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Title:
METHOD FOR OXIDIZING ALCOHOLS
Document Type and Number:
WIPO Patent Application WO/2012/008228
Kind Code:
A1
Abstract:
Disclosed is a method for oxidizing alcohols, wherein it is possible to efficiently oxidize primary alcohols and secondary alcohols and to achieve high reaction efficiency even when air is used as the bulk oxidant. Specifically disclosed is a method for performing oxidization in the presence of a compound represented by formula (I) and a bulk oxidant.

Inventors:
IWABUCHI YOSHIHARU (JP)
HAYASHI MASAKI (JP)
Application Number:
PCT/JP2011/062324
Publication Date:
January 19, 2012
Filing Date:
May 30, 2011
Export Citation:
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Assignee:
DAIICHI SANKYO CO LTD (JP)
UNIV TOHOKU (JP)
IWABUCHI YOSHIHARU (JP)
HAYASHI MASAKI (JP)
International Classes:
C07C45/30; B01J31/02; C07C45/38; C07C45/39; C07C47/228; C07C47/575; C07C49/04; C07C49/213; C07C49/407; C07C49/437; C07C49/453; C07C49/657; C07C49/76; C07C49/784; C07C269/06; C07C271/24; C07D213/50; C07H9/04; C07H19/16; C07B53/00; C07B61/00
Domestic Patent References:
WO2006001387A12006-01-05
WO2011027865A12011-03-10
WO2009145323A12009-12-03
WO2006001387A12006-01-05
Foreign References:
JP2009161613A2009-07-23
JP2009114143A2009-05-28
FR2219159A11974-09-20
JP2008212853A2008-09-18
Other References:
DUPEYRE R; RASSAT A: "Nitroxides LXXIII: Oxidation of secondary and tertiary amines with potassium permanganate in a basic medium", TETRAHEDRON LETTERS, no. 22-23, 1975, pages 1839 - 1840, XP002990391
YOSUKE DEMIZU ET AL.: "Efficient oxidation of alcohols electrochemically mediated by azabicyclo-N-oxyls", TETRAHEDRON LETTERS, vol. 49, no. 1, January 2008 (2008-01-01), pages 48 - 52, XP022374252
See also references of EP 2594550A4
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THE JOURNAL OF ORGANIC CHEMISTRY, vol. 74, no. 12, 2009, pages 4619 - 4622
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TETRAHEDRON LETTERS, vol. 50, 2009, pages 1493 - 1494
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GREEN ET AL.: "Protective Groups in Organic Synthesis", 1999, JOHN WILEY & SONS, INC.
Attorney, Agent or Firm:
SIKs & Co. (JP)
Patent business corporation patent firm Sykes (JP)
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Claims: