Title:
MODIFICATION METHOD AND ANALYSIS METHOD FOR MIXTURE CONTAINING TRIFLUOROSULFANYL AROMATIC COMPOUND
Document Type and Number:
WIPO Patent Application WO/2018/186331
Kind Code:
A1
Abstract:
The purpose of the present invention is to provide a modification method for a mixture containing a trifluorosulfanyl aromatic compound and a fluorosulfinyl aromatic compound, wherein one or both of these compounds are converted into derivatives. Provided is a method for modifying a mixture that contains: a trifluorosulfanyl aromatic compound represented by general formula (1): Ar-SF3 (Ar denotes a substituted or unsubstituted aryl group); and a fluorosulfinyl aromatic compound represented by general formula (2): Ar-SOF (Ar denotes a substituted or unsubstituted aryl group). The method includes an amidation step in which the mixture is subjected to a reaction with a primary or secondary amine represented by general formula (A): R1R2NH (R1 denotes an alkyl group having 1-4 carbon atoms, and R2 denotes a hydrogen atom or an alkyl group having 1-4 carbon atoms), thereby converting the fluorosulfinyl aromatic compound into a sulfinamide compound represented by general formula (3): Ar-SONR1R2 (the definitions of Ar, R1 and R2 are as described above).
Inventors:
SAITO NORIMICHI (JP)
SHIMA HIDETAKA (JP)
YOKOTA NAOYUKI (JP)
SHIMA HIDETAKA (JP)
YOKOTA NAOYUKI (JP)
Application Number:
PCT/JP2018/014070
Publication Date:
October 11, 2018
Filing Date:
April 02, 2018
Export Citation:
Assignee:
UBE INDUSTRIES (JP)
International Classes:
C07C381/00; C07C313/04; C07C313/06; G01N24/08
Foreign References:
| JP2015509907A | 2015-04-02 | |||
| JP2009544735A | 2009-12-17 |
Other References:
UMEMOTO, TERUO ET AL.: "Discovery of 4- tert -Butyl-2,6-dimethylphenylsulfur Trifluoride as a Deoxofluorinating Agent with High Thermal Stability as Well as Unusual Resistance to Aqueous Hydrolysis, and Its Diverse Fluorination Capabilities Including Deoxofluoro-Arylsulfinylation with High Stereoselectivity", JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, vol. 132, no. 51, 2010, pages 18199 - 18205, XP055083243
WEI XU ET AL.: "Arylsulfur trifluorides: Improved method of synthesis and use as in situ deoxofluorination reagents", JOURNAL OF FLUORINE CHEMISTRY, vol. 132, no. 7, July 2011 (2011-07-01), pages 482 - 488, XP055062891
WEI XU ET AL.: "Arylsulfur trifluorides: Improved method of synthesis and use as in situ deoxofluorination reagents", JOURNAL OF FLUORINE CHEMISTRY, vol. 132, no. 7, July 2011 (2011-07-01), pages 482 - 488, XP055062891
Attorney, Agent or Firm:
ONO, Shinjiro et al. (JP)
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