Title:
METHOD FOR CATALYTICALLY ACTIVATING CARBON DIOXIDE AS CARBONYLATION REAGENT WITH INORGANIC SULFUR
Document Type and Number:
WIPO Patent Application WO/2022/135355
Kind Code:
A1
Abstract:
Provided is a method for catalytically activating carbon dioxide as a carbonylation reagent with inorganic sulfur. In the method, carbon dioxide can be used to replace a toxic and harmful carbonylation reagent in the presence of H2S and an alkali for the synthesis of a carbonyl-containing fine chemical product. The method has a relatively high atomic economy and can reduce the generation of by-products.
Inventors:
ZHU NING (CN)
HE RONGTING (CN)
CHENG SILIU (CN)
YU LILI (CN)
WU JIAKAI (CN)
SHI GUANGHUI (CN)
WANG YANG (CN)
FANG TINGXUAN (CN)
HONG HAILONG (CN)
HAN LIMIN (CN)
HE RONGTING (CN)
CHENG SILIU (CN)
YU LILI (CN)
WU JIAKAI (CN)
SHI GUANGHUI (CN)
WANG YANG (CN)
FANG TINGXUAN (CN)
HONG HAILONG (CN)
HAN LIMIN (CN)
Application Number:
PCT/CN2021/139810
Publication Date:
June 30, 2022
Filing Date:
December 20, 2021
Export Citation:
Assignee:
UNIV INNER MONGOLIA TECHNOLOGY (CN)
International Classes:
C07D277/68; C07C273/18
Foreign References:
| CN108440445A | 2018-08-24 | |||
| US20040116518A1 | 2004-06-17 |
Other References:
ZHU NING ET AL: "Study on the Synthesis of Benzothiine U-type Compounds Based on the Construction of C-S Bonds by Activated CO2", TECHNOLOGICAL ACHIEVEMENTS, 31 December 2019 (2019-12-31), CN, pages 1 - 4, XP009538035
YU BO, ZHANG HONGYE, ZHAO YANFEI, CHEN SHA, XU JILEI, HAO LEIDUAN, LIU ZHIMIN: "DBU-Based Ionic-Liquid-Catalyzed Carbonylation of o -Phenylenediamines with CO 2 to 2-Benzimidazolones under Solvent-Free Conditions", ACS CATALYSIS, vol. 3, no. 9, 6 September 2013 (2013-09-06), US , pages 2076 - 2082, XP055944663, ISSN: 2155-5435, DOI: 10.1021/cs400256j
SANG, GUOZHI ET AL.: "Synthesis of o-Halothiobenzamide Derivatives From the Selective Thiolysis Reaction of O-Halobenzonitrile Mediated by CO2", CHINESE JOURNAL OF ORGANIC CHEMISTRY, vol. 39, no. 12, 1 August 2019 (2019-08-01), pages 3542 - 3549, XP055944667
YU BO, ZHANG HONGYE, ZHAO YANFEI, CHEN SHA, XU JILEI, HAO LEIDUAN, LIU ZHIMIN: "DBU-Based Ionic-Liquid-Catalyzed Carbonylation of o -Phenylenediamines with CO 2 to 2-Benzimidazolones under Solvent-Free Conditions", ACS CATALYSIS, vol. 3, no. 9, 6 September 2013 (2013-09-06), US , pages 2076 - 2082, XP055944663, ISSN: 2155-5435, DOI: 10.1021/cs400256j
SANG, GUOZHI ET AL.: "Synthesis of o-Halothiobenzamide Derivatives From the Selective Thiolysis Reaction of O-Halobenzonitrile Mediated by CO2", CHINESE JOURNAL OF ORGANIC CHEMISTRY, vol. 39, no. 12, 1 August 2019 (2019-08-01), pages 3542 - 3549, XP055944667
Attorney, Agent or Firm:
XU & PARTNERS, LLC. (CN)
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