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Title:
HYDROSILYLATION REACTION CATALYST
Document Type and Number:
WIPO Patent Application WO/2016/024607
Kind Code:
A1
Abstract:
A hydrosilylation reaction catalyst prepared from: a catalyst precursor comprising a transition metal compound, excluding platinum, belonging to group 8-10 of the periodic table, e.g., iron acetate, cobalt acetate, nickel acetate, etc; and a ligand comprising an isocyanide compound such as t-butyl isocyanide. The hydrosilylation reaction catalyst has excellent handling and storage properties. As a result of using this catalyst, a hydrosilylation reaction can be promoted under gentle conditions.

Inventors:
NAGASHIMA HIDEO (JP)
SUNADA YUSUKE (JP)
TAHARA ATSUSHI (JP)
NODA DAISUKE (JP)
SOEJIMA HIROE (JP)
SAKUTA KOJI (JP)
Application Number:
PCT/JP2015/072830
Publication Date:
February 18, 2016
Filing Date:
August 12, 2015
Export Citation:
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Assignee:
UNIV KYUSHU NAT UNIV CORP (JP)
SHINETSU CHEMICAL CO (JP)
International Classes:
B01J31/22; C07F7/08; C07B61/00
Foreign References:
Other References:
SUGINOME MICHINORI ET AL.: "Optically Active Isonitrile Ligand for Palladium-Catalyzed Enantioselective Bis-Silylation of Carbon- Carbon Double Bonds", TETRAHEDRON LETTERS, vol. 38, no. 4, 1997, pages 555 - 558, XP004016672, ISSN: 0040-4039, DOI: doi:10.1016/S0040-4039(96)02370-2
ADAMS K. PAIGE ET AL.: "The Catalytic Activity of Transition Metal Complexes of Sterically Hindered Isocyanides", JOURNAL OF MOLECULAR CATALYSIS, vol. 29, 1985, pages 201 - 208, XP055348157, ISSN: 0304-5102
ITO HAJIME ET AL.: "Synthesis of New Bulky Isocyanide Ligands and Their Use for Rh- catalyzed Hydrosilylation", CHEMISTRY LETTERS, vol. 35, no. 9, 2006, pages 1038 - 1039, XP009500131, ISSN: 0366-7022
Attorney, Agent or Firm:
KOJIMA Takashi et al. (JP)
Takashi Kojima (JP)
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