The present invention relates to a phosphor for a UV emitting device and to a UV generating device comprising such a phosphor.

A phosphor in this context is a chemical composition, which is absorbs electromagnetic radiation of a certain energy and subsequently re-emits electromagnetic radiation exhibiting a different energy. Such phosphors are for example commonly known from fluorescent lamps. The term "phosphor" must not be understood as the chemical element Phosphorus.

UV-C emitting gas discharge lamps such as low pressure or medium pressure Hg discharge lamps are widely used for disinfection purposes in water and wastewater applications. They are also useful for so-called "advanced oxidation processes" for cracking highly persistent fluorinated or chlorinated carbons.

Low pressure mercury gas discharge lamps emit UV-C mainly at 254 nm wavelength, which is radiated through the wall material of the lamps and sheath tubes, which are usually made of quartz. This part of the radiation is directly effective in damaging DNA of e.g. bacteria and viruses. However, a significant proportion of about 15% of the total radiation energy, produced inside the lamp, is located in the shorter wavelength range around 185 nm, and when Xe excimer lamps are used, even in the range 172 nm ± 8 nm. This part of the electromagnetic spectrum is called "vacuum ultraviolet" (VUV). A large part of this high energy radiation is absorbed by the quartz body of the lamp and thus lost for the application.

SHEET INCORPORATED BY REFERENCE (RULE 20.6) Several phosphors have been proposed which convert radiation of 170 nm to 185 nm wavelength into longer wavelengths around 250 nm, for example in the documents US 6,734,631 B2, US 2005/0073239 Al, US 2012/0319011 Al, US 2008/0258601 Al, US 7,935,273 B2 and US 8,647,531 B2. These documents are herewith incorporated by reference.

The phosphors proposed in the prior art documents have several drawbacks in the technical applications mentioned above.

First of all, many phosphors contain rare and expensive elements, making the use in large-scale installations too expensive. Furthermore, some of the compounds of the prior art do not show the desired long-term stability, which is necessary for example in municipal installations, e.g. water works and the like. When applied to the inside of a quartz body of a low pressure mercury discharge lamp, radiation and especially the presence of mercury atoms leads to a deterioration of the known phosphors and consequently to a loss in efficiency. Finally, phosphors containing Yttrium absorb some of the short wavelengths without emitting a UV-C photon and therefore do not significantly increase the radiation output in the desired UV-C range.

Therefore, it is an object of the present invention to provide a novel phosphor for UV emitting devices, which improves on the deficiencies mentioned above. Furthermore, it is an object of the present invention to provide a UV generating device wtth

comprising such a phosphor.

This object is achieved by a phosphor with the features of claim 1 and by a UV generating device with the features of claim 9.

A novel phosphor for a UV emitting device, having the formula

A l+x B i- _2c R0 ₄ : RG ³⁺ _C

wherein

A is selected from Na or K or a mixture thereof, and

B is selected from Mg, Ca or Sr or a mixture thereof, and 0 < x < 0.5

solves the problem defined above.

Preferably, the formula is Na i _+x Ca i-2x P04: Pr ³⁺ _x because at least the metals Na and Ca in this formula are very abundant and available at low cost.

Good results are generally achieved when the value of x is 0 < x < 0.25, preferably the value of x is 0 < x < 0.1.

SHEET INCORPORATED BY REFERENCE (RULE 20.6) Still better results are achieved when the value of x is 0.01 < x < 0.1, and preferably the value of x is 0.03 < x < 0.07, especially when x is 0.04 < x < 0.06.

A UV generating device with a UV radiation source comprising a phosphor as described above also solves the object of the invention, because a UV-C source is provided with a relatively cost-effective phosphor having good VUV to UV-C conversion efficiency and long-term stability.

Preferably the UV radiation source is a gas discharge lamp, especially a low pressure mercury amalgam gas discharge lamp or an excimer gas discharge lamp.

It is preferred that the UV radiation source is an excimer gas discharge lamp with a gas filling that predominantly emits the Xenon excimer spectrum at VUV wavelengths around 172 nm is advantageous in this case. The gas filling may preferably contain more than 50% by volume of Xenon.

For environmental considerations it is preferred that the UV radiation source is an excimer gas discharge lamp with a gas filling that is essentially free of mercury. It is generally known how to produce phosphors of a given formula using wet chemistry. Generally, the compounds are used in batches in the form of oxides or phosphates in the desired molar ratio. These substances are then suspended in distilled water and, under stirring, H3PO4 is added and the suspension is stirred for several hours at ambient temperature. The suspension is then concentrated in an evaporator and dried. The solid residue is grounded in a mortar. The powder can then be calcinated at high temperatures with exposure to air, for example up to

1000° C for 2-4 hours. After cooling to ambient temperature, the phosphor results as a solid. The phosphor can additionally be washed with distilled water, filtered off and dried in order to obtain a pure white powder. · In a preferred embodiment, the molar ratio of the compounds is chosen such that the phosphor obtained after the procedure has the formula Nai,os Ca _o ,9 P04: Pr ³⁺ o,os. This phosphor has been tested, and it has been established that the phosphor absorbs UV- radiation at a wavelength of 172 nm and 185 nm and re-emits a significant portion of the absorbed energy in a wavelength range between 230 and 260 nm. The phosphor is essentially free of Yttrium, which means that Yttrium is present only up to concentrations which qualify as unavoidable impurities.

In another preferred embodiment, the phosphor described above is applied to the outside or preferably to the inside of a quartz tube, which is the lamp body of a UV-

SHEET INCORPORATED BY REFERENCE (RULE 20.6) emitting gas discharge la'mp. The lamp may be of the low-pressure mercury amalgam gas discharge type or the Xe excimer lamp type. A coating can be applied to the lamp body by wet or dry deposition methods. These methods are known in the prior art.

In a preferred embodiment, the gas filling of the lamp is essentially free of mercury, namely free of mercury except for unavoidable impurities. It is furthermore preferred that the UV radiation source is an excimer gas discharge lamp with a gas filling that predominately emits the 2. Xenon excimer continuum.

In the following, three examples of the preparation and properties of phosphors according to the present invention are disclosed. Reference to the drawings is made, which show

Fig. 1 : the XRD pattern of Nai _, o ₅ Cao, ₉ P0 ₄ : Pr ³⁺ o,o ₅ (top) and the respective

reference pattern (bottom),

Fig. 2: the reflection spectrum of Nai,o5Cao,9P04: Pr ³⁺ _o ,o5,

Fig. 3 : the emission spectrum of Nai,o5Cao,9P04: Pr ³⁺ o,os,

Fig. 4: the excitation spectrum of Nai,o5Cao, ₉ P0 ₄ :Pr ³⁺ o,o5,

Fig. 5 : the XRD pattern of Ki,oiSro, ₉₈ P0 ₄ : Pr ³⁺ o,oi (top) and the respective

reference pattern (bottom),

Fig. 6: the reflection spectrum of Ki,oiSro,9 ₈ P0 ₄ : Pr ³⁺ o,oi,

Fig. 7 : the emission spectrum of Ki,oiSro,98P04: Pr ³⁺ o,oi,

Fig. 8: the excitation spectrum of Ki,oiSro, ₉₈ P0 ₄ : Pr ³⁺ o,oi,

Fig. 9: the XRD pattern of Nai,oiSro, ₉₈ P0 ₄ : Pr ³⁺ o,oi (top) and the respective reference pattern (bottom),

Fig. 10: the reflection spectrum of Nai,oiSro, ₉₈ P0 ₄ : Pr ³⁺ o,oi,

Fig. 11 : the emission spectrum of ai,oiSro, ₉₈ P0 ₄ : Pr ³⁺ o,oi,

Fig. 12: the excitation spectrum of Nai,oiSro,98P0 ₄ : Pr ³⁺ o,oi,

Fig. 13: a UV emission spectrum of a prior art low-pressure Hg discharge lamp, and

SHEET INCORPORATED BY REFERENCE (RULE 20.6) Fig. 14: the UV emission spectrum of a low-pressure Hg discharge lamp with a

VUV to UV-C converting phosphor.

Example 1 : Preparation and properties of Nai,osCao,9P04: Pr ³⁺ o,os

The powdered educts Na ₂ C03 (1.3911 g, 13.12 mmol), CaC03 (2.2520 g,

22.20 mmol), NH4H2PO4 (2.8758 g, 25.00 mmol) and Pr ₆ Ou (0.2128 g, 0.21 mmol) were thoroughly ground into a homogeneous mixture under the addition of a few milliliters of ethanol within an polyethene (PE) bottle on a roller band for 16 h. After the ethanol evaporated completely, the resulting mixture was transferred into a porcelain crucible and was annealed for 3 hours at 900 °C under ambient atmosphere. After the first annealing step, the sample material was again homogenized utilizing the roller belt method described above. After drying, the resulting pulverized sample was transferred into a corundum crucible and was heated for 3 hours at 1300 °C under 5 % H2-atmosphere. The yielded light green powder was characterized as phase pure NaCaPC , crystallized in space group Pna2i (33) via PXRD and a respective matching with a reference spectrum, taken from a PCD database entry (PCD Entry No. :

2070162). The as prepared material was then ground to a mean particle size distribution of <40 pm via agitation within a PE bottle under addition of a few milliliters of ethanol on a roller band for several hours before a final drying step.

The XRD pattern and the reflection, emission and excitation spectra of the prepared material are shown in figs. 1 - 4.

Example 2: Preparation and properties of Ki,oiSro,98P0 ₄ : Pr ³⁺ o,oi

The powdered educts K2CO3 (1,0469 g, 7,58 mmol), SrCCh (2.1702 g, 14.70 mmol), NH4H2PO4 (1.7255 g, 15.00 mmol) and Pr ₆ Ou (0.0255 g, 0.025 mmol) were thoroughly ground into a homogeneous mixture under the addition of a few milliliters of ethanol within an polyethene (PE) bottle on a roller band for 16 h. After the ethanol evaporated completely, the resulting mixture was transferred into a porcelain crucible and was annealed for 3 hours at 900 °C under ambient atmosphere. After the first annealing step, the sample material was again homogenized utilizing the roller belt method described above. After drying, the resulting pulverized sample was transferred into a corundum crucible and was heated for 3 hours at 1300 °C under 5 % H2- atmosphere. The yielded light green powder was characterized as phase pure KSrP0 ₄ , crystallized in space group Pnma (62) via PXRD and a respective matching with a reference spectrum, taken from a PCD database entry (PCD Entry No.: 1414892). The as prepared material was then ground to a mean particle size distribution of <40 pm

SHEET INCORPORATED BY REFERENCE (RULE 20.6) via agitation within a PE bottle under addition of a few milliliters of ethanol on a roller band for several hours before a final drying step.

The XRD pattern and the reflection, emission and excitation spectra of the prepared material are shown in figs. 5 - 8. Example 3: Preparation and properties of Nai,oiSro,98P0 ₄ : Pr ³⁺ o,oi

The powdered educts Na ₂ C03 (1.3381 g, 12.62 mmol), SrCCb (3.6169 g,

24.50 mmol), NH4H2PO4 (2.8758 g, 25 mmol) and RGbOh (0.0426 g, 0.041 mmol) were thoroughly ground into a homogeneous mixture under the addition of a few milliliters of ethanol within an polyethene (PE) bottle on a roller band for 16 h. After the ethanol evaporated completely, the resulting mixture was transferred into a porcelain crucible and was annealed for 3 hours at 900 °C under ambient atmosphere. After the first annealing step, the sample material was again homogenized utilizing the roller belt method described above. After drying, the resulting pulverized sample was transferred into a corundum crucible and was heated for 3 hours at 1300 °C under 5 % H2-atmosphere. The yielded light green powder was characterized as phase pure

NaSrPC via matching with a reference spectrum, taken from a PCD database entry (PCD Entry No. : 1706169). An assignment of the respective space group was not possible as the respective literature did only comprise the assignment of the parameter of the monocline unit cell. The as prepared material was then ground to a mean particle size distribution of <40 pm via agitation within a PE bottle under addition of a few milliliters of ethanol on a roller band for several hours before a final drying step.

The XRD pattern and the reflection, emission and excitation spectra of the prepared material are shown in figs. 9 - 12. Spectra of a conventional UV lamp and a modified UV lamp using a phosphor according to one of the examples given above are illustrated in figs. 13 and 14, respectively.

Fig. 13 shows a UV emission spectrum of a conventional lamp which emits a small, yet significant proportion of its UV radiation power at a wavelength of 185 nm, below the main emission peak at 250 nm. The UV emission spectrum shown in fig. 14

demonstrates the effect of the application of a phosphor according to the present invention in a UV lamp. It is clearly visible that this combination of lamp with a phosphor now emits a part of its radiation power in a band below the main peak at 254 nm, namely roughly between 230 nm and 250 nm and peaking at 240 nm. The

SHEET INCORPORATED BY REFERENCE (RULE 20.6) energy comprised in this part of the emission spectrum has been converted by the phosphors from the lamps 185 nm emission. This radiation is therefore no longer lost, but rather available for e.g. disinfection purposes. The energetic efficiency of the lamp is therefore increased in comparison to the conventional lamp of fig. 13.

SHEET INCORPORATED BY REFERENCE (RULE 20.6)