Title:
METHOD FOR PRODUCING 1,1,1-TRIFLUORO-2,2-BISARYLETHANE, AND 1,1,1-TRIFLUORO-2,2-BISARYLETHANE
Document Type and Number:
WIPO Patent Application WO/2020/162408
Kind Code:
A1
Abstract:
The present invention has the effect of making it possible to produce 1,1,1-trifluoro-2,2-bisarylethane efficiently by a simple procedure by condensing a mixture of fluoral and hydrogen fluoride with an aryl compound under anhydrous conditions. The purity of the 1,1,1-trifluoro-2,2-bisarylethane obtained can be raised by a simple purification method such as crystallization or distillation.
Inventors:
HOSOI KENJI (JP)
HIROTAKI KENSUKE (JP)
MURAKAMI YOSUKE (JP)
HORI HIROTO (JP)
EGUCHI HIROSHI (JP)
HIROTAKI KENSUKE (JP)
MURAKAMI YOSUKE (JP)
HORI HIROTO (JP)
EGUCHI HIROSHI (JP)
Application Number:
PCT/JP2020/003964
Publication Date:
August 13, 2020
Filing Date:
February 03, 2020
Export Citation:
Assignee:
CENTRAL GLASS CO LTD (JP)
International Classes:
C07C22/08; C07B61/00; C07C17/32; C07C25/18; C07C37/20; C07C39/367; C07C41/30; C07C43/313; C07C209/78; C07C211/50; C07C215/80
Domestic Patent References:
| WO2018123649A1 | 2018-07-05 | |||
| WO2019216163A1 | 2019-11-14 |
Foreign References:
| JPS57502055A | 1982-11-18 | |||
| US3388097A | 1968-06-11 | |||
| GB1036870A | 1966-07-20 |
Other References:
G. K. SURYA PRAKASH ET AL.: "Fluoroanalogs of DDT: Superacidic BF3 - H20 catalyzed facile synthesis of 1,1,1,-trifluoro-2,2-diarylethanes and 1,1- difluoro-2,2-diarylethanes", ORGANIC LETTERS, vol. 13, no. 15, 2011, pages 4128 - 4131, XP055729107
PETER DELVIGS ET AL.: "Addition polyimides from non-mutagenic diamines", HIGH PERFORMANCE POLYMERS, vol. 13, 2001, pages 301 - 312
PETER DELVIGS ET AL.: "Addition polyimides from non-mutagenic diamines", HIGH PERFORMANCE POLYMERS, vol. 13, 2001, pages 301 - 312
Attorney, Agent or Firm:
HAYAMI Shinji (JP)
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