Title:
PREPARATION METHOD FOR CONJUGATED DIENE COMPOUND
Document Type and Number:
WIPO Patent Application WO/2019/052236
Kind Code:
A1
Abstract:
The present invention pertains to the field of fine chemicals and related chemical technologies and provides a preparation method for a butadiene derivative. Phenylacetylene and derivatives thereof are used as raw materials and react in an anhydrous organic solvent under the action of a metal catalyst and an additive, to be transformed into a 2,3-disubstituted-1,3-butadiene compound. The present invention has the beneficial effects of simple operation, mild preparation conditions, environmental friendliness, industrialization potential, and production of a higher yield butadiene compound. The butadiene compound synthesized by the method can further be functionalized to obtain various types of compounds for subsequent application in the research and development of natural products, functional materials, and fine chemicals.
Inventors:
BAO MING (CN)
GUO HONGYU (CN)
ZHANG SHENG (CN)
GUO HONGYU (CN)
ZHANG SHENG (CN)
Application Number:
PCT/CN2018/090254
Publication Date:
March 21, 2019
Filing Date:
June 07, 2018
Export Citation:
Assignee:
UNIV DALIAN TECH (CN)
International Classes:
C07C2/38; C07C15/50; C07C17/269; C07C25/24; C07C41/30; C07C43/215; C07C45/69; C07C49/796; C07D333/04
Foreign References:
| CN107556153A | 2018-01-09 |
Other References:
ANSARI, N.H. ET AL.: "Double Palladium Catalyzed Reductive Cyclizations. Synthesis of 2,2'-, 2,3'-, and 3,3'-Bi-1H-indoles, Indolo[3,2-b]indoles, and Indolo[2,3-b]indoles", JOURNAL OF ORGANIC CHEMISTRY, vol. 81, no. 19, 17 September 2016 (2016-09-17), pages 9337 - 9349, XP055582768, ISSN: 0022-3263
GHOSAL, S. ET AL.: "Formation of 1,3-Diynes, 1,3-Dienes, and Biphenyls via the Copper(II) Nitrate Mediated Coupling of Organotin Compounds", JOURNAL OF ORGANIC CHEMISTRY, vol. 52, no. 19, 30 December 1987 (1987-12-30), pages 4296 - 4298, XP055582769, ISSN: 0022-3263
ANSARI, N.H. ET AL.: "Syntheses of Three Naturally Occurring Polybrominated 3,3'-Bi-1H- indoles", TETRAHEDRON LETTERS, vol. 58, no. 11, 3 February 2017 (2017-02-03), pages 1053 - 1056, XP029925552, ISSN: 0040-4039, DOI: doi:10.1016/j.tetlet.2017.01.103
GHOSAL, S. ET AL.: "Formation of 1,3-Diynes, 1,3-Dienes, and Biphenyls via the Copper(II) Nitrate Mediated Coupling of Organotin Compounds", JOURNAL OF ORGANIC CHEMISTRY, vol. 52, no. 19, 30 December 1987 (1987-12-30), pages 4296 - 4298, XP055582769, ISSN: 0022-3263
ANSARI, N.H. ET AL.: "Syntheses of Three Naturally Occurring Polybrominated 3,3'-Bi-1H- indoles", TETRAHEDRON LETTERS, vol. 58, no. 11, 3 February 2017 (2017-02-03), pages 1053 - 1056, XP029925552, ISSN: 0040-4039, DOI: doi:10.1016/j.tetlet.2017.01.103
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