyamide layer 5 and along the underside provided with a second and pure polyethylene layer 7, which in turn borders a third polyethylene/ethylene vinyl acetate copolymer layer 8 with 22.5 weight% ethylene vinyl acetate and with a melting point of 73°C. A second non-woven material 9 which is thermoformable is located under the third polyethylene layer 8.
Figure 2 shows a variant of figure 1, whereby in this case an insulating bitumen layer 10 is applied between the back layer 3 according to the invention and the first polyethylene/ ethylene vinyl acetate copolymer layer 6 with five weight% ethylene vinyl acetate. The aim of the bitumen layer 10 is to obtain a better sound insulation in certain sensitive points of the surface of the layer package 1 and is only applied in such sensitive points. The operation of the adhesive water- and steam-tight barrier layer 4 according to the invention is very simple and as follows.
The barrier layer 4 was produced in advance by coextrusion, whereby the acoustically insulating polyamide layer 5 is already firmly bound to the first polyethylene layer 6 on its upperside and to the second and pure polyethylene layer 7 on its underside, which is also already fused with the third polyethylene layer 8 by coextrusion. During the thermal and pressure treatment with steam of the layer package 1, the back layer 3 of polyethylene- terephthalate of the first non-woven material 2 will fuse with the first polyethylene/ethylene vinyl acetate copolymer layer 6 with five weight% ethylene vinyl acetate and with a melting point of 109°C which is located along the upperside of the watertight polyamide layer 5. Thanks to this fusing, the first non-woven material 2 is firmly bound to the acoustically insulating polyamide layer 5. At the same time the third polyethylene/ethylene vinyl acetate copolymer layer 8 with 22.5 weight% ethylene vinyl acetate and with a melting point of 73°C will fuse with the second non-woven material 9 in which the melted layer 8 partially penetrates. Thanks to this fusing, the second non- woven material 9 is also firmly bound to the acoustically insulating polyamide layer 5.
The adhesive water- and steam-tight barrier layer 4 hereby ensures a firm and moreover water- and steam-tight adhesion between an upper and a bottom non-woven material under the influence of temperature and pressure, whereby the used steam cannot penetrate through the water- and steam-tight barrier layer thus preventing thermal degradation of the first non- woven material 2 which comes into contact with the passengers in a vehicle for example. The second and pure polyethylene layer 7 is optional and protects the layer package 1 against tears in case of excessive pressure loads, but can also be omitted for a number of applications.
The use of a bitumen layer 10 in the layer package 1 is also optional and typically is restricted to certain points of the layer package 1 which require a higher acoustic insulation.
Preferably, the total thickness of the adhesive water- and steam-tight barrier layer 4 itself varies between 40 micrometers and 250 micrometers. The thickness of a first non-woven material 2 and a second but different non-woven material 9 which are bound together by the adhesive barrier layer 4, varies strongly with the possible applications and can fall within a large range of thicknesses whereby the weight in g/cm 2 can vary from a few tens to a couple of thousands of g/cm 2 .
The present invention is by no means limited to the embodiments described as an example and shown in the figures, but an adhesive water- and steam-tight barrier layer according to the invention can be realised in all kinds of forms and dimensions without departing from the scope of the invention, as is described in the following claims.
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