Title:
INTERMEDIATE FOR BLOCK COPOLYMER, BLOCK COPOLYMER, AND METHODS FOR PRODUCING SAME
Document Type and Number:
WIPO Patent Application WO/2021/140860
Kind Code:
A1
Abstract:
Provided are: a block copolymer which can be used in DSA technologies and has a narrow molecular weight distribution; an intermediate for said block copolymer; and methods for producing same. Specifically, a block copolymer intermediate indicated by general formulas (1) or (2) is used. (In the formulas, R1 and R7 each independently represent a polymerization initiator residue, R2 and R8 each independently represent an aromatic group or an alkyl group, Y1 represents a polymer block of (meth)acrylic ester, Y2 represents a polymer block of styrene or a derivative thereof, and m and n each independently represent an integer of 1–5. R3 represents a C1–6 alkylene group, L indicates a connecting group, R4 indicates a hydrogen atom, a C1–6 alkyl group, or an aromatic group, and R5 and R6 each independently indicate a hydrogen atom or a C1–6 alkyl group.)
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Inventors:
KOU YOUKI (JP)
TANAKA HISAKAZU (JP)
TANAKA HISAKAZU (JP)
Application Number:
PCT/JP2020/047077
Publication Date:
July 15, 2021
Filing Date:
December 17, 2020
Export Citation:
Assignee:
DAINIPPON INK & CHEMICALS (JP)
International Classes:
C08F297/02; C08F265/06
Domestic Patent References:
| WO2016093111A1 | 2016-06-16 | |||
| WO2020255727A1 | 2020-12-24 |
Foreign References:
| JP2010180353A | 2010-08-19 |
Other References:
GOSEKI, R. ET AL.: "Precise synthesis of novel star-branched polymers containing reactive poly(1,4-divinylbenzene) arm(s) by linking reaction of living anionic poly(1,4-divinylbenzene) with chain-(a-phenyl acrylate)- functionalized polymers", MACROMOLECULES, vol. 48, 15 April 2015 (2015-04-15), pages 2370 - 2377, XP055840799
ITO SHOTARO, ISHIZONE TAKASHI, HIRAO AKIRA: "Precise Synthesis of New Exactly Defined Graft Copolymers Made up of Poly(alkyl methacrylate)s by Iterative Methodology Using Living Anionic Polymerization", MACROMOLECULES, vol. 48, no. 22, 24 November 2015 (2015-11-24), US , pages 8307 - 8314, XP055939530, ISSN: 0024-9297, DOI: 10.1021/acs.macromol.5b01908
YOO, H. S. ET AL.: "Precise synthesis of dendrimer-like star-branched poly(tert-butyl methacrylate)s and their block copolymers by a methodology combining a-terminal-functionalized living anionic polymer with a specially designed linking reaction in an iterative fashion", MACROMOLECULES, vol. 45, 9 December 2011 (2011-12-09), pages 100 - 112, XP055840806
KOU, Y. ET AL.: "Block polymers for DSA(directed self assembly) using anionic polymer coupling technology and microreactor technology", JOURNAL PHOTOPOLYMER SCIENCE AND TECHNOLOGY, vol. 32, 24 June 2019 (2019-06-24), pages 417 - 421, XP055840807
YOO, H. S. ET AL.: "Precise synthesis of dendrimer-like star-branched polystyrenes and block copolymers composed of polystyrene and poly (methyl methacrylate) segments by an iterative methodology using living anionic polymerization", MACROMOLECULES, vol. 42, 2009, pages 4558 - 4570, XP055840810
GOSEKI, R. ET AL.: "Cylindrical nanostructure of rigid-rod POSS-containing polymethacrylate from a star-branched block copolymer", ACS MACRO LETTERS, vol. 2, 16 July 2013 (2013-07-16), pages 625 - 629, XP055840812
See also references of EP 4089125A4
ITO SHOTARO, ISHIZONE TAKASHI, HIRAO AKIRA: "Precise Synthesis of New Exactly Defined Graft Copolymers Made up of Poly(alkyl methacrylate)s by Iterative Methodology Using Living Anionic Polymerization", MACROMOLECULES, vol. 48, no. 22, 24 November 2015 (2015-11-24), US , pages 8307 - 8314, XP055939530, ISSN: 0024-9297, DOI: 10.1021/acs.macromol.5b01908
YOO, H. S. ET AL.: "Precise synthesis of dendrimer-like star-branched poly(tert-butyl methacrylate)s and their block copolymers by a methodology combining a-terminal-functionalized living anionic polymer with a specially designed linking reaction in an iterative fashion", MACROMOLECULES, vol. 45, 9 December 2011 (2011-12-09), pages 100 - 112, XP055840806
KOU, Y. ET AL.: "Block polymers for DSA(directed self assembly) using anionic polymer coupling technology and microreactor technology", JOURNAL PHOTOPOLYMER SCIENCE AND TECHNOLOGY, vol. 32, 24 June 2019 (2019-06-24), pages 417 - 421, XP055840807
YOO, H. S. ET AL.: "Precise synthesis of dendrimer-like star-branched polystyrenes and block copolymers composed of polystyrene and poly (methyl methacrylate) segments by an iterative methodology using living anionic polymerization", MACROMOLECULES, vol. 42, 2009, pages 4558 - 4570, XP055840810
GOSEKI, R. ET AL.: "Cylindrical nanostructure of rigid-rod POSS-containing polymethacrylate from a star-branched block copolymer", ACS MACRO LETTERS, vol. 2, 16 July 2013 (2013-07-16), pages 625 - 629, XP055840812
See also references of EP 4089125A4
Attorney, Agent or Firm:
OGAWA Shinji (JP)
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