THE SYSTEM OF TREATING ODOR AND HAZARDROUS GAS WITH

ROTARY REGENERATIVE HEAT EXCHANGER AND ITS APPARATUS

Technical Field

The present invention relates to a harmful material

treatment system for which recovers the energy and removes

the harmful material in the process of treating gas

containing the harmful material generated in the multiplex

utilization facility, the display mall, diverse

manufacturing processes and the vehicle painting process,

more particularly, to a harmful material treatment system,

which can recover the energy contained in the air

conditioning facility or in the exhaust gas of the process

with an efficiency of more than 90%, for exhausting the

inside air to the outside so as to treat the contaminating

material such as odor and volatile organic chemicals (VOCs) ,

and simultaneously remove the harmful material with a high

removal efficiency of more than 90% by adsorbing and

concentrating the harmful material with a rotary-type adsorbent .

Background Art

In general, a rotary-type heat exchanger is employed

to perform the heat exchange in facilities requiring a

large-sized air conditioning device, such as a multiplex

utilization facility, a habitation facility, and an event

mall, and the like. In such facilities, thermal energy

contained in the air exhausted to the outside is transferred

to thermal energy storing elements at one side of the

rotary-type heat exchanger and recover it at the opposite

side to thereby recover the thermal energy.

However, nowadays, recognition about the material

causing the sick-house syndrome has been increased in the

habitant and the multiplex utilization facilities, and there

occurs a problem that harmful material generated from the

manufacturing process of the factory has made the work

environment badly off to thereby reduce the productivity, so

that cleaner life environment and factory working

environment are required.

However, according to the conventional rotary-type

heat exchanger, it is possible to recover the energy, but it

is impossible to treat the harmful material introduced from the outside and the harmful material exhausted to the

outside. Whereas, with regard to the method for treating the

harmful material exhausted to the outside from the building

or the factory, there are several methods such as an adsorption treatment method using activated carbon, a direct combustion method for removing it through combustion, a heat accumulating combustion method, and a catalyst combustion method, and the like, and there are also several methods for treating it by using microbes, and the like.

However, according to such diverse methods, although it is possible to remove the harmful material to be exhausted, it is also impossible to recover the thermal energy contained in the gas exhausted from the inside to the

outside, resulting in a loss in the thermal energy.

FIG. 1 is a view for showing a conventional rotary- type heat exchanger disclosed in the US patent NO. 4,542,782. Referring to FIG. 1, the air flow exhausted with high temperature is effected in such a manner that heat is accumulated at one side of the heat exchanger through the rotary-type heat exchanger, and then is moved to the other side of the heat exchanger while being rotated to perform the heat exchange with the gas introduced from the outside to thereby recover the thermal energy. However, for such a method, there is a problem that the harmful material contained in the exhausted air cannot be removed.

FIG. 2 is a view for showing another example of the

conventional rotary-type heat exchanger disclosed in Korea Patent Laid-Open Publication No. 2002-0033353. In FIG. 2, there is shown a rotary-type heat exchanger with a cleaning sector, which can improve the cleanliness of the indoor air by purifying the air backward-flowed toward the inside among

the exhausted air to make it flow into the indoor.

However, this type of the heat exchanger is to prevent the backward-flow of the air contained in the inside space of the medium of the heat exchanger in the process of the conversion of the heat exchanger from the exhaust region to the suction region, by providing the cleaning sector at a

boundary region between the suction region and the exhaust region of the heat exchanger for making a portion of the

exhausted air purified and flowing into the suction region.

In this regard, there is no element for adsorbing the harmful material in the heat exchanger. Further, with regard to the cleaning method, it is constructed that the air received in the heat exchanger can be naturally exhausted by means of the pressure differential by closing one side of the cleaning sector and fluidically communicating the other side with the flow passage toward the exhaust fan.

However, with regard to this structure, there is also

produced a problem that it is impossible to treat the harmful material exhausted to the outside and several contaminating material contained in the outside air flowing

into the inside.

Disclosure Technical problem

Therefore, the present invention has been made to solve the problems occurring in the conventional arts, and the primary object of the present invention is to provide a harmful material treatment system, which can adsorb and treat the harmful material exhausted from the inside to the

outside or from the outside to the inside of the heat exchanger separately or treat them by means of a catalyst

directly, not to mention the heat exchange, by making the rotating heat exchanger from material with adsorption and catalyst property for removing the harmful material and with high thermal energy storage and heat exchange capacities .

Another object of the present invention is to provide a harmful material treating system, which can accomplish the

heat recovery of more than 90% of the exhausted energy and concurrently removing the harmful material with a removal percentage of more than 90% by using one treating system.

Still another object of the present invention is to

provide a harmful material treatment system, which can

adsorb and treat the harmful material by providing

additionally the heat exchange function to an exhaust source

incapable of adsorbing the harmful material due to the high

temperature of the exhaust gas from the exhaust source.

Technical solution

To solve such objects of the present invention,

according to the present invention, there is provided a

harmful material treatment system, which is configured to

store and recover thermal energy, comprising a rotary-type

rotor with a heat exchange medium having functions of

adsorbing the harmful material and storing the thermal

energy concurrently, and a heat exchange medium-receiving

portion for supporting and rotating the heat exchange medium,

the heat exchange medium being divided into three regions

such as a suction region into which the air is sucked, an

exhaust region from which the air is exhausted, and a

concentration and desorption region disposed between the

suction region and the exhaust region for concentrating and removing the harmful material; and driving means for

rotating the rotary-type rotor.

Also, to attain the technical subject of the present

invention, there is provided a harmful material treatment

system, which is configured to regenerate thermal energy,

comprising a heat exchange medium portion with a heat

exchange medium having functions of adsorbing the harmful

material and storing the thermal energy concurrently, and a

heat exchange medium-receiving portion for supporting the

heat exchange medium, the heat exchange medium being divided

into at least three regions consisted of a suction region

into which the air is sucked, an exhaust region from which

the air is exhausted, and a concentration and desorption

region disposed between the suction region and the exhaust

region for concentrating and removing odor, volatile organic

chemicals, or the harmful material/ and rotatable

distribution plates with a plurality of openings mounted

respectively at the heat exchange medium portion, so that

respective regions of the heat exchange medium defines

separate flow passages to allow the inflow of the outside

air and outflow of the inside air.

In addition, the present invention may further comprise

heating means for heating the desorption air flowing into the concentration and desorption region.

Also, the desorption of the harmful material in the

concentration and desorption region of the rotary-type rotor is carried out by the radiation of ultra-violet rays, by means of a sound wave or pressure reduced air.

In the present invention, the rotary-type rotor may further comprise a cooling region disposed between the concentration and desorption region and the suction region

for cooling the heat exchange medium heated for desorption. In this instance, the outflow air exhausted from the cooling region is preferable to flow into the concentration and desorption region.

In the present invention, the heat exchange medium may

use any one material selected from the group consisting of

cordierite having a high thermal energy storage function, bending-type ceramic sheet, alumina, silica, polymer resin, aluminum, stainless, asbestos, and natural fiber, or a

composite material made by combining such materials, as a

thermal energy storage material, and can be made by performing coating of any one material selected from the group consisting of zeolite, activated charcoal, activated carbon fiber, alumina, silica, photo-catalyst, and low- temperature oxidation catalyst, or a composite material made by combining such materials on the thermal energy storage material, or is made by mixing such materials, and wherein

the heat exchange medium may be made of at least one

material selected from the group consisting of zeolite with

a high thermal energy storage property, activated charcoal,

activated carbon fiber, alumina, and silica.

In the present invention, the heat exchange medium

comprises a thermal energy storage layer and an adsorption

layer, and the thermal energy storage layer may be made of

any one material selected from the group consisting of

cordierite having a high thermal energy storing function,

bending-type ceramic sheet, alumina, silica, polymer resin,

aluminum, stainless, asbestos, and natural fiber, or a

composite material made by combining such materials, and the

adsorption layer may be made of any one material selected

from the group consisting of zeolite, activated charcoal,

activated carbon fiber, alumina, silica, photo-catalyst, and

low-temperature oxidation catalyst, or a composite material

made by combining such materials.

In the present invention, the treating system may

further comprise an inside conduit portion having a

plurality of separation plates closely contacting with the

heat exchange medium at one side of the heat exchange medium, and forming separate flow passages at the heat exchange

medium to correspond to said at least three regions, and a

plurality of conduits for allowing the inflow and outflow of the air through the flow passages formed by the separation

plates; and an outside conduit portion having a plurality of separation plates closely contacting with the heat exchange

medium at the other side of the heat exchange medium, and forming separate flow passages fluidically to communicate with the inside conduit portion to correspond to the at

least three regions of the heat exchange medium, and a plurality of conduits for allowing the inflow and outflow of the air through the formed flow passages.

Advantageous Effects

As described above, according to the present invention, it is possible to accomplish the thermal energy recovery percentage and recovery percentage of harmful material of more than 90% with using one system by removing the harmful material discharged from several discharge sources and concurrently treating the thermal energy discharged to the outside with the exhaust gas. Furthermore, when the zeolite is used as the adsorbent, it is possible to perform the action of removing the water component and concurrently enriching the oxygen in the air introduced from the outside.

Description of Drawings

FIG. 1 is a view showing a structure of a conventional rotary-type heat exchange device;

FIG. 2 is a view showing another conventional rotary-

type heat exchange device;

FIG. 3 is a basic conceptual view of a harmful material treatment system, which is configured to regenerate thermal energy by using a rotor, according to a preferred embodiment of the present invention; FIG. 4 is a basic conceptual view of a harmful material treatment system, which is configured to regenerate thermal energy by using a rotor, according to another embodiment of the present invention;

FIG. 5 is a basic conceptual view of a harmful

material treatment system, which is configured to regenerate thermal energy by using a rotor, according to still another embodiment of the present invention;

FIG. 6 is a use conceptual view of the harmful material treatment system of the present invention, which is configured to regenerate thermal energy by using a rotor;

FIG. 7 is a use conceptual view of another example of the harmful material treatment system of the present invention, which is configured to regenerate thermal energy

by using a rotor;

FIG. 8 is a view showing a harmful material treatment

system, which is configured to regenerate thermal energy by

using a rotor, according to a preferred embodiment of the

present invention;

FIG. 9 is a view showing a harmful material treatment

system, which is configured to regenerate thermal energy by

using a distribution plate, according to another embodiment

of the present invention; and

FIG. 10 is an exploded perspective view showing a

harmful material treatment system, which is configured to

regenerate the thermal energy, according to an embodiment of

the present invention in detail .

Best Mode

Hereinafter, most preferable embodiment of the present

invention will be explained in detail with reference to the

appended drawings .

In the specification explained hereinafter, the term of

^Λ heat exchange medium' is used to represent that it performs

not only the heat exchange simply, but it performs the adsorption of the harmful material concurrently. In the

present invention, the term of ^thermal energy storage' is

used in place of the term of ^λ heat exchange medium' for the

medium designed to perform the heat exchange only.

FIG. 3 is a basic conceptual view showing a harmful material treatment system, which is configured to store and recover the thermal energy by using a rotor, according to a preferred embodiment of the present invention. In FIG. 3, a rotary-type rotor 1 of the present invention comprises a heat exchange medium 400 and a receiving portion 500 for the heating exchange medium for supporting it. A region in which the heat exchange medium 400 exists is divided into a suction region 2, an exhaust region 3, and

a concentration and desorption region 4. The heat exchange

medium contains adsorption material for removing the harmful material by means of adsorption or reaction, and is comprised of thermal energy storage material with high thermal energy storage amount.

In the present invention, a specified portion of the

heat exchange medium 400 is transported to the suction region 2, the concentration and desorption region 4, and the exhaust region 3 in order sequentially by means of the

rotation of the rotary-type rotor 1.

For convenience's sake in representing, a rotation shaft of the rotary-type rotor 1 is not shown, and it will

be the same in the other embodiments to be described below.

The outside air, which has been flown into the suction

region 2 according to the rotation of the heat exchange

medium 400, recovers the thermal energy stored in the

exhaust region 3 with an efficiency of more than 90%, and

the harmful material adsorbed by the heat exchange medium in

the exhaust region 3 is detached in the concentration and

desorption region 4, so that it is possible to treat the

harmful material economically by treating the harmful

material with enriching more than one times the existing

concentration .

As for an adsorption material for adsorbing and

treating the harmful material in the present invention, one

kind of material selected from the group consisting of

zeolite, activated charcoal, activated carbon fiber, alumina,

silica, photo-catalyst, and low-temperature oxidation

catalyst, and a composite material made by combining at

least two kinds selected from the group can be used.

Furthermore, with regard to the thermal energy storage

material, one kind of material selected from the group

consisted of ceramic material such as cordierite, bending- type ceramic sheet, alumina, silica, and the like, polymer

resin (urethane resin, polyethylene resin, polypropylene

resin, and the like) , aluminum, stainless, activated

charcoal, natural fiber (palm fiber, pine fiber, hinoki-

fiber, wool, cotton, ski- fiber, momi-fiber, buna-fiber,

elm-like tree fiber) , and asbestos, or a composite material

made by combining such material selected from the group can

be used.

The structure of the heat exchange medium 400 is a low-

pressure loss type structure of honeycomb type, bending-type,

or a net shape structure, or it can be used with forming the

material into predetermined shape and then filling it.

The rotation direction of the rotor is as denoted by

the arrow, so that the heat exchange medium 400 of the

exhaust region 3 is converted sequentially into the exhaust

region 3 → concentration and desorption region 4 → suction

region 2 → exhaust region 3, according to the rotation of

the rotor, so that heat exchange function and the harmful

material removing function can be performed.

When the temperature of the air exhausted from the

inside is high, the thermal energy contained in the gas

exhausted from the inside is derived by the heat exchange

medium 400 in the exhaust region 3, and the harmful material is adsorbed by the heat exchange medium 400, so that the

purified gas can be exhausted to the outside.

In this instance, the heat exchange medium 400 storing

the thermal energy and adsorbing the harmful material in the

exhaust region 3 is transported to the concentration and

desorption region 4. Then, the transported heat exchange

medium 400 is detached in the concentration and desorption

region 4 by using temperature, pressure, photo energy, or

sound wave energy, and is transported through a separate

routine to thereby be exhausted to the outside by means of

separate treating means, which can treat the harmful

material.

In this instance, the gas purified by the treating

means can be re-circulated into the exhaust region 3. Also,

the volume of the air flowing into the concentration and

desorption region 4 for the desorption is smaller than that

of the air passing through the exhaust region 3, and it is

desirable, so far as the volume of the air becomes smaller.

In general, it is preferable to be 1/5 to 1/20. In this

instance, it is necessary to cope with the desorption time

and method properly so that there can be no energy loss

stored in the heat exchange medium 400 during the desorption.

If the desorption time is too long, or if too high temperature is required for the desorption, energy loss can

be occurred. Thus, the heat exchange medium 400 removed of

the harmful material in the concentration and desorption

region 4 is transported to the suction region 4 again, and it emits the energy stored in the rotary-type rotor 1 to transfer it to the air to be sucked. Also, the harmful

material contained in the sucked air are adsorbed by a surface of the rotary-type rotor 1, resulting in the removal of them.

The heat exchange medium 400 passing through such processes is transported to the exhaust region 3 at last,

and such process continues as long as the system is operated. If the treating system of the present invention is employed, it is possible to obtain the high heat recovery percentage of more than 90% and the harmful material removal percentage of more than 90% of the conventional thermal energy storage

type heat exchanger.

Mode for Invention

FIG. 4 is a basic conceptual view showing another example of a harmful material treatment system, which is configured to store and recover the thermal energy by using a rotor, according to the present invention. In the present example, a cooling region 9 is further formed between the concentration and desorption region 8 and the suction region

6. According to this embodiment, when the concentration and

desorption process is to be performed to remove the harmful

material adsorbed at the concentration and desorption region

8 by using the thermal energy, the thermal energy added for

performing the desorption is recovered to be flowing into

the inside progressively.

In this instance, the cooling region 9 is formed to

reduce the amount of the thermal energy flowing into the

inside, and the temperature of the rotary-type rotor 5 is

maintained to be low in the suction region 6, so that it is

possible to better adsorb and treat the contaminating

material flowed in from the outside to the inside.

FIG. 5 is a view showing another embodiment of the

harmful material treatment system, which is configured to

store and recover the thermal energy by using a rotor,

according to the present invention.

In FIG. 5, it is constructed that the heat exchange

medium is divided into a thermal energy storage medium 13

with which the heat exchange medium performs the function of

heat exchange, and an adsorption medium 14 with which the

heat exchange medium performs the function of removing the

harmful material .

Such structure can be applied to a case in which it is

difficult to adsorb the harmful material because the

temperature of the gas exhausted from the inside to the

outside is high. The exhaust gas with high temperature can

perform the function of heat exchange in the thermal energy

storage medium 13 for performing the heat exchange, and is

flowing into the adsorption medium 14 at low temperature to

remove the harmful material easily.

With regard to the physical adsorption property of the

adsorbent, the adsorption is well performed at the low

temperature and is not performed well at the high

temperature. In general, it is preferable to set the

adsorption temperature of the zeolite, and the activated

charcoal to be below 50 ^° C.

However, the rotary-type rotor 51 of the present

invention can be used with combining the thermal energy

storage medium 13 with the adsorption medium 14 in serious,

or with adding or coating the adsorption medium 14 on the

surface of the thermal energy storage medium.

Furthermore, it is possible to change the arranging

order of the adsorption medium and the thermal energy

storage medium, and to arrange them with more than one pair.

In other words, it can be constructed in the order of

"thermal energy storage medium - adsorption medium - thermal

energy storage medium", or "adsorption medium - thermal

energy storage medium - adsorption medium". Also, the rotor

can be constructed of more than two sets of the combination

described above.

FIG. 6 is an example of an embodiment according to the

present invention, in which the energy is recovered and the

indoor air is purified in the multiplex using facility such

as a large display mall. The air exhausted from the large

display mall 26 is flowing into the exhaust region 17

through an exhaust line 37. Depending on the circumstances,

a portion of the gas exhausted through circulation air

conditioning means 41 is made to circulate again.

By means of the gas flowing into the exhaust region 17,

the harmful material produced in the display mall 26 is

adsorbed on the surface of the rotary-type rotor 15 located

at the exhaust region 17, and the energy exhausted from the

indoor to the outside is transferred to the rotary-type

rotor 15.

Then, the rotary-type rotor 15 is rotated to progress

into the concentration and desorption region 20. In this

instance, additional energy is applied to remove the harmful material attached on the surface of the rotary-type rotor 15

located in the concentration and desorption region 20, the

energy being detached by desorption means 21.

With regard to the desorption energy added at this

stage, desorption means 21 using the temperature, the

pressure, and the combination of them can be used. In

general, a detaching method using the thermal energy

produced by increasing the temperature is employed.

Furthermore, photo energy (UV) , and microwave can be

used as desorption methods. Thus, the detached gas can be

treated by means of removing means 22 for the harmful

material. With regard to the removing means 22 for the

harmful material, an adsorption method using a general

adsorbent, an adsorption method using adsorbents, a

combustion system using combustion (direct combustion,

catalyst combustion, thermal energy storage combustion,

thermal energy storage and catalyst combustion,

concentration combustion) , a biological treating method

employing microbes can be used.

Also, a photo-catalytic device and a low-temperature

oxidation catalytic device can be used, when the

concentration of the exhaust gas is low. When the photo-

catalytic device or the low-temperature oxidation catalytic device are to be used, the rotary-type rotor can be used by

coating the surface thereof with the photo-catalyst and the

low-temperature oxidation catalyst, after removing the

removing means 22 for the harmful material.

The purified gas decomposed by the removing means 22

for the harmful material is exhausted to the outside through

a blower 25. The rotary-type rotor 15, which has removed the

harmful material at the concentration and desorption region

20, is transported to the suction region 16 with retaining

the thermal energy only. The transported rotary-type rotor

15 heats the outside air flowed in by a suction fan 23 to a

predetermined temperature and make it flow into the inside

of the display mall 26.

In this instance, the rotation speed of the rotating

rotary-type rotor 15 is preferable to be under three

revolutions per minute in consideration of the durability of

the device, although it is preferable so long as it is fast.

FIG. 7 shows another embodiment of the present

invention, in which the present invention is applied to a

vehicle painting process, and the like.

In such a case, the gas containing volatile organic

chemicals produced in the painting process is exhausted at a

high temperature above 80 ^° C. If the temperature of the exhausted gas is so high, the removing percentage decreases

rapidly because the harmful material such as the volatile

organic chemicals contained in the exhaust gas is not well

adsorbed to the adsorbent such as zeolite, or the activated

charcoal, and the like.

In such a case, if the system suggested by the present

invention is applied, it is possible to operate the removing

means 22 for the harmful material by means of the combustion

heat of the harmful material exhausted by adsorbing and

concentrating the harmful material with the rotary-type

adsorbent together with recovering the thermal energy of

high temperature. It can be explained as follows more

concretely.

The harmful material produced from the painting process

36 is exhausted to the outside through the exhaust line 40.

The exhaust gas is at first flowing into the exhaust region

29, and then the heat exchange and the adsorption of the

harmful material are performed concurrently, and is

exhausted to the outside through the exhaust fan 34. In this

regard, the heat exchange is carried out at the front of the

rotary-type rotor 27, and the adsorption of the harmful

material is carried out at the back thereof. Accordingly,

the rotary-type rotor can be constructed of material for performing the heat exchange principally at the front

portion thereof and material for performing the adsorption

at the back portion thereof in principal . The rotary-type

rotor 27, which has carried out the heat exchange and

adsorption in the exhaust region 29, is transported to the

concentration and desorption region 30, in which the

temperature is increased by means of a detachable burner 31

using a portion of the exhaust gas to thereby remove the

harmful material in the rotary-type rotor 27 using the

thermal energy. The rotary-type rotor 27, which has removed

the harmful material in the concentration and desorption

region, is moved to the suction region 28 to thereby

transfer the heat to the outside air flowed in by the

suction fan 33 to heat the sucked air, and is moved to the

inside of the painting process .

FIG. 8 is a conceptual view showing the system using

the rotary-type rotor according to the present invention.

The system comprises a rotary-type rotor 44 and a casing 45

for receiving it. The system employs a system, in which the

casing 45 is fixed and the rotary-type rotor 44 is rotated

to thereby convert the air flow path. While a rotation shaft

and driving means for rotating the rotary-type rotor 44 are

not shown separately, it can be easily designed by referring to FIG. 10 to be described below by those skilled in the art

of the technical field to which the present invention

pertains .

While, FIG. 9 is a conceptual view showing a system

using distribution plates according to the present invention,

in which distribution plates 47, 49 are arranged for

converting the flow path at the front portion and the back

portion thereof to produce an effect identical with that of

the rotary-type rotor without using the rotary-type rotor

separately.

When the rotary-type rotor is used, it is possible to

reduce the damage and wear of the machine due to the load of

the rotor, and to change the numbers of revolution to

thereby better improve the heat recovery percentage.

Furthermore, an air inducing conduit 113, and a plurality of

opening portions or conduits 61, 62, 63, and 64 can be

designed to define the flow passage between the heat

exchange medium portion (represented by numeral 48 for

denoting the heat exchange medium and the casing integrally)

and the distribution plates 47, 49. The conduits comprise an

inflow opening 62, an exhaust opening 61, a desorption

opening 63 and a desorption conduit 64.

It is possible to form the shape of the air inflow conduit 113 to be tapering, so that a portion joining with

the heat exchange medium 48 becomes large and a portion

joining with the distribution plates 47, 49 becomes small to

thereby reduce the diameter of the distribution plates 47,

49. Also, it is possible to reduce the size of the rotating

distribution plates to thereby reduce the power expense

relative to the gas leakage and the driving.

FIG. 10 is an exploded perspective view showing an

example of the harmful material treatment system using the

rotary-type rotor of the present invention.

Referring to FIG. 10, the treating system comprises

substantially an inside conduit portion 200, a rotary-type

rotor 100, and an outside conduit portion 300.

As for the rotary-type rotor 100, the rotary-type

rotors as described above can be employed. As shown in the

drawings, the rotary-type rotor 110 is comprised of a heat

exchange medium 112 divided into a plurality of regions 115,

116, 117, and 118, and a receiving portion 120, and is

rotated by driving means such as a motor 150, a speed-

reduction gear 152, and a driving shaft 140. The rotation

shaft of the rotary-type rotor 110 has not been shown. In

the present system, the driving means, the speed-reduction

gear 152, and the driving shaft 140 can be mounted at the inside of the casing 120.

The inside conduit portion 200 comprises separation

plates 210, 212, 214, 216 for separating several inlet and outlet flow passages and conduits 220, 222, 224, and 226 added to respective flow passages of the regions divided by

the separation plates .

The inside air flowed in through the inlet conduit 220 of the inside conduit portion progresses through the exhaust region 116 of the rotary-type rotor to be exhausted to the

outside through the outlet conduit 320. In this instance, the adsorption and thermal energy storage operation of the harmful material is produced in the exhaust region 116. The exhaust region 116, which has performed the operation of the adsorption and thermal energy storage is rotated to the

desorption region by means of the rotation of the rotor, and the desorption operation can be produced by the air flowed in from the inlet conduit 324 for the desorption air. The desorbed air is exhausted to the outside through the outlet conduit 324 for the desorption air. In this instance, the

inlet air for the desorption can be heated .by means of heating means such as a burner, and the like for facilitating the desorption.

Thus, when the inlet air is to be heated, it is preferable that a cooling region is formed in the heat exchange medium, as shown in the drawing. This is because,

if the heat exchange medium is at excessively high temperature, the adsorption operation cannot be performed

easily when it returns to the exhaust region again.

The detached heat exchange medium 112 is rotated to

progress into the cooling region 118, and is cooled by the cooling air flowed in from a cooling air inlet opening 326. The cooled air is exhausted through the cooling air outlet conduit 226. Since the cooling air is at higher temperature relative to the outside air, it is possible to reduce the energy for heating the air flowing into the desorption air inlet conduit 224 by forming a flow passage between the cooling air outlet conduit 226 and the desorption air inlet

conduit 224 and recycling it.

Then, when the heat exchange medium progresses into the suction region 115 by the rotation of the rotor, the outside air is flowed in through an outside air inlet opening 322 to pass through the suction region 115. In this instance, it

flows into the inside of the rotor through the outside air outlet opening 222 after recovering the thermal energy stored in the heat exchange medium in the suction region 115. In the embodiments of the present invention as described above, it is preferable to perform sealing at the boundary of the respective region of the exhaust region, the

suction region, the desorption region, and the cooling

region, so that the air is not to be mixed. It is preferable

to use heat resistant material such as silicon rubber,

teflon, and the like as proper sealing material. The sealing

can be accomplished by providing sealing material at proper

position of the distribution plates between the distribution

plates and the heat exchange medium, or at the separation

plate between the separation plate and the heat exchange

medium.

While the present invention has been described with

reference to the preferred embodiments, the present

invention can be performed in various forms without

departing from the spirit or principal features . Accordingly,

the above embodiment is only illustrative in all respects,

and should not be construed to limit the present invention.

The scope of the present invention is represented by the

appended claims, and it is not restricted by the detailed

description of the specification. As a result, all

modifications and changes pertained to the equivalents of

the appended claims are belonged to the scope of the present

invention.

Industrial Applicability

Accordingly, the harmful material treatment system of the present invention can be used advantageously as

facilities for improving the quality of the indoor air and treating the harmful process gas, and as the air conditioning device for improving the work environment.