Title:
PREPREG, AND CARBON FIBER REINFORCED COMPOSITE MATERIAL
Document Type and Number:
WIPO Patent Application WO/2014/050264
Kind Code:
A1
Abstract:
Provided are a prepreg and a carbon fiber reinforced composite material with excellent adhesion between the carbon fibers and matrix resin and excellent long-term storage stability, as well as excellent microcrack resistance due to enhanced toughness. The present invention is a prepreg in which sizing-agent-coated carbon fiber, which has been coated with a sizing agent containing an aliphatic epoxy compound (A) and an aromatic epoxy compound (B1), in the form of a fabric or braided cord is impregnated with a thermosetting resin composition containing a thermosetting resin (D), a thermoplastic resin (F) and a latent curing agent (G), characterized by the ratio (a)/(b) between the level of the bond energy component attributed to (a) CHx, C-C, or C=C in the C1s inner shell spectrum when the surface of the sizing-agent-coated carbon fibers is measured by x-ray photoelectron spectroscopy and the level of the bond energy component attributed to (b) C-O is within a predetermined range.
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Inventors:
ARAI NOBUYUKI (JP)
ICHIKAWA TOMOKO (JP)
TAIKO HIROSHI (JP)
ENDO MAKOTO (JP)
KOBAYASHI MASANOBU (JP)
MISUMI JUN (JP)
ICHIKAWA TOMOKO (JP)
TAIKO HIROSHI (JP)
ENDO MAKOTO (JP)
KOBAYASHI MASANOBU (JP)
MISUMI JUN (JP)
Application Number:
PCT/JP2013/069321
Publication Date:
April 03, 2014
Filing Date:
July 16, 2013
Export Citation:
Assignee:
TORAY INDUSTRIES (JP)
International Classes:
D06M13/11; C08J5/24; D06M15/55; D06M101/40
Domestic Patent References:
WO2003010383A1 | 2003-02-06 | |||
WO2006077153A2 | 2006-07-27 |
Foreign References:
JP2005179826A | 2005-07-07 | |||
JP2005213687A | 2005-08-11 | |||
JPH07279040A | 1995-10-24 | |||
JPS6129613B2 | 1986-07-08 | |||
JPS6234251B2 | 1987-07-25 | |||
JP2010059300A | 2010-03-18 | |||
JP2009280669A | 2009-12-03 | |||
JP2006219078A | 2006-08-24 | |||
JP2009513438A | 2009-04-02 | |||
JP2005179826A | 2005-07-07 | |||
JP2005256226A | 2005-09-22 | |||
JP2008280624A | 2008-11-20 | |||
JP2005213687A | 2005-08-11 | |||
JP2002309487A | 2002-10-23 | |||
JPH02307979A | 1990-12-21 | |||
JP2002173873A | 2002-06-21 | |||
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Other References:
JOURNAL OF ADVANCED MATERIALS, vol. 26, no. 4, 1995, pages 48 - 62
JIS-R-7608, 2004
JIS K7121, 1987
JIS K7171, 1999
See also references of EP 2886590A4
JIS-R-7608, 2004
JIS K7121, 1987
JIS K7171, 1999
See also references of EP 2886590A4
Attorney, Agent or Firm:
SAKAI, HIROAKI (JP)
Hiroaki Sakai (JP)
Hiroaki Sakai (JP)
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