Title:
METAL-ORGANIC FRAMEWORK, AND METHOD FOR MANUFACTURING SAME
Document Type and Number:
WIPO Patent Application WO/2022/014702
Kind Code:
A1
Abstract:
Provided are a metal-organic framework suitably used as a functional material, and a method for manufacturing same, the metal-organic framework containing a cluster (α) and a cluster (β) as constituent units respectively, wherein the cluster (α) contains a metal ion (Mα ion) and ligands (ligands Lα) that coordinate with the Mα ion, the cluster (β) contains a cubane-type structure containing a metal ion (Mβ ion) as an essential component, and at least one of the ligands Lα is a polydentate ligand (ligand Lα
1) that also coordinates with the Mβ ion.
Inventors:
KONNO TAKUMI (JP)
YOSHINARI NOBUTO (JP)
NAKAZAWA YASUHIRO (JP)
YAMASHITA SATOSHI (JP)
YOSHINARI NOBUTO (JP)
NAKAZAWA YASUHIRO (JP)
YAMASHITA SATOSHI (JP)
Application Number:
PCT/JP2021/026797
Publication Date:
January 20, 2022
Filing Date:
July 16, 2021
Export Citation:
Assignee:
JAPAN SCIENCE & TECH AGENCY (JP)
International Classes:
C07C53/08; C07C323/58; C07F1/08; C07F3/06; C07F5/00; C07F15/00; C07F15/04; C07F15/06; C07F19/00
Other References:
BARCLAY J. ELAINE, M.ISABEL DIAZ, DAVID J. EVANS, GABRIEL GARCIA, M. DOLORES SANTANA, M. CARMEN TORRALBA: "The binding of amino acids to the differentiated iron in 3:1 site- differentiated {Fe4S4} clusters", INORGANICA CHIMICA ACTA, ELSEVIER BV, NL, vol. 258, no. 2, 30 May 1997 (1997-05-30), NL , pages 211 - 219, XP055898577, ISSN: 0020-1693, DOI: 10.1016/S0020-1693(96)05515-6
IGASHIRA-KAMIYAMA ASAKO, FUJIOKA JUNJI, MITSUNAGA SEIICHI, NAKANO MOTOHIRO, KAWAMOTO TATSUYA, KONNO TAKUMI: "A new class of hydroxo-bridged heptacopper(II) clusters with an acentrosymmetric corner-sharing double- cuba ne framework supported by D-penicillaminedisulfides", CHEMISTRY - A EUROPEAN JOURNAL, vol. 14, no. 31, 30 November 2007 (2007-11-30), DE, pages 9512 - 9515, XP009534213, ISSN: 0947-6539, DOI: 10.1002/chem.200801299
YOSHINARI NOBUTO, YAMASHITA SATOSHI, FUKUDA YOSUKE, NAKAZAWA YASUHIRO, KONNO TAKUMI: "Mobility of hydrated alkali metal ions in metallosupramolecular ionic crystals", CHEMICAL SCIENCE, ROYAL SOCIETY OF CHEMISTRY, UNITED KINGDOM, vol. 10, no. 2, 2 January 2019 (2019-01-02), United Kingdom , pages 587 - 593, XP055898578, ISSN: 2041-6520, DOI: 10.1039/C8SC04204G
YOSHINARI, NOBUTO; SODKHOMKHUM, RAPHEEPRAEW; FUKUDA, YOSUKE; KONNO, TAKUMI: "3PA-032 Transition Metal Ion Exchange on Single Crystals of an Anionic RhIII4ZnII4 Octanuclear Complex with L-Cysteinate", 67TH JSCC CONFERENCE, JAPAN SOCIETY OF COORDINATION CHEMISTRY; SAPPORO, JAPAN; SEPTEMBER 16-18, 2017, vol. 67, 1 September 2017 (2017-09-01) - 18 September 2017 (2017-09-18), pages 280, XP009534246
YOSHINARI NOBUTO, NATTHAYA MEUNDAENG, HIROYASU TABE, YUSUKE YAMADA, SATOSHI YAMASHITA, YASUHIRO NAKAZAWA, TAKUMI KONNO: "Single-crystal-to- single-crystal installation of Ln4(OH)4 cuba nes in an anionic metallosupramolecular framework", ANGEWANDTE CHEMIE INTERNATIONAL EDITION, ¬VERLAG CHEMIE| :, vol. 59, 13 August 2020 (2020-08-13), pages 18048 - 18053, XP055898584, ISSN: 1433-7851, DOI: 10.1002/anie.202008296
YOSHINARI, NOBUTO ET AL.: "Synthesis of highly functional rare earth hydroxide clusters: Method for simple synthesis in the crystal that does not require strict reaction conditions", KAGAKU - CHEMISTRY, KAGAKU DOJIN, KYOTO, JP, vol. 76, no. 3, 1 March 2021 (2021-03-01), JP , pages 43 - 46, XP009534230, ISSN: 0451-1964
IGASHIRA-KAMIYAMA ASAKO, FUJIOKA JUNJI, MITSUNAGA SEIICHI, NAKANO MOTOHIRO, KAWAMOTO TATSUYA, KONNO TAKUMI: "A new class of hydroxo-bridged heptacopper(II) clusters with an acentrosymmetric corner-sharing double- cuba ne framework supported by D-penicillaminedisulfides", CHEMISTRY - A EUROPEAN JOURNAL, vol. 14, no. 31, 30 November 2007 (2007-11-30), DE, pages 9512 - 9515, XP009534213, ISSN: 0947-6539, DOI: 10.1002/chem.200801299
YOSHINARI NOBUTO, YAMASHITA SATOSHI, FUKUDA YOSUKE, NAKAZAWA YASUHIRO, KONNO TAKUMI: "Mobility of hydrated alkali metal ions in metallosupramolecular ionic crystals", CHEMICAL SCIENCE, ROYAL SOCIETY OF CHEMISTRY, UNITED KINGDOM, vol. 10, no. 2, 2 January 2019 (2019-01-02), United Kingdom , pages 587 - 593, XP055898578, ISSN: 2041-6520, DOI: 10.1039/C8SC04204G
YOSHINARI, NOBUTO; SODKHOMKHUM, RAPHEEPRAEW; FUKUDA, YOSUKE; KONNO, TAKUMI: "3PA-032 Transition Metal Ion Exchange on Single Crystals of an Anionic RhIII4ZnII4 Octanuclear Complex with L-Cysteinate", 67TH JSCC CONFERENCE, JAPAN SOCIETY OF COORDINATION CHEMISTRY; SAPPORO, JAPAN; SEPTEMBER 16-18, 2017, vol. 67, 1 September 2017 (2017-09-01) - 18 September 2017 (2017-09-18), pages 280, XP009534246
YOSHINARI NOBUTO, NATTHAYA MEUNDAENG, HIROYASU TABE, YUSUKE YAMADA, SATOSHI YAMASHITA, YASUHIRO NAKAZAWA, TAKUMI KONNO: "Single-crystal-to- single-crystal installation of Ln4(OH)4 cuba nes in an anionic metallosupramolecular framework", ANGEWANDTE CHEMIE INTERNATIONAL EDITION, ¬VERLAG CHEMIE| :, vol. 59, 13 August 2020 (2020-08-13), pages 18048 - 18053, XP055898584, ISSN: 1433-7851, DOI: 10.1002/anie.202008296
YOSHINARI, NOBUTO ET AL.: "Synthesis of highly functional rare earth hydroxide clusters: Method for simple synthesis in the crystal that does not require strict reaction conditions", KAGAKU - CHEMISTRY, KAGAKU DOJIN, KYOTO, JP, vol. 76, no. 3, 1 March 2021 (2021-03-01), JP , pages 43 - 46, XP009534230, ISSN: 0451-1964
Attorney, Agent or Firm:
OHISHI Haruhito (JP)
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