Title:
TRANSITION METAL-BASED HETEROGENEOUS CARBONYLATION REACTION CATALYST AND METHOD FOR PRODUCING LACTONE OR SUCCINIC ANHYDRIDE BY USING CATALYST
Document Type and Number:
WIPO Patent Application WO/2019/143220
Kind Code:
A1
Abstract:
The present invention relates to a transition metal-based heterogeneous carbonylation reaction catalyst, which has excellent catalyst activity and selectivity in a carbonylation reaction by polymerizing transition metal-based heterogeneous catalyst units by means of cross-linking through the Friedel-Craft reaction and which is easily separated from a product; and to a method for producing a lactone by using the catalyst. The transition metal-based heterogeneous carbonylation reaction catalyst can produce a lactone or succinic anhydride from an epoxide compound while showing high selectivity and facilitates the separation from a product and recycling, and thus the transition metal-based heterogeneous carbonylation reaction catalyst can be used industrially very advantageously.
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Inventors:
YOON SUNGHO (KR)
RAJENDIRAN SENKUTTUVAN (KR)
JIANG JIANWEI (KR)
PARK KWANG HO (KR)
RAJENDIRAN SENKUTTUVAN (KR)
JIANG JIANWEI (KR)
PARK KWANG HO (KR)
Application Number:
PCT/KR2019/000876
Publication Date:
July 25, 2019
Filing Date:
January 22, 2019
Export Citation:
Assignee:
UNIV KOOKMIN IND ACAD COOP FOUND (KR)
International Classes:
B01J31/16; B01J37/00; C07D303/04; C07D305/12
Foreign References:
| KR20170134374A | 2017-12-06 | |||
| KR20120023643A | 2012-03-13 | |||
| KR20130091891A | 2013-08-20 | |||
| KR20160097062A | 2016-08-17 |
Other References:
TANIGUCHI, M. ET AL.: "Synthesis of oligo(p-phenylene)-linked dyads containing free base, zinc(II) or thallium(III) porphyrins for studies in artificial photosynthesis", TETRAHEDRON, vol. 66, 2010, pages 5549 - 5565, XP027169021
Attorney, Agent or Firm:
LEE, Cheo Young et al. (KR)
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