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Title:
PHOTOELECTRIC CONVERSION ELEMENT, DYE-SENSITIZED SOLAR CELL, AND METAL COMPLEX DYE USED IN SAME
Document Type and Number:
WIPO Patent Application WO/2014/168119
Kind Code:
A1
Abstract:
Provided are: a photoelectric conversion element which has excellent durability and photoelectric conversion efficiency; a dye-sensitized solar cell; and a metal complex dye. A photoelectric conversion element which comprises a conductive supporting body, a photosensitive body layer containing an electrolyte, a charge transfer body layer containing an electrolyte and a counter electrode, and wherein the photosensitive body layer comprises semiconductor fine particles that are loaded with a metal complex dye represented by formula (I); a dye-sensitized solar cell; and a metal complex dye. M1(LA)(LD)(Z1)·(CI) Formula (1) In formula (I), M1 represents a metal atom; Z1 represents a monodentate ligand; LA represents a tridentate ligand represented by formula (AL-1); LD represents a bidentate ligand represented by formula (DL-1) and CI represents counter ions necessary for neutralizing the electrical charge. In formula (AL-1) and formula (DL-1), each of Za, Zb and Zc represents a non-metal atom group forming a five- or six-membered ring, provided that at least one of the rings formed by Za, Zb and Zc has an acidic group; m1 represents an integer of 0-3; m2 represents an integer of 1-4; n1 represents an integer of 1-4; l1 represents an integer 0-3; L1 represents an arylene group, an alkynylene group or an alkynylene arylene group; and R1 represents an amino group, an alkylamino group, an arylamino group, a heteroarylamino group, a halogen atom, an alkyl group, an alkynyl group, an alkoxy group, an aryloxy group, an alkylthio group or an arylthio group.

Inventors:
WATANABE KOHSUKE (JP)
SATO HIROTAKA (JP)
TANI YUKIO (JP)
FUJIWARA RYO (JP)
TSUNA KAZUHIRO (JP)
KOBAYASHI KATSUMI (JP)
Application Number:
PCT/JP2014/060108
Publication Date:
October 16, 2014
Filing Date:
April 07, 2014
Export Citation:
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Assignee:
FUJIFILM CORP (JP)
International Classes:
H01G9/20; C09B57/10; H01L51/44
Domestic Patent References:
WO2013047615A12013-04-04
WO2013047238A12013-04-04
Foreign References:
JP2012119195A2012-06-21
JP2003100357A2003-04-04
JP2000311723A2000-11-07
JP2001236999A2001-08-31
JP2002280587A2002-09-27
Attorney, Agent or Firm:
ODAHARA Shuichi et al. (JP)
Shuichi Odawara (JP)
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