Title:
METHOD FOR PREPARING VILSMEIER REAGENT
Document Type and Number:
WIPO Patent Application WO/2020/050368
Kind Code:
A1
Abstract:
The purpose of the present invention is to provide: a method for preparing a Vilsmeier reagent, that can be carried out safely, easily, and at a low cost; and a method for producing an aromatic aldehyde or an aromatic ketone, a carboxylic halide, and a formic ester. A method for preparing a Vilsmeier reagent according to the present invention is characterized by comprising: a step for degrading C1-4 halogenated hydrocarbon by irradiating with light, in the presence of an enzyme, a composition that comprises a C1-4 halogenated hydrocarbon having at least one halogen group selected from the group consisting of chlorine, bromine and iodine; and a step for reacting a degraded product of the C1-4 halogenated hydrocarbon with a specific amide compound.
Inventors:
TSUDA AKIHIKO (JP)
OKAZOE TAKASHI (JP)
WADA AKIHIRO (JP)
MORI NOBUAKI (JP)
KONISHI KATSUHIKO (JP)
OKAZOE TAKASHI (JP)
WADA AKIHIRO (JP)
MORI NOBUAKI (JP)
KONISHI KATSUHIKO (JP)
Application Number:
PCT/JP2019/035031
Publication Date:
March 12, 2020
Filing Date:
September 05, 2019
Export Citation:
Assignee:
UNIV KOBE NAT UNIV CORP (JP)
AGC INC (JP)
AGC INC (JP)
International Classes:
C07B41/06; C07C249/02; C07B41/10; C07B41/12; C07B61/00; C07C251/30; C07C51/60; C07C53/40; C07C53/42; C07C53/48; C07C55/36; C07C57/66; C07C63/00; C07C63/68; C07C65/21; C07C67/18; C07C69/06; C07C69/08; C07C205/57; C07D207/333; C07D209/12; C07D307/46; C07D307/48; C07D307/80; C07D333/22; C07D333/38
Domestic Patent References:
| WO2008105464A1 | 2008-09-04 |
Foreign References:
| JP2012136502A | 2012-07-19 | |||
| JP2013541533A | 2013-11-14 | |||
| JP2013181028A | 2013-09-12 |
Other References:
ZHAO, YUBAO ET AL.: "Visible-Light-Driven Conversion of Alcohols into Iodide Derivatives with Iodoform", CHEMPHOTOCHEM, vol. 2, no. 8, 2018, pages 720 - 724, XP055690926, ISSN: 2367-0932, [retrieved on 20180503]
BARRETT, ANTHONY G. M. ET AL.: "Nucleophilic Substitution Reaction of (Alkoxymethylene)dimethylammonium Chloride", THE JOURNAL OF ORGANIC CHEMISTRY, vol. 63, no. 18, 1998, pages 6273 - 6280, XP055205955, ISSN: 1520-6904, DOI: 10.1021/jo980583j
CHEN, YUESU ET AL.: "Visible Light-Promoted Beckmann Rearrangements: Separating Sequential Photochemical and Thermal Phenomena in a Contituous Flow Reactor", EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, vol. 2019, no. 11, 15 February 2019 (2019-02-15), pages 2163 - 2171, XP055690921, ISSN: 1434-193X
BARRETT, ANTHONY G. M. ET AL.: "Nucleophilic Substitution Reaction of (Alkoxymethylene)dimethylammonium Chloride", THE JOURNAL OF ORGANIC CHEMISTRY, vol. 63, no. 18, 1998, pages 6273 - 6280, XP055205955, ISSN: 1520-6904, DOI: 10.1021/jo980583j
CHEN, YUESU ET AL.: "Visible Light-Promoted Beckmann Rearrangements: Separating Sequential Photochemical and Thermal Phenomena in a Contituous Flow Reactor", EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, vol. 2019, no. 11, 15 February 2019 (2019-02-15), pages 2163 - 2171, XP055690921, ISSN: 1434-193X
Attorney, Agent or Firm:
USFI PATENT ATTORNEYS INTERNATIONAL OFFICE (JP)
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