RAW MATERIAL AND TO RECYCLE CIGARETTE BUTTS

DESCRIPTION

Field of application

The present invention is generally applicable to the technical field of the production of thermoplastic polymers to be used as raw materials in the manufacturing of objects through hot-forming processes. In particular, the object of the invention is to produce cellulose diacetate obtained by cigarette filters.

State of the Art

As known, most part of cigarette filters is made of cellulose diacetate, also commonly known as“cellulose acetate”. For the sake of simplicity, the term cellulose acetate will be used hereinafter to mean cellulose diacetate.

The cellulose acetate is a fibrous polymer particularly suited to be used in cigarette filters, because it is very efficient in stopping toxic substances produced by the combustion of the tobacco and the paper of which cigarettes are made.

Nevertheless, every day a large quantity of cigarette butts are thrown in the waste, or worse, on the ground. Despite cellulose acetate is per-se biodegradable, the toxic substances contained in exhausted cigarette filters make the latter highly polluting.

Therefore, the need to prevent the above mentioned source of pollution is more and more felt.

A known technique suggests to reuse cellulose acetate fibers of cigarette filters, duly purified, mixed with other plastic materials to obtain composite materials.

According to a further known technique, the cellulose acetate of the cigarette filters is liquefied through using a suitable solvent, for example acetone, to obtain a material that can be employed to mold objects.

Both the above mentioned known techniques have the drawback of requiring the use of other materials, in particular plastic materials and solvents, that are not biodegradable but, on the contrary, are often pollutants.

The second of the above mentioned known techniques has the further drawback that the thereby obtained objects must be treated in order to eliminate the residues of solvents.

The materials obtained through the above mentioned known techniques have the further drawback of being unsuitable to be used as such as raw materials in the manufacturing of objects, because they require further operations, for example mixing with other plastic materials, or eliminating solvents.

Summary of the invention

The present invention aims at overcoming at least partially the above mentioned drawbacks of the known art.

In particular, it is an aim of the invention that of recycling exhausted cigarette butts through a method having a smaller environmental impact compared to that of the methods of known kind.

Is is also an aim of the invention to obtain from cigarette filters a thermoplastic raw material which can be immediately used in the production of objects made of cellulose acetate.

The above mentioned aims are achieved by a method for obtaining a thermoplastic raw material, according to the main claim.

The above mentioned aims are also achieved by a method for manufacturing an object in cellulose acetate, according to claim 6.

The above mentioned aims are also achieved by a method for recycling exhausted cigarette butts, according to claim 9.

The above mentioned aims are also achieved by a plant to obtain a thermoplastic raw material from the recycle of exhausted cigarette butts, according to claim 10.

Further detail features of the invention are specified in the corresponding dependent claims.

According to a first aspect, the invention concerns a method for obtaining cellulose acetate to be used as a thermoplastic raw material, the method comprising obtaining a plurality of cigarette filters and mixing them at a temperature higher that the ambient temperature, to obtain a homogeneous mass of cellulose acetate that is then formed in the shape of a wire, grain, sheet, or whatever shaped that can be used as thermoplastic raw material in a hot-forming processing.

A variant embodiment of the invention comprises adding a biodegradable plasticizer substance during the mixing of the filters.

A further variant embodiment of the invention comprises obtaining the cigarette filters from exhausted cigarette butts.

A further variant embodiment of the invention comprises using cigarette filters derived from scrap of the manufacturing process of cigarette filters.

According to a further aspect, the invention concerns a method for manufacturing an object obtained through a hot-forming process using the above mentioned thermoplastic raw material.

According to a further aspect, the invention concerns a recycling method to obtain the above mentioned thermoplastic raw material from exhausted cigarette butts.

Advantageously, the invention allows to use cigarette filters that cannot be used any more in order to obtain a thermoplastic raw material suited to be used in hot-forming processes in order to manufacture objects of different kinds.

Still advantageously, obtaining the above mentioned cigarette filters from exhausted cigarette butts allows to reduce the environmental pollution.

Still advantageously, the methods of the invention do not need the use of polluting substances, hence they are particularly sustainable from the environmental point of view.

The above mentioned aims and advantages, together with others that will be mentioned hereinafter, will appear more evidently from the following description of some preferred embodiments of the invention, that are shown by non-limiting examples with the aid of the attached drawings.

Brief description of the drawings Fig. 1 represents a block diagram of the method of the invention to manufacture an object.

Fig. 2 represents a block diagram of a portion of the method of Fig. 1.

Fig. 3 represents a block diagram of the method of the invention to recycle cigarette butts.

Fig. 4 represents the plant of the invention in schematic view.

Detailed description of some preferred embodiments

The method of the invention for manufacturing an object 10 in cellulose acetate is overall indicated in Fig. 1 by 120. Method 120 envisages obtaining a thermoplastic raw material 8 to be used in a hot-forming process 112 to manufacture object 10.

The thermoplastic raw material 8 is obtained through a method that is represented in Fig. 1 as surrounded by a rectangle in dotted lines, overall indicated by 100.

Method 100 comprises first of all an operation 101 of obtaining a plurality of cigarette filters 4 in cellulose acetate.

The above mentioned cigarette filters 4 are then subjected to a mixing operation 110 at a mixing temperature at least equal to 200°C and, even more preferably, at least equal to 210°C, in order to obtain a homogeneous mass 7 of cellulose acetate.

Preferably, the above mentioned mixing 110 occurs in a mixer or equivalent device, provided that it is suited to heat the material to the above indicated temperatures.

Preferably but not necessarily, before the mixing 110 a plasticizer substance 11 is added to filters 4, that, advantageously, facilitates the formation of the homogeneous mass 7.

Preferably, the above mentioned plasticizer substance 11 is soybean oil. Advantageously, since the soybean oil is a non-toxic substance, it is not necessary to remove it from the thermoplastic raw material 8 or from the object 10 once they have been obtained. Still advantageously, the soybean oil is a natural and biodegradable product, hence it does not cause pollution and it facilitates obtaining a low- environmental-impact manufacturing process for the object 10.

Once the above mentioned homogeneous mass 7 is obtained, it is subjected to an operation of plastic deformation processing 111 to obtain the thermoplastic raw material 8 in the preferred form, that can be used e.g. in a hot-forming processing 112 to make object 10.

The above mentioned plastic deformation processing 111 may comprise an operation for extruding the homogeneous mass 7 to obtain a wire in cellulose acetate, that may be used in a three-dimensional printing processing in which the wire is selectively laid down in successive layers until obtaining the object 10.

According to a variant embodiment of the invention, the plastic deformation processing 111 comprises an operation of sizing of the homogeneous mass 7, for example to reduce it in cellulose acetate grains. The above mentioned grains may be used in an injection mold to obtain the object 10.

According to a variant embodiment of method 100, not represented in the drawings, the operation 101 of obtaining cigarette filters 4 comprises using the scraps deriving from the manufacture of cigarette filters.

According to a further variant embodiment of method 100, the operation 101 of obtaining cigarette filters 4 occurs starting from exhausted cigarette butts 1 , as can be seen in Fig. 2.

More precisely, it is known that an exhausted cigarette butt 1 generally contains a cigarette filter 2 in cellulose acetate, besides residues of several materials belonging to the cigarette, such as paper waste 3 and tobacco residues. The used cigarette filter 2 in turn contains toxic waste 5 derived from the combustion of paper and tobacco belonging to the cigarette.

Before the mixing operation 110, the method 100 preferably comprises a first removal 104 of the above mentioned paper waste 3 and tobacco from the cigarette butts 1 , in order to separate used cigarette filters 2 from the above mentioned residues.

Preferably, the above mentioned operation of first removal 104 envisages a pre-washing 106 of the cigarette butts 1 in a pre-washing liquid 9 to cause detachment of the paper waste 3 from the used cigarette filters 2 contained in the cigarette butts 1. Preferably, pre-washing 106 occurs by immersing the cigarette butts 1 in the pre-washing liquid 9 while the pre-washing liquid 9 is in motion, in order to enhance detachment of paper waste 3 from cigarette filters 2. Still preferably, the pre-washing liquid 9 is water, that, advantageously, has no drawbacks as to environmental impact.

After pre-washing 106, a separation operation 107 occurs to separate the used cigarette filters 2 from the paper waste 3. Separation 107 may occur manually, or automatically through the use of a machine.

Still preferably, pre-washing 106 may comprise a plurality of the above mentioned immersion operations, accomplished in succession, and preferably replacing the pre-washing liquid 9 in each operation. The pre-washing 106 may comprise a plurality of the above mentioned separation operation 107, each one of which may be accomplished following a corresponding one of the above mentioned immersion operations.

After the first removal operation 104 and before the mixing operation 110, the method 100 preferably comprises an operation of second removal 105 to remove the above mentioned toxic waste 5 from the used cigarette filters 2.

Preferably, the second removal operation 105 comprises a washing operation 108 to wash used cigarette filters 2 in a washing liquid 6. Still preferably, the washing operation 108 occurs through immersing cigarette filters 2 in the washing liquid 6. Even more preferably, washing operation 108 occurs while the washing liquid 6 is in motion.

Still preferably, the washing liquid 6 is water, that, advantageously, has no drawbacks as to environmental impact. Still more preferably, the washing water is at a temperature higher than 40°C. Moreover, preferably, the washing operation 108 lasts for at least 1 hour. The applicant of the present invention noticed that a washing operation 108 in water with temperature and duration as above disclosed allows to eliminate more than 70% of the toxic waste 5 contained in the used cigarette filters 2, in order to obtain a material that can be used to manufacture commonly used objects 10, provided they are not intended to be used in contact with foodstuff.

Preferably, the temperature of the washing water is higher than 60°, and the duration of the washing operation 108 is at least 2 hours, allowing to further increase the cleanness degree of cigarette filters 2.

According to a variant embodiment of method 100, the washing liquid 6 contains additives suited to increase its power to remove the toxic waste 5. The above mentioned additives may comprise one or more substances among ethyl alcohol, acetone, and other organic solvents.

After the washing operation 108, the method 100 comprises an eliminating operation 109 to eliminate the washing liquid 9 and the pre-washing liquid 6 from used cigarette filters 2, in order to obtain dried cigarette filters 4. The above mentioned eliminating operation 109 is particularly important because, as known, cellulose acetate is a hygroscopic material, and the liquid residues possibly retained in the material during the subsequent operations of the method would lead to a thermoplastic raw material 8 with limited quality.

Preferably, the above mentioned liquid eliminating operation 109 comprises a drying operation, accomplished for example in air at a temperature higher than the ambient temperature, for example higher than 80°C, in order to favor evaporation of liquids 6, 9. Preferably, drying air is kept in movement in order to further favoring the evaporation of the liquids. The accomplishment of the drying operation at a pressure lower than the ambient pressure also favors the evaporation of the liquids.

Preferably, the eliminating operation 109 also comprises an operation of mechanical eliminating the excess liquids, for example by centrifugation of the filters 2. Advantageously, the mechanical elimination of the liquids allows reducing the temperature and the duration of the subsequent drying operation. For example, the mechanical elimination of the liquids allows reducing the temperature of the subsequent drying operation to about 80°C, and the corresponding duration to about 2 hours.

The eliminating operation 109 may comprise a plurality of the above mentioned operations of drying and/or of mechanical elimination of excess liquids, accomplished in sequence.

Preferably, the liquid that is removed through the above mentioned eliminating operation 109 is conveyed to a purification unit that, advantageously, retains the pollutant substances and allows inputting the thereby purified liquid again into the environment, for the benefit of the ecologic sustainability of the method.

As previously said, the invention also concerns a method for recycling used cigarette butts 1 , the method indicated in the overall in Fig. 3 by 130. The above mentioned method 130 comprises a first operation 102 for collecting the cigarette butts 1. The collected cigarette butts 1 are used to obtain a thermoplastic raw material 8 through a method 100 according to any one of the above disclosed variant embodiments. Preferably, the above mentioned thermoplastic raw material 8 is then used in a hot-forming processing 112 to manufacture an object 10 made in cellulose acetate.

Preferably, the above mentioned recycling method 130, after the collection operation 102 and before the execution of the method 100 for obtaining the thermoplastic raw material 8, comprises an operation 103 for eliminating the unwanted materials 12 and aimed at separating the cigarette butts 1 from ash, debris and other waste materials.

Advantageously, the above mentioned eliminating operation 103 allows to obtain a homogeneous material, because in general the cigarette butts 1 resulting from the collection operation 102 are mixed to other waste materials.

The eliminating operation 103 of the above mentioned unwanted materials 12 may occur, for example, through screening or sieving.

Preferably, the methods 100, 120 and 130 above disclosed are performed through a plant of the kind indicated in the overall in Fig. 4 by 20.

The above mentioned plant 20 comprises a sieving unit 21 to separate the cigarette butts 1 , obtained by the collecting operation 102, from the above mentioned unwanted materials 12.

Downstream of the sieving unit 21 a pre-washing unit 22 is arranged in which the cigarette butts 1 are wet with the above mentioned pre-washing liquid 9 to cause the paper waste 3 to detach from the cigarette filters 2.

Preferably but not necessarily, a separation device 27 is envisaged downstream of the pre-washing unit 22 to separate the cigarette filters 2 from the paper waste 3.

Downstream of the pre-washing unit 22 and of the possible separation device 27 a washing unit 23 is arranged, in which the cigarette filters 2 are wet with a washing liquid 6 to remove the above mentioned toxic waste 5.

Downstream of the washing unit 23 a drying unit 24 is arranged, which is configured to eliminate the liquid 6, 9 from the cigarette filters 2 in order to obtain dried cigarette filters 4. Preferably, the drying unit 24 comprises a desiccator, for example of the kind that employs a hot air current and/or a depressurized chamber to facilitate the evaporation of the liquid 6, 9 from the cigarette filters 2.

The above mentioned dried cigarette filters 4 are conveyed to a mixing unit 25 configured to mix and heat the dried cigarette filters 4 in order to obtain the above mentioned homogeneous mass 7. Preferably, the mixing unit 25 comprises a mixing chamber in which one or more rotating bodies are arranged to move, mix, squeeze and/or blend the dried cigarette filters 4.

The movement of the materials along the plant 20 is made by a transport apparatus 26. In particular, the transport apparatus 26 conveys the cigarette butts 1 from the sieving unit 21 to the pre-washing unit 22, conveys the cigarette filters 2 from the pre-washing unit 22 to the washing unit 23 and from the washing unit 23 to the drying unit 24, and also conveys the dried cigarette filters 4 from the drying unit 24 to the mixing unit 25, according to a corresponding feeding direction X indicated in Fig. 4 by an arrow.

Preferably, the plant 20 also comprises an extrusion device 28, for example of the screw type, configured to extrude the homogeneous mass 7 coming from the mixing unit 25 in such a way to obtain the thermoplastic raw material 8 in the requested shape. Still more preferably, the extrusion device 28 belongs to the mixing unit 25, so that the mixing operation occurs simultaneously to the extrusion. As previously mentioned, the homogeneous mass 7 may be machined in such a way as to obtain a thermoplastic raw material 8 in the form of a wire, for example for the use in a three-dimensional printing process, or in granular form, for example for the use in injection processes, or even in the form of a sheet, for example for the use in thermoforming processes, or in any other form suited for the use in any hot- forming process of known kind.

The thermoplastic raw material 8 that may be obtained through the method and through the plant of the invention is suited to manufacture different kinds of objects, such as for example stationery, casings, components for glasses, tool handles, and other commonly used objects.

From the above description, it may be understood that the invention achieves the preset aims.

In particular, the limited or null use of pollutant substances permitted by the invention allows to recycle the exhausted cigarette butts with an environmental impact smaller compared to the methods of known type.

Moreover, the cellulose acetate obtained by the cigarette filters through the method and the plant of the invention is a thermoplastic raw material that may be immediately used for manufacturing objects.

The invention is susceptible of changes and variants, all comprised in the inventive concept expressed in the attached claims. In particular, the elements of the invention may be replaced by other elements technically equivalent.

Moreover, the materials may be chosen according to the needs, yet without departing from the scope of the invention.

Moreover, one or more elements of a specific embodiment of the invention that are technically compatible with another specific embodiment of the invention may be introduced in the latter, in addition or in replacement of elements thereof.

Where technical elements specified in the claims are followed by reference signs, those reference signs are included for the sole aim to improve the intelligibility of the invention, hence they do not involve any limitation of the scope of protection claimed.