Title:
ROTAXANE COMPOUND
Document Type and Number:
WIPO Patent Application WO/2019/208723
Kind Code:
A1
Abstract:
A rotaxane compound including one or more cyclic molecules and an axial molecule that penetrates the inner hole portion of the cyclic molecule, the axial molecule having a cap structure arranged so that the cyclic molecule does not detach, wherein one of the cyclic molecule and the axial molecule has one of a functional group capable of reacting with silica and a functional group capable of reacting with a carbon-carbon unsaturated bond, and the other of the cyclic molecule and the axial molecule has the other of the functional group capable of reacting with silica and the functional group capable of reacting with a carbon-carbon unsaturated bond.
Inventors:
NAKAHATA SHOKO (JP)
TAKATA TOSHIKAZU (JP)
TSUTSUBA TOYOKAZU (JP)
TAKATA TOSHIKAZU (JP)
TSUTSUBA TOYOKAZU (JP)
Application Number:
PCT/JP2019/017761
Publication Date:
October 31, 2019
Filing Date:
April 25, 2019
Export Citation:
Assignee:
SUMITOMO RUBBER IND (JP)
TOKYO INST TECH (JP)
TOKYO INST TECH (JP)
International Classes:
C07F7/18; C07D323/00; C08K3/36; C08K5/16; C08L9/00; C08L101/02
Other References:
FARCAS, A. ET AL.: "Synthesis, Photophysical, and Morphological Properties of Azomethine- Persylilated a-Cyclodextrin Main-Chain Polyrotaxane", MACROMOLECULAR CHEMISTRY AND PHYSICS, vol. 216, no. 6, 2015, pages 662 - 670, XP055652705, ISSN: 1022-1352
FARCAS, A. ET AL.: "Synthesis and characterization of low-molecular-weight n-conjugated polymers covered by persilylated beta-cyclodextrin", BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY, vol. 170, pages 1505 - 1514, XP055652706, ISSN: 1860-5397
VINCENT, S. P. ET AL.: "Biologically Active Hetero-glycoclusters Constructed on a Pillar[5]arene-Containing [2]Rotaxane Scaffold", CHEMISTRY-A EUROPEAN JOURNAL, vol. 22, no. 1, 2016, pages 88 - 92, XP055391906, ISSN: 0947-6539, DOI: 10.1002/chem.201504110
SUGIYAMA, J. ET AL.: "Novel approach to stabilize unstable molecular wires by simultaneous rotaxane formation-synthesis of inclusion complexes of oligocarbynes with cyclic host molecules", EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, 2007, pages 4651 - 4653, XP055652712, ISSN: 1434-193X
SASABE, H. ET AL.: "Synthesis of poly[2]rotaxane by Sonogashira polycondensation", JOURNAL OF POLYMER SCIENCE , PART A: POLYMER CHEMISTRY, vol. 45, no. 17, 2007, pages 4154 - 4160, XP055652714, ISSN: 0887-624X
AKAE, Y. ET AL.: "Cyclodextrin-Based [3]Rotaxane- Crosslinked Fluorescent Polymer: Synthesis and De- Crosslinking Using Size Complementarity, Angewandte Chemie", INTERNATIONAL EDITION, vol. 57, no. 45, 21 September 2018 (2018-09-21), pages 14832 - 14836, XP055652716, ISSN: 1433-7851
FARCAS, A. ET AL.: "Effect of permodified f3-cyclodextrin on the photophysical properties of poly[2, 7-(9, 9-dioctylfluorene)-alt-(5, 5'- bithiophene)] main chain polyrotaxanes", JOURNAL OF POLYMER SCIENCE , PART A: POLYMER CHEMISTRY, vol. 52, no. 4, 2014, pages 460 - 471, XP055652719, ISSN: 0887-624X
MAROIS, J. ET AL.: "Synthesis and Surface Self- Assembly of [3]Rotaxane-Porphyrin Conjugates: Toward the Development of a Supramolecular Surface Tweezer for C60", LANGMUIR, vol. 24, no. 19, 2008, pages 10865 - 10873, XP055652721, ISSN: 0743-7463
MAROIS, J. ET AL.: "[3]Rotaxane-Porphyrin Conjugate as a Novel Supramolecular Host for Fullerenes", ORGANIC LETTERS, vol. 10, no. 1, 2008, pages 33 - 36, XP055652722, ISSN: 1523-7060
GONG, X. ET AL.: "Synthesis, characterization and in vitro evaluation of a series of novel polyrotaxane-based delivery system for artesunate", CARBOHYDRATE RESEARCH, vol. 412, 2015, pages 7 - 14, XP055652723, ISSN: 0008-6215
JUNG, S. ET AL.: "Anti-AIDS active polyrotaxane- AZT conjugates with bioactive bulky stoppers and their nanoparticles", JOURNAL OF POLYMER SCIENCE , PART A: POLYMER CHEMISTRY, vol. 50, no. 23, 2012, pages 4895 - 4901, XP055652726, ISSN: 0887-624X
HYUN, H. ET AL.: "Mono-, di-, or triazidated cyclodextrin-based polyrotaxanes for facile and efficient functionalization via click chemistry", MACROMOLECULAR RAPID COMMUNICATIONS, vol. 32, no. 3, 2011, pages 326 - 331, XP055652729, ISSN: 1022-1336
OKUMURA ET AL., ADVANCED MATERIALS, vol. 13, no. 7, 2001, pages 485 - 487
ITO, POLYMER JOURNAL, vol. 39, no. 6, 2007, pages 489 - 499
KOYAMA ET AL., POLYMER JOURNAL, vol. 46, 2014, pages 315 - 322
OLEO SCIENCE, vol. 5, no. 5, 2005, pages 209
See also references of EP 3786169A4
FARCAS, A. ET AL.: "Synthesis and characterization of low-molecular-weight n-conjugated polymers covered by persilylated beta-cyclodextrin", BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY, vol. 170, pages 1505 - 1514, XP055652706, ISSN: 1860-5397
VINCENT, S. P. ET AL.: "Biologically Active Hetero-glycoclusters Constructed on a Pillar[5]arene-Containing [2]Rotaxane Scaffold", CHEMISTRY-A EUROPEAN JOURNAL, vol. 22, no. 1, 2016, pages 88 - 92, XP055391906, ISSN: 0947-6539, DOI: 10.1002/chem.201504110
SUGIYAMA, J. ET AL.: "Novel approach to stabilize unstable molecular wires by simultaneous rotaxane formation-synthesis of inclusion complexes of oligocarbynes with cyclic host molecules", EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, 2007, pages 4651 - 4653, XP055652712, ISSN: 1434-193X
SASABE, H. ET AL.: "Synthesis of poly[2]rotaxane by Sonogashira polycondensation", JOURNAL OF POLYMER SCIENCE , PART A: POLYMER CHEMISTRY, vol. 45, no. 17, 2007, pages 4154 - 4160, XP055652714, ISSN: 0887-624X
AKAE, Y. ET AL.: "Cyclodextrin-Based [3]Rotaxane- Crosslinked Fluorescent Polymer: Synthesis and De- Crosslinking Using Size Complementarity, Angewandte Chemie", INTERNATIONAL EDITION, vol. 57, no. 45, 21 September 2018 (2018-09-21), pages 14832 - 14836, XP055652716, ISSN: 1433-7851
FARCAS, A. ET AL.: "Effect of permodified f3-cyclodextrin on the photophysical properties of poly[2, 7-(9, 9-dioctylfluorene)-alt-(5, 5'- bithiophene)] main chain polyrotaxanes", JOURNAL OF POLYMER SCIENCE , PART A: POLYMER CHEMISTRY, vol. 52, no. 4, 2014, pages 460 - 471, XP055652719, ISSN: 0887-624X
MAROIS, J. ET AL.: "Synthesis and Surface Self- Assembly of [3]Rotaxane-Porphyrin Conjugates: Toward the Development of a Supramolecular Surface Tweezer for C60", LANGMUIR, vol. 24, no. 19, 2008, pages 10865 - 10873, XP055652721, ISSN: 0743-7463
MAROIS, J. ET AL.: "[3]Rotaxane-Porphyrin Conjugate as a Novel Supramolecular Host for Fullerenes", ORGANIC LETTERS, vol. 10, no. 1, 2008, pages 33 - 36, XP055652722, ISSN: 1523-7060
GONG, X. ET AL.: "Synthesis, characterization and in vitro evaluation of a series of novel polyrotaxane-based delivery system for artesunate", CARBOHYDRATE RESEARCH, vol. 412, 2015, pages 7 - 14, XP055652723, ISSN: 0008-6215
JUNG, S. ET AL.: "Anti-AIDS active polyrotaxane- AZT conjugates with bioactive bulky stoppers and their nanoparticles", JOURNAL OF POLYMER SCIENCE , PART A: POLYMER CHEMISTRY, vol. 50, no. 23, 2012, pages 4895 - 4901, XP055652726, ISSN: 0887-624X
HYUN, H. ET AL.: "Mono-, di-, or triazidated cyclodextrin-based polyrotaxanes for facile and efficient functionalization via click chemistry", MACROMOLECULAR RAPID COMMUNICATIONS, vol. 32, no. 3, 2011, pages 326 - 331, XP055652729, ISSN: 1022-1336
OKUMURA ET AL., ADVANCED MATERIALS, vol. 13, no. 7, 2001, pages 485 - 487
ITO, POLYMER JOURNAL, vol. 39, no. 6, 2007, pages 489 - 499
KOYAMA ET AL., POLYMER JOURNAL, vol. 46, 2014, pages 315 - 322
OLEO SCIENCE, vol. 5, no. 5, 2005, pages 209
See also references of EP 3786169A4
Attorney, Agent or Firm:
ASAHINA & CO. (JP)
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