Title:
METHOD FOR HYDROBORATION OF CARBONATE
Document Type and Number:
WIPO Patent Application WO/2021/253868
Kind Code:
A1
Abstract:
The present invention relates to a carbonate hydroboration reaction, and particularly relates to a hydroboration reaction method with a carbonate and borane as raw materials. β-ketimines, as an important class of non-metallocene ligands, have the characteristics of being easy to synthesize, with the charge and steric effect thereof being conveniently regulated by changing α and β substituents, being able to be coordinated with a metal in a number of coordination manners to form structurally diverse metal complexes, etc. The present invention provides a new method for the hydroboration of a carbonate and has a good range of applicable substrates.
Inventors:
XUE MINGQIANG (CN)
ZHOU SHUAI (CN)
XU XIAOJUAN (CN)
KANG ZIHAN (CN)
CHEN SUFANG (CN)
ZHU ZHANGYE (CN)
ZHOU SHUAI (CN)
XU XIAOJUAN (CN)
KANG ZIHAN (CN)
CHEN SUFANG (CN)
ZHU ZHANGYE (CN)
Application Number:
PCT/CN2021/078341
Publication Date:
December 23, 2021
Filing Date:
February 27, 2021
Export Citation:
Assignee:
UNIV SOOCHOW (CN)
International Classes:
C07F5/04; B01J31/22; C07F1/02
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Other References:
XU, XIAOJUAN: "Tris(Bis (Trimethylsilyl) Amino) Lanthanide Complexes and the Deprotonated β-ketoimine Lithium Compound and Their Application in Hydroboration", CHINESE MASTER'S THESES FULL-TEXT DATABASE, no. 2, 15 February 2021 (2021-02-15), pages 1 - 133, XP055882722, ISSN: 1674-0246, DOI: 10.27351/d.cnki.gszhu.2020.003223
MAN LUO;SHENLUO ZANG;WEIWEI YAO;JING ZHENG;MENGTAO MA: "Recent Advances in Alkaline Earth Metal Catalyzed Hydroboration Reactions", SCIENTIA SINICA(CHIMICA), vol. 50, no. 6, 1 June 2020 (2020-06-01), pages 639 - 654, XP055882825, ISSN: 1674-7224
SUN YUE, GUAN RUI, LIU ZHAOHONG, WANG YEMING: "Recent Advances in Hydroboration of Alkenes Catalyzed by Fe, Co and Ni", CHINESE JOURNAL OF ORGANIC CHEMISTRY, vol. 40, no. 4, 19 December 2019 (2019-12-19), pages 899 - 912, XP055882830, ISSN: 0253-2786, DOI: 10.6023/cjoc201909035
PAN HUIFEN: "The Synthesis and Catalytic Properties of Main Group-,Transition-and Rare Earth-Organometallic Compounds Based on β-Diketiminate Ligands", CHINESE MASTER'S THESES FULL-TEXT DATABASE, no. 6, 1 August 2019 (2019-08-01), pages 1 - 105, XP055882832, DOI: 10.27351/d.cnki.gszhu.2019.002964
MAN LUO;SHENLUO ZANG;WEIWEI YAO;JING ZHENG;MENGTAO MA: "Recent Advances in Alkaline Earth Metal Catalyzed Hydroboration Reactions", SCIENTIA SINICA(CHIMICA), vol. 50, no. 6, 1 June 2020 (2020-06-01), pages 639 - 654, XP055882825, ISSN: 1674-7224
SUN YUE, GUAN RUI, LIU ZHAOHONG, WANG YEMING: "Recent Advances in Hydroboration of Alkenes Catalyzed by Fe, Co and Ni", CHINESE JOURNAL OF ORGANIC CHEMISTRY, vol. 40, no. 4, 19 December 2019 (2019-12-19), pages 899 - 912, XP055882830, ISSN: 0253-2786, DOI: 10.6023/cjoc201909035
PAN HUIFEN: "The Synthesis and Catalytic Properties of Main Group-,Transition-and Rare Earth-Organometallic Compounds Based on β-Diketiminate Ligands", CHINESE MASTER'S THESES FULL-TEXT DATABASE, no. 6, 1 August 2019 (2019-08-01), pages 1 - 105, XP055882832, DOI: 10.27351/d.cnki.gszhu.2019.002964
Attorney, Agent or Firm:
SUZHOU CREATOR PATENT AND TRADEMARK AGENCY, LTD (CN)
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