Title:
METAL-ORGANIC STRUCTURAL BODY
Document Type and Number:
WIPO Patent Application WO/2020/230756
Kind Code:
A1
Abstract:
The present invention addresses the problem of providing a metal-organic structural body capable of adsorbing gases such as carbon dioxide and hydrogen molecules at a practical level for use. This metal-organic structural body is used for adsorbing gases such as carbon dioxide and hydrogen and includes a multivalent metal ion and a carboxylate ion represented by formula [I] [in formula [I], X1-X3 each independently represent a functional group represented by formula [II] (in formula [II], Z represents a single bond or a multivalent linkage group, k represents an integer of 1-4, * indicates the position at which a bond is formed with a benzene ring, Y1 and Y2 each independently represent a hydrogen atom, a halogeno group, a C1-6 alkyl group, or the like, but, when said multivalent metal ion is a trivalent metal ion, Y1 and Y2 each independently represent a halogeno group, a C1-6 alkyl group, or the like)], wherein the carboxylate ion and the multivalent metal ion are bound to each other.
Inventors:
MINOURA MAO (JP)
SUGAMATA KOH (JP)
YANAGISAWA DAICHI (JP)
IIHAMA TERUYUKI (JP)
SUGAMATA KOH (JP)
YANAGISAWA DAICHI (JP)
IIHAMA TERUYUKI (JP)
Application Number:
PCT/JP2020/018825
Publication Date:
November 19, 2020
Filing Date:
May 11, 2020
Export Citation:
Assignee:
RIKKYO EDUCATIONAL CORP (JP)
NIPPON SODA CO (JP)
NIPPON SODA CO (JP)
International Classes:
C07C63/49; B01D53/02; B01J20/22; B01J20/26; C07C63/66; C07C63/72; C07C63/74; C07F1/08; C07F3/02; C07F3/06; C07F5/06; C07F7/00; C07F11/00
Domestic Patent References:
| WO2009098001A1 | 2009-08-13 | |||
| WO2009098001A1 | 2009-08-13 |
Foreign References:
| JP2018058814A | 2018-04-12 | |||
| JP2019090662A | 2019-06-13 | |||
| JP2019172510A | 2019-10-10 | |||
| JP2018058814A | 2018-04-12 |
Other References:
ANGELA K. CRANE, PATRICK BRIAN O., MACLACHLAN MARK J.: "New metal–organic frameworks from triptycene: structural diversity from bulky bridges", DALTON TRANSACTIONS, vol. 42, no. 22, 1 January 2013 (2013-01-01), pages 8026, XP055761067, ISSN: 1477-9226, DOI: 10.1039/c3dt00079f
ZHIJIE CHEN, PENGHAO LI, XUAN ZHANG, PENG LI, MEGAN C. WASSON, TIMUR ISLAMOGLU, J. FRASER STODDART, OMAR K. FARHA: "-MOFs with Rigid Trigonal Prismatic Linkers for Water Sorption", JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, AMERICAN CHEMICAL SOCIETY, US, vol. 141, no. 7, 20 February 2019 (2019-02-20), US, pages 2900 - 2905, XP055761075, ISSN: 0002-7863, DOI: 10.1021/jacs.8b13710
ZHIJIE CHEN, PENGHAO LI, RYTHER ANDERSON, XINGJIE WANG, XUAN ZHANG, LEE ROBISON, LOUIS R REDFERN, SHINYA MORIBE, TIMUR ISLAMOGLU, : "Balancing volumetric and gravimetric uptake in highly porous materials for clean energy", SCIENCE (AMERICAN ASSOCIATION FOR THE ADVANCEMENT OF SCIENCE), AMERICAN ASSOCIATION FOR THE ADVANCEMENT OF SCIENCE (AAAS), UNITED STATES, 1 January 2020 (2020-01-01), United States, pages 297 - 303, XP055761118, DOI: 10.1126/science.aaz8881
PUJARI CHANDRASEKHAR, ARINDAM MUKHOPADHYAY, GOVARDHAN SAVITHA, JARUGU NARASIMHA MOORTHY: "Orthogonal self-assembly of a trigonal triptycene triacid: signaling of exfoliation of porous 2D metal–organic layers by fluorescence and selective CO 2 capture by the hydrogen-bonded MOF", JOURNAL OF MATERIALS CHEMISTRY A, ROYAL SOCIETY OF CHEMISTRY, GB, vol. 5, no. 11, 1 January 2017 (2017-01-01), GB, pages 5402 - 5412, XP055761125, ISSN: 2050-7488, DOI: 10.1039/C6TA11110F
PUJARI CHANDRASEKHAR, GOVARDHAN SAVITHA , JARUGU NARASIMHA MOORTHY: "Robust MOFs of 'tsg' Topology Based on Trigonal Prismatic Organic and Metal Cluster SBUs: Single Crystal to Single Crystal Postsynthetic Metal Exchange and Selective C02 Capture", CHEMISTRY-A EUROPEAN JOURNAL, vol. 23, no. 30, 29 May 2017 (2017-05-29), pages 7297 - 7305, XP055865639, ISSN: 0947-6539, DOI: 10.1002/chem.201700139
PENGHAO LI, PENG LI, MATTHEW R. RYDER, ZHICHANG LIU, CHARLOTTE L. STERN, OMAR K. FARHA, J. FRASER STODDART: "Interpenetration Isomerism in Triptycene-Based Hydrogen-Bonded Organic Frameworks", ANGEWANDTE CHEMIE, vol. 58, no. 6, 4 February 2019 (2019-02-04), pages 1664 - 1669, XP055865640, ISSN: 1433-7851, DOI: 10.1002/anie.201811263
J. F. STODDART ET AL., ANGEW. CHEM., vol. 58, 2019, pages 1664 - 1669
J. F. STODDART ET AL., J. AM. CHEM. SOC., vol. 141, 2019, pages 2900 - 2905
See also references of EP 3971163A4
ZHIJIE CHEN, PENGHAO LI, XUAN ZHANG, PENG LI, MEGAN C. WASSON, TIMUR ISLAMOGLU, J. FRASER STODDART, OMAR K. FARHA: "-MOFs with Rigid Trigonal Prismatic Linkers for Water Sorption", JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, AMERICAN CHEMICAL SOCIETY, US, vol. 141, no. 7, 20 February 2019 (2019-02-20), US, pages 2900 - 2905, XP055761075, ISSN: 0002-7863, DOI: 10.1021/jacs.8b13710
ZHIJIE CHEN, PENGHAO LI, RYTHER ANDERSON, XINGJIE WANG, XUAN ZHANG, LEE ROBISON, LOUIS R REDFERN, SHINYA MORIBE, TIMUR ISLAMOGLU, : "Balancing volumetric and gravimetric uptake in highly porous materials for clean energy", SCIENCE (AMERICAN ASSOCIATION FOR THE ADVANCEMENT OF SCIENCE), AMERICAN ASSOCIATION FOR THE ADVANCEMENT OF SCIENCE (AAAS), UNITED STATES, 1 January 2020 (2020-01-01), United States, pages 297 - 303, XP055761118, DOI: 10.1126/science.aaz8881
PUJARI CHANDRASEKHAR, ARINDAM MUKHOPADHYAY, GOVARDHAN SAVITHA, JARUGU NARASIMHA MOORTHY: "Orthogonal self-assembly of a trigonal triptycene triacid: signaling of exfoliation of porous 2D metal–organic layers by fluorescence and selective CO 2 capture by the hydrogen-bonded MOF", JOURNAL OF MATERIALS CHEMISTRY A, ROYAL SOCIETY OF CHEMISTRY, GB, vol. 5, no. 11, 1 January 2017 (2017-01-01), GB, pages 5402 - 5412, XP055761125, ISSN: 2050-7488, DOI: 10.1039/C6TA11110F
PUJARI CHANDRASEKHAR, GOVARDHAN SAVITHA , JARUGU NARASIMHA MOORTHY: "Robust MOFs of 'tsg' Topology Based on Trigonal Prismatic Organic and Metal Cluster SBUs: Single Crystal to Single Crystal Postsynthetic Metal Exchange and Selective C02 Capture", CHEMISTRY-A EUROPEAN JOURNAL, vol. 23, no. 30, 29 May 2017 (2017-05-29), pages 7297 - 7305, XP055865639, ISSN: 0947-6539, DOI: 10.1002/chem.201700139
PENGHAO LI, PENG LI, MATTHEW R. RYDER, ZHICHANG LIU, CHARLOTTE L. STERN, OMAR K. FARHA, J. FRASER STODDART: "Interpenetration Isomerism in Triptycene-Based Hydrogen-Bonded Organic Frameworks", ANGEWANDTE CHEMIE, vol. 58, no. 6, 4 February 2019 (2019-02-04), pages 1664 - 1669, XP055865640, ISSN: 1433-7851, DOI: 10.1002/anie.201811263
J. F. STODDART ET AL., ANGEW. CHEM., vol. 58, 2019, pages 1664 - 1669
J. F. STODDART ET AL., J. AM. CHEM. SOC., vol. 141, 2019, pages 2900 - 2905
See also references of EP 3971163A4
Attorney, Agent or Firm:
HIROTA, Masanori (JP)
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