Title:
METAL-ORGANIC FRAMEWORK WITH CARBOXYLIC ACID ION HAVING TERPHENYL SKELETON AS LIGAND
Document Type and Number:
WIPO Patent Application WO/2021/172433
Kind Code:
A1
Abstract:
A problem addressed by the present invention is to provide a novel metal-organic framework with a dicarboxylic acid having a terphenyl skeleton as an organic ligand, and a gas storage method using the same. A metal-organic framework obtained by bonding a carboxylic acid ion represented by formula (I) and a polyvalent metal ion. (In formula (I), R1 and R2 each independently represent a hydroxy group, a substituted or unsubstituted C1-6 alkyl group, etc. R10 and R11 each independently represent a substituted or unsubstituted C1-6 alkyl group, etc. R20 represents a substituted or unsubstituted C1-6 alkyl group, etc. However, a carboxy group (COOH) and carboxylic acid ion group (COO-) are excluded as substituents on R1, R2, R3, R4, R5, R6, R7, R8, R10, R11, and R20. Also, R10 and R11 may not simultaneously be methyl groups.)
Inventors:
MINOURA MAO (JP)
SUGAMATA KOH (JP)
IIHAMA TERUYUKI (JP)
SUGAMATA KOH (JP)
IIHAMA TERUYUKI (JP)
Application Number:
PCT/JP2021/007113
Publication Date:
September 02, 2021
Filing Date:
February 25, 2021
Export Citation:
Assignee:
RIKKYO EDUCATIONAL CORP (JP)
NIPPON SODA CO (JP)
NIPPON SODA CO (JP)
International Classes:
C07C63/331; B01J20/22; C07F1/08; C07F3/06; C07F7/00; C07F15/04
Domestic Patent References:
| WO2015195179A2 | 2015-12-23 | |||
| WO2009133366A2 | 2009-11-05 | |||
| WO2015079229A1 | 2015-06-04 |
Foreign References:
| JP2015510490A | 2015-04-09 | |||
| US20130122297A1 | 2013-05-16 | |||
| JP2020032043A | 2020-03-05 | |||
| US20100075123A1 | 2010-03-25 |
Other References:
FLAIG ROBINSON W., OSBORN POPP THOMAS M., FRACAROLI ALEJANDRO M., KAPUSTIN EUGENE A., KALMUTZKI MARKUS J., ALTAMIMI RASHID M., FAT: "The Chemistry of CO 2 Capture in an Amine-Functionalized Metal–Organic Framework under Dry and Humid Conditions", JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, AMERICAN CHEMICAL SOCIETY, vol. 139, no. 35, 6 September 2017 (2017-09-06), pages 12125 - 12128, XP055850605, ISSN: 0002-7863, DOI: 10.1021/jacs.7b06382
YUTA GOTO, HIROKI SATO, SEIJI SHINKAI, KAZUKI SADA: "“Clickable” Metal−Organic Framework", JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, AMERICAN CHEMICAL SOCIETY|, vol. 130, no. 44, 5 November 2008 (2008-11-05), pages 14354 - 14355, XP055119605, ISSN: 00027863, DOI: 10.1021/ja7114053
DIANNE J. XIAO, JULIA OKTAWIEC, PHILLIP J. MILNER, JEFFREY R. LONG: "Pore Environment Effects on Catalytic Cyclohexane Oxidation in Expanded Fe 2 (dobdc) Analogues", JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, AMERICAN CHEMICAL SOCIETY, vol. 138, no. 43, 2 November 2016 (2016-11-02), pages 14371 - 14379, XP055715475, ISSN: 0002-7863, DOI: 10.1021/jacs.6b08417
H. LI, M. EDDAUDI, M. O'KEEFE, 0. M. YAGHI, NATURE, vol. 402, 1999, pages 276
M. EDDAUDIJ. KIMN. ROSID. VODAKJ. WACHTERM. O'KEEFE0. M. YAGHI, SCIENCE, vol. 295, no. 5554, 2002, pages 469
S. KAYEA. DAILY0. M. YAGHIJ. LONG, J. AM. CHEM. SOC., vol. 129, no. 46, 2007, pages 14176
YUTA GOTO, HIROKI SATO, SEIJI SHINKAI, KAZUKI SADA: "“Clickable” Metal−Organic Framework", JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, AMERICAN CHEMICAL SOCIETY|, vol. 130, no. 44, 5 November 2008 (2008-11-05), pages 14354 - 14355, XP055119605, ISSN: 00027863, DOI: 10.1021/ja7114053
DIANNE J. XIAO, JULIA OKTAWIEC, PHILLIP J. MILNER, JEFFREY R. LONG: "Pore Environment Effects on Catalytic Cyclohexane Oxidation in Expanded Fe 2 (dobdc) Analogues", JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, AMERICAN CHEMICAL SOCIETY, vol. 138, no. 43, 2 November 2016 (2016-11-02), pages 14371 - 14379, XP055715475, ISSN: 0002-7863, DOI: 10.1021/jacs.6b08417
H. LI, M. EDDAUDI, M. O'KEEFE, 0. M. YAGHI, NATURE, vol. 402, 1999, pages 276
M. EDDAUDIJ. KIMN. ROSID. VODAKJ. WACHTERM. O'KEEFE0. M. YAGHI, SCIENCE, vol. 295, no. 5554, 2002, pages 469
S. KAYEA. DAILY0. M. YAGHIJ. LONG, J. AM. CHEM. SOC., vol. 129, no. 46, 2007, pages 14176
Attorney, Agent or Firm:
HIROTA, Masanori (JP)
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