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Title:
UV ACTIVE DERIVATIVES OF Pd(AcAc)2L CATALYZED POLYCYCLOOLEFIN COMPOSITIONS AS OPTICAL MATERIALS
Document Type and Number:
WIPO Patent Application WO/2021/138383
Kind Code:
A1
Abstract:
Embodiments in accordance with the present invention encompass compositions comprising a organopalladium compound, a photoacid generator, a photosensitizer and one or more olefinic monomers which undergo vinyl addition polymerization when said composition is exposed to a suitable actinic radiation to form a substantially transparent film. The monomers employed therein have a range of optical and mechanical properties, and thus these compositions can be tailored to form films having various opto-electronic properties. Accordingly, compositions of this invention are useful in various applications, including as coatings, encapsulants, fillers, leveling agents, among others.

Inventors:
DENG GUODONG (US)
BURTOVYY OLEKSANDR (US)
HAYAKAWA SHUN (US)
Application Number:
PCT/US2020/067399
Publication Date:
July 08, 2021
Filing Date:
December 30, 2020
Export Citation:
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Assignee:
PROMERUS LLC (US)
International Classes:
C08F232/08; C08F2/44; C08F2/48; C08F4/70; C08J5/18; C08K5/06; C08K5/45; C08L45/00; G03F7/004
Foreign References:
JP2010260916A2010-11-18
US20040254318A12004-12-16
US20110104614A12011-05-05
US20040229157A12004-11-18
US20030017404A12003-01-23
Attorney, Agent or Firm:
GUPTA, Balaram (US)
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Claims:
CLAIMS hat is claimed is: A composition comprising: a) one or more olefinic monomers; b) an organopalladium compound selected from the group consisting of a compound of formula (I) and a compound of formula (IA): wherein:

L isa ligand selected from the group consisting ofP(R)i, P(OR>3, 0=P(R)¾ RCN and substituted or unsubstituted pyridines, where R is selected from the group consisting of linear or branched alkyl and fluoroalkyl having the formula CqHxFy, where q is an integer from 1 to 16, x and y are integers from 0 to 2q+l, and the sum ofx and y is 2q+l, (Ce-Cio)aiyl(C1 -Ci6)alkyl and substituted or unsubstituted (C*-Cio)aryl; each A independently is a bidentate monoanionic ligand of formula (Π): herein: n is an integer 0, 1 or 2;

X and Y are independently of each other selected from O, N and S;

Ri, R¾ R¾ Ri, Rs, Rs and R? arc the same or different and each independently selected from the group consisting of hydrogen, linear or branched alkyl and fluoroalkyl having the formula CqHxFy, where q is an integer from 1 to 16, x and y are integers from 0 to 2q+l, and the sum of x and y is 2q+l, (C3-Cio)cycloalkyl, (Ce-Cio)aryl(C1 -Ci6)alkyl and substituted or u ituted (C«-Cio)aryl; provided when either X or Y is 0 or S,

R1 and Rs, respectively, do not exist; c) a photoadd generator selected from the group consisting of: a compound of the formula (ΙΠ): ΟΠ); a compound of the formula (IV): herein: a is an integer from 0 to 5;

AnΘ is selected from the group consisting of tetralds(peatafluoiophenyl)borate, tctrakis(3,5-bis(trifluorometfayl¾Aenyl)borate, tetndds(2-fluorophenyl)borBte, tetralds(3-fluorophenyl)borate, tetrakis(4- fluorophenyl)borate, tetralds(3,5-difluon^hes]yl)borate, tetrakis(2^,4,5- trirafluorophenyl)borate, tetrakis(3,4^,6-tetrafluorophaiyl)borate, tetraltis(3,4>5- trifhron¾>henyl)borate, methyltris(perfluorophenyl)borate, etbyltris(perfluorophenyl)borate, phenyltris(perfluorophenyl)borate, tetralds(l,2,2- trifhioroethylenyl)borate, tetralds(4-tri-l-propylsilyltetrafliicMophenyl)borate, tctrakis(4-dimeth)i-tcrt-butylsilyltetraflu<H(¾Amyl)borate, (triphenylsiloxy)tris(pentafluorophenyl)borale,

(octyloxy)tris(pentafluorophenyl)borate, tetrakis[3,5-bis[l -me&oxy-2,2^-trifluoro-l - (trifluoromethyl)ethyl]phGnyI]borate> tetralris[3-[l-melhoxy-2,2^trifluoio-l - (trifluoromethyl)ethyl] — 5^trifluoromethyl)phenyl]borate, and tetrakis[3-[2^2- tiifluoix>-l-(2^2-trifluoroethoxy)-l -(trifluorometiiyl> ethyl]-5-

(trifluoromethyl)phenyl]borate, P and

Re, R¾ Rio, R11 and R12 are the same or different and each independently selected from the group consisting of halogen, methyl, ethyl, linear or branched (C3-C2o)alkyl, (C3-Cu)cycloalkyl, (Ce-Ci2)bicycloalkyl, (C7-Cu)tricycloelkyl, (Ce-Cio)aiyl, (C6-Cio)aryl(C1 -C3)alkyl, (C1 -Cu)alkoxy, (C3-Cu)cycloalkoxy, (C6-Ci2)bicycloalkoxy, (C?-Ci4)tricycloalkoxy, (C6-Cio)aryloxy(C1 -C3)alkyl, (C6-Cio)aiyloxy, (C«-Cio)thioaiyl, (C1 -C<)alkanoyl(C6-Cio)thioaryl, (C1 -C6)alkoxy(C6-Cio)aroyl(C1 -C6)alkyl and (C6-Cio)tiiioaiyl-(C6-Cio)diarylsulfomum salt; and d) a photosensitizer. The composition according to claim 1 , wherein said olcfinic monomer is of the formula

(V): wherein: m is an integer 0, 1 or 2;

===== is a single bond or a double bond;

Ri3, R14, Ris and R16 are the same or different and each independently selected from the group consisting of hydrogen, halogen, a hydrocaibyl or halohydrocaibyl group selected from methyl, ethyl, linear or branched (C3-Ci6)alkyl, perfluoro(C1 -Ci2)aIkyl, (C3-C u)cycloalky 1, (C¾-Ci2)bicycloalkyl, (C7-Cw)tricycloalkyl, (Ce-Cio)aqd, (Ce-Cio)aiyl(C1 -C6)alkyl, perfluoro(Ce-Cio)aiyl, perfluoro(C*<!io)aryl(C1 -C«)alkyl, methoxy, ethoxy, linear or branched (Cs-Ci6)alkoxy, perfluoro(C1 -Ci2)alkDxy, (C3-Ci2>cycloalkoxy, (C6-Ci2)bicycloalkoxy, (C?-Ci4)tricycloalkoxy, (Ce-Cio)aiyloxy, (C6-Cio)aiyl(C1 -C6)alkoxy, perfluoro(C6-Cio)aryloxy, pefluoro(C6-Cio)aryl(C1 -C3)alkoxy, a group of formula (A): -Z-Aryl (A); a group of formula (Al): (Al); a group of formula (A2): (A2); a group of formula (A3): a group of formula (A4): wherein:

Z is selected from the group consisting of:

0, CO, C(0)0, 0C(0), OC(OX), S, (CRnRiiX 0(CRi7Ru)b, (CRi7R»)bO, C(OXCRi7Ru)b, (CRi7Ris)bC(OX C(0)0(CRi7Ri«)b, (CRi7Ru)bC(0)0, OC(OXCRi7Ru)b, (CR[7Ri8)b0C(0), (CRi7Ru)b0C(0)0, (CR,7Rig>OC(OXXCRi7Rii)b, 0C(0)0(CRi7Rig)b, S(CRi7Ri8)b, (CR|7Ri«)bS, (SiRi7Ris)b, 0(SiRi7Ris)b, (SiRnRit)bO, where Ri7 and Rig arc the same or different and each independently selected from hydrogen, methyl, ethyl, linear or branched (C3-Ci2)alkyl, substituted or unsubstituted (C6-Ci4)aiyl, methoxy, ethoxy, linear or branched (C3-Ce)alkyloxy, (C2-Ce)acyl, (C2- Ci)acyloxys and substituted or unsubstituted (Ce-Ci4)aryloxy; and b is an integer from 0 to 12, inclusive;

Aryl is selected from the group consisting of substituted or unsubstituted phenyl, substituted or unsubstituted biphenyl and substituted or unsubstituted naphthyl, substituted or unsubstituted terphenyl, substituted or unsubstituted anthracenyl substituted or unsubstituted fluorenyl, wherein said substituents are selected from the group consisting of halogen, methyl, ethyl, linear or branched (C3-Ce)alkyl, perfluoro(C1 -Ci2)alkyl, (C3-Ci2>cycloalkyl, (C6-Cio)aryl, (Ci-Cio)aryl(C1 -C6)alkyl, perfluoroCOC io)ary 1, perfluoro((VCio)aryl(C1 -C6)alkyl, methoxy, ethoxy, linear or branched (C3-Cie)aIkoxy, perfluoro(C1 -Ci2)alkoxy, (C3-Ci2)cycloalkoxy, (C6-Cio)aryloxy, (C«-C io)aryl(C1 -C6)alkoxy, perfluoro(C6-Cio)aiyloxy and perfluoro(Ce-Cio)aryl(C1 -C3)alkoxy; k is an integer from 1 to 12;

R23, R24 and R23 are the same or different and each independently selected from the group consisting of hydrogen, methyl, ethyl, linear or branched (C3-Ci:)alkyl, perfluoro(C1 -Ci2)alkyl, methoxy, ethoxy, linear or branched (C3-Cu)alkoxy, (C3-Ci2)cycloalkyl, (C6-Ci2)bicycloalkyl, (C7-Ci4)tricycloalkyl, (Ce-Cio)aryl, (C6-Cio)aryl(C1 -C6)alkyl, perfluoro(C6-Cio)aryl and perfluoro(C6-Cio)aryKC1 -(¾)alkyl; or

R23 and Ra* taken together with the intervening carbon atoms to which they are attached to form a substituted or unsubstituted (Cs-Ci4)cyclic, (C$-Ci4)bicyclic or (C*-Ci4)tricyclic ring; and Aiylene is substituted or unsubstituted bivalent (Ce-Ci4)aiyl; or one of R1 and Ra taken together with one of R3 and R4 and the carbon atoms to which they are attached to form a substituted or unsubstituted (Cs-Ci4)cyclic, (Cs-Ci4)bicyclic or (Cs-Ci4)tricqrclic ring. The composition according to claim 2, wherein said composition comprises at least two different monomers of formula (V) and is in a dear liquid state having a viscosity below 100 centipoise. The composition according to daim 2, wherein said compositions contains said two distinctive monomers of formula (V) in a molar ratio of from 1:99 to 99:1. The composition according to claim 1, wherein said composition forms a substantially transparent film when exposed to suitable actinic radiation. The composition according to claim 5, wherein said film has a transmission of equal to or higher than 90 percent of the visible light. The composition according to claim 1, wherein said bidentate monoanionic ligand is selected from the group consisting of: The composition according to claim 2 further comprising one or more monomers selected from monomer of formula (VI) or monomer of formula (VII), wherein said monomer of formula (VI) is: herein: o is an integer from 0 to 2, inclusive;

D is S1R29R30R31 or a group selected from:

-(OfcXrO-SiRzsRaoRsi (E);

-(ClfcVSiRajRsoRa 1 (F); and

-(SiR29R3o)c-0-SiR29R3oR31 (G); wherein c is an integer from 1 to 10, inclusive, and where one or more of CHa is optionally substituted with (C1 -Cio)alkyl or (C1 -Cio)perfluaroaIkyl;

R26, R27 and Rag are the same or different and independently of each other selected from hydrogen, halogen and hydrocarbyl, where hydrocarbyl is selected from methyl, ethyl, linear or branched (C3-Cia)alkyl, (C3-Cia)cycloalkyl, (C6-Ci2)bicycloalkyl, (C7-Ci4)tricycloalkyl, (C¼-Cio)aryl, (Ci-Cio)aiyl(C1 -C3)alkyl, (C1 -Cu)alkoxy,

(C3-C ia)cycloalkoxy , (OC i2)bicy cloalkoxy , (C7-Ci4)tricycloalkoxy, (C6-Cio)aryloxy(C1 -C3)aIkyl or (Ce-Cio)aryloxy; and R29, R30 and R31 are each independently of one another methyl, ethyl, linear or branched (C3-Cg)alkyl, substituted or unsubstituted (C«-Ci4)aiyl, metboxy ethoxy, linear or blanched (C3-Cg)alkoxy or substituted or unsubstituted (C6-Cu)aiyloxy; said monomer of formula (VII) is: wherein:

Zi is selected from the group consisting of substituted or unsubstituted

(C1 -Cia)alkylene, -(CHaWCHak, KCHaMSaUsRasXOSiRioIUiXCHa).- where d, e and f are independently integers from 0 to 6, inclusive, Rae, R39, R40 and R41 are the same or different and independently of each other selected from methyl, ethyl, linear or branched (C3-Ci2)alkyl, and an arylene selected from the following:

R32, R33, R34, R35, R36 and R37 are the same or different and independently of each other selected from hydrogen, halogen and hydrocarbyl, where hydrocarbyl is selected from methyl, ethyl, linear or hunched (C3-Ci2)alkyl, (C3-Ci2)cycloalkyl,

(C*-C i2)bicycloalkyl, (C7-Cu)tricycloalkyl, (Ce-Cio)aryl, (Ce-Cio)aiyl(C1 -C3)alkyl, (C1 -Ci2)alkoxy, (C3-C i2)cycloalkoxy, (Ci-Ci2)bicycloalkoxy, (C?-Ci4)tricycloalkoxy, (C6-Cio)aryloxy(C1 -C3)alkyl or (C6-Cio)aiyloxy. The composition according to claim 2, wherein the monomer of formula (V) is selected from the group consisting of:

2-(bicyclo[22.1 ]hept-5-en-2-ylmethyl)naphthalene;

1 -(bicyclo [2.2.1 ]hept-5-en-2-y lmethy l)naphthalene;

2-((3-methylbicyclo[2Jl.1 ]hcpt-5-cn-2-yl)methyl)naphthalene;

2-(bicyclo[2.2.1 ]hept-5-en-2-ylmethyl>7-mefcylnaphthalene;

5 -([1,1 '-biphenyl]-3-ylmethyl)bicyclo[2.2.1]hcpt-2-cne;

5-((2'-methyl-[l , 1 '-biphenyl]-3-yl)inethyl)bicyclo[2.2.1 ]hept-2-eae;

5-([l ,1 '-biphenyl]-4-ylmethyl)bicyclo[2.2.1 ]hept-2-ene:

5-([l, r-biphenyl]-2-ylmethyl)bicyclo[2.2. l]hept-2-cne;

5-(2-([l , 1 '-biphmyl]-4-yl)ethyl)bicyclo[22.1 ]hept-2-ene (NBEtPhPh);

S-^-^'-ethyl-fl, 1 '-biphenyl]-4-yl)cthyl)bicyclo[2.2. l]hept-2-enc;

5*(3-([l , 1 '4)iphenyl]-4-yl)propyl)bicyck)[2.2.1 ]hept-2-ene;

5-(2-([l J '-biphenyl]-4-yl)ethoxy)bicyck>[2.2.1 ]hept-2-ene;

5-(2-(2,,4,-dimetiiyl-[l,l,-biiAcnyl]-4-yl)cthoxy)bicyclo[2J.ipiept-2-ene; bicyck)[2.2. l]hept-5-cn-2-yl 2-([l ,l'-biphenyl]-4-yl)acetate; bicyclo[2.2.1 ]hept-5-en-2-ylmethyl [1,1 '^iphenyl]-4-caiboxylate;

5-(2-([l , 1 -biphenyl]-4-yloxy)cthyl)bicyclo[22.1 ]hept-2-ene;

5-(2-([l , 1 '-biphenyl]-2-yloxy)ethyl)bicyclo[2.2.1 ]hept-2-ene (NBEtOPhPfa);

[1,1 '-biphenyl]-4-yl 2-(bicyclo[2.2.1 ]hept-5-cn-2-yl)acetaie;

2-((4-(bicy cio [2.2.1 ]hept-5-en-2-yl)butoxy)methyl)naphthalene;

5-(4-([l , 1 '4)iphcnyl]^yl)butyl)bicyclo[2.2.1 ]hept-2-ene;

(9H-fluoren-9-yI)methyl (bicyclo[2.2.1 ]hept-5-en-2-ylmethyl) carbonate;

1 -(4-bicyclo[2.2. l]hq>t-5-ai-2-yl^iyl)-3,4-dimrtfayl-l H-pym>Ie-2,5-dione;

1 -(4-bicyclo[2.2.1 ]hept-5-cn-2-ylpropyl)-3, 4-dimethyl- 1 H-pyirole-2^-dione;

1 -(4-bicyclo[22. l]hept-5-en-2-ylbutyl>3 ,4-dimtihyl- 1 H-pyrrole-^-dione;

5-(4-phenyIbutyl)bicyclo[22.1 ]hept-2-ene;

5-{2-phenoxyethyl)bicyclo[2.2.1 ]hept-2-ene;

5^3-phenylpropyl)bicyclo[2.2.1]hept-2-ene;

5-phenethoxybicyclo[2.2.1 ]hept-2-ene; 5-((benzyloxy)mcthyl)bicyck)[2.2.1 Jhept-2-me;

5-(phenoxymethyl)bicyclo[2.2.1 ]hept-2-ene;

5-(bcnzyloxy)bicyclo[22.1 ]hept-2-ene;

:i

5-(2-chloroethyl)bicyclo[2.2.1 ]hept-2-ene (NBEtCl);

5-octylbicyclo[2.2. l]hept-2-ene (OctNB);

5-decylbicyclo[2

5-dodecylbicyclo[22.1 ]hept-2-ene (DoDecNB); and

5-tetradecylbicyclo[22.1 ]hept-2-ene (TetraDccNB). . The composition according to claim 8, wherein the monomer of formula (VI) or the monomer of formula (VII) is selected from the group consisting of:

(bicyclo[2.2. l]hept-5-en-2-ylmcthoxyXmethyl)diphenylsilane (NBCHzOSiMePltz);

(bicyclo[22.1 ]hept-5-en-2-ylmethoxyXethyl)diphenylsilane;

(bicyclo[22.1 ]hept-5-en-2-ylmethoxyXethylXmethyl)(phenyl)silane;

(bicyclo[2.2.1 Jhcpt-5-en2-ylmethoxy)dimethyl(phenyI)silane; bicyclo[22.1 ]hept-5-en-2-yltrimethoxysilane; bicyclo[22.1 ]hept-5-en-2-yltriethoxysilane (NBSi(OC2Hs)3; bicyclo[2.2.1 ]hept-5-en2-yl(tert-4nitoxy)dimethoxysilane;

(2-(bicyclo[Z2.1 ]hqrt-5-ei>2-yl)ethy l)trimethoxysilane;

1 ,4-di(bicyclo[2.2.1 ]hept-5-en-2-yl)benzene; 4,4'-di(bicycIo[12.1]hept-5-en-2-yl>l,l,-biphenyl;

4,4n-di(bicyclo[2.2.1 ]hcpt-5-en-2-yl> 1,1':4',1 "-terphenyl;

O i

13-bis(noibomenykthyl)- 1 , 133,-tetramediyldisiloxane; and

1 ,5-bis(norbomenylethyl)- 1 , 1 ,3,3,5,5,-hexamethyltrisiloxane. . The composition according to claim 1, wherein the organopalladium compound of formula (I) or the organopalladium compound of formula (IA) is selected from the group consisting of: palladium (acetylacetonatc)2 tri-isopropylphosphine; palladium (hexafluoroacetylacetonate)2 tri-isopropylphosphine; palladium (hexafluoroacdylacetonate)2 tri-cyclohexylphosphine; palladium (tctarmethylheptenonoate)2 tri-cyclohcxylphosphme; palladium (trifluoroacetylacetonate): (Pd(tfecac)2) ti½>propylphosphine; palladium (pcntafluoropropionyltrifluoroacetonate)2 tri-cyclohexylphosphme; and

P<Kacac)zPCy3. . The composition according to claim 1 , wherein the compound of formula (ΠΙ) or the compound of formula (IV) is selected from the group consisting of: tolylcumytiodomum-tetrakis pentafluorophenylborate;

4^octyloxy)phenyl)(phenyl)iodomum hexafluorophosphate;

4-(octyloxy)phenylXphenyl)iodomum hexafluoroantimonate; bis(4-tert-butylphcnyl)iodonmm perfluoro- 1 -butanesulfonate; bis(4-tert-buiyli*enyl)iodcmium p-tolucncsulfonatc; bis(4-tert-butylphenyl)iodonium triflate; where R42 and R43 are the same or different and each independently selected from linear or branched (Cio-Cujalkyl; diphenyliodoniuni chloride;

(4-tMophenyl)phenyl-<liphcnylsulfbmum hexafluorophosphate; bis-(triphenylsulfomum) sulfide bis- hexafluorophosphate; tris(4-tert-butylpheiiyl)sulfoiiium perfluoro-l-butanesulfooate; tris(4-tcrt-butylphenyl)sulfbnium inflate; triphenylsulfonium chloride;

(4^he∞xyphenyl)diphenylsulfbnium triflate; tris(4^(4-acetylphenyl)thio)phenyl)sulfonhnn tetrakis-pentafhiorophenylboraie; and

(2-(4-methoxynaphthalen- 1 -yl)-2-oxoeihyl)dimethylsulfoiiium tetralds- penlafluorophenylborate. . The composition according to claim 1, wherein the photosensitizer is a compound of formula (VIII) or a compound of formula (IX): wherein

R44, R45 and R46 are the same or different and independently of each other selected from the group consisting of hydrogen, halogen, hydroxy, N0¾ NH¼ methyl, ethyl, linear or branched (C3-Ci2>dkyl, (C3-Ci2)cycloalkyl, (Ce-Ci2)bicycloalkyl, (C7-Ci4)lricycloalkyl, (Ce-Cio)aryL (Cfi-Cio)aryl(C1 -C3)alkyl, (C1 -Cu)alkoxy, (C3-Ci2>cycloalkoxy, (CVCi2)bicycloaIkoxy, (C7-Ci4)tricycloalkoxy, (C6-Cio>iyloxy(C1 -C3)alkyl, (Ce-Cio)aryloxy, C(0XC1 -C6)aIkyl, COOH, C(0)0(C1 -C6)alkyl, and S02(C6-Cio)aryl;

R47 and R*s are the same or different and independently of each other selected from the group consisting of methyl, ethyl, linear or branched (C3-Ci2)alkyl, (C3-Ci2)cycloalkyl, (C¼-C n)bicycloalky 1, (C7-C u)tricycloalky 1, (C«-Cio)aryl and (C6-Cio>uyl(C1 -C3)alkyL . The composition according to claim 1 , wherein the compound of formula (VIE) or the compound of formula (EX) is selected from the group consisting of:

1 -ctioro-4-methoxy-9H-tMoxanthen-9-one;

1 -chloro-4-ethoxy-9H-thioxanthen-9-one;

1 -cMoro-4-pn¾x)xy-9H-thioxanthai-9-one;

1 -cMoro-2-propoxy-9H-tMoxanthen-9-one;

1 -chloro-2-ethoxy-9H-tiiioxanflien-9-one;

1 ^hloro-2-methoxy-9H-ttooxanthen-9-one;

1 -cMoro-4-methyl-9H-tfaioxanthen-9-OM;

1 -chloro-4-etiiyl-9H-thioxantiiai-9-one;

1 -chloro-4-i*enoxy-9H-tiiioxanth«i-9-one;

2-chlorothioxanthen-9-one;

2-isopropyl-9H-thioxanthen-9-one;

9, 10-dimethoxy anthracene;

9,10-diethoxyanlhracene; and

9,10-di-n-butoxyanthracene. . The composition according to claim 1, which is selected from the group consisting of:

5-phenethylbicyclo[2.2.1 ]hept-2-ene, palladhim (hexafluoroacetylacetonate)2 tri-cyclohexylphosphine, tolylcumyliodonium-tetrakis pentafhiorophenylborate and 2- isopropyl-9H-thioxanthen-9-one;

5-phenethylbicyclo[2.2.1 ]hept-2-ene, palladium (hexaflix>roacetylacetonate)2 tri-isopropylphosphine; tolylcumyliodonium-tetrakis pentafluorophenylborate and2- isopropyl-9H-thioxanthen-9-one;

5-phenethylbicyclo[2.2.1 ]hept-2-ene, Pd(acac)2PCy3; tolylcumyliodonium-tetrakis pentafluoropheiiylborale and 2-isopropyl-9H-thioxanthen-9-one; and

5-decylbicyclo [22.1 ]hept-2-ene, palladium (hexafluoroacetylacetonate)2 tri-cyclohexylphosphine, iodonhnn, diphenyl-, 4,4'-di-(Cio-Ci3)alkyl derivatives, tetrakis(23,4,5,6-pentafluorophenyl)bor8les and 2-isopropyl-9H-thioxanthen-9-one. . A kit for forming a substantially transparent film comprising: a) one or more olefinic monomers; b) an organopalladium compound selected from the group consisting of a compound of formula (I) and a compound of formula (IA):

(D Lisa ligand selected from the group consisting ofP(R)3, P(OR)3, 0=P(R)3, RCN and substituted or unsubstituted pyridines, where R is selected from the group consisting of linear or branched alkyl and fluoroalkyl having the formula CqHxFy, where q is an integer from 1 to 16, x and y are integers from 0 to 2q+l, and the sum of x and y is 2q+l, (C3-Cio)cycloalkyl, (CeCio)aryl(C1 -Ci6)alkyl and substituted or unsubstituted (Ce-Cio)aiyl; each A independently is a bidentate monoanionic ligand of formula (Π): wherein: n is an integer 0, 1 or 2;

X and Y are independently of each other selected from 0, N and S;

R1, R¾ Rj, Ri, Rs, Re and R? are the same or different and each independently selected from tiie group consisting of hydrogen, linear or bnmched alkyl and ftuoroalkyl having the formula CqH*Fy, where q is an integer from 1 to 16, x and y are integers from 0 to 2q+l , and the sum of x and y is 2q+l, (C3-Cio)cycloalkyl, (C6-Cio)aryl(C1 -Ci6)alkyl and substituted or unsubstituted (Ce-Cio)axyl; provided when either X or Y is 0 or S,

R1 andRj, respectively, do not exist; c) a photoacid generator selected from the group consisting of: a compound of the formula (ΙΠ): (HI); and a compound of the formula (TV): wherein: a is an integer from 0 to 5;

AnΘ is selected from the group consisting of tetrakis(pentafluorophenyl)borate, tetraltis(3,5-bis(trifluoromethyl)phenyl)borate, tetrakis(2-fluorophenyl)boratei tetrakis(3-fluorophenyl)borate, tetrakis(4- fluorophenyl)borate, tetrakis(3,5-<lifluorophenyl)borate, tetrakis(23,4,5- tetrafluorophenyfyborate, tetrakis(3,4^,6-tetrafluorophenyl)borate, tetrakis(3,4,5- trifluorophenyl)boiate, methyltris(perfluorophenyl)borate, ethyltris(perfluorophenyl)borate, phenyhris(perfluorophenyl)borate, tetndds(l,2,2· trifluoroetiiylenyl)borate, tetralds(4-tri- 1 -propylsilyltetrafluorophenyl)borate, tetrakis(4-dimethyl-tert-butylsilyltetrafluorophenyl)borate, (triphenylsiloxy)tris(peiitafliiorophenyl)borale,

(octyloxy)tris(pentafluorophenyl)borate, tetralris[3,5-bis[ 1 -methoxy-2,2^-trifhioro- 1 - (trifluoronMthyl)ethyl]phenyl]borate, tetralds[3-[l-methoxy-2A2-trifluMO-l- (trifluOTomethyl)ethyl] — 5^trifluoromethyl)phenyl]borate, and tetralds[3-[2^L2- trifluoro- 1 -(2^,2-trifluoroethoxy)- 1 -{trifhioromethy 1)- ethyl]-5-

(trifluoromethyl)phenyl]borate, and

Rs, Rg, Rio, Rii and R12 are the same or different and each independently selected from the group consisting of halogen, methyl, ethyl, linear or branched (C3-Cio)alkyl, (C3-Cu)cycloalkyl, (Cc-Ci2)bicycloalkyl, (C7-Ci4>tricycloalkyl, (Ce-Cio)aiyl, Cio)aiyl(C1 -C3)alkyl, (C1 -Ci2)alkoxy, (C3-C u)cycloalkoxy , (OC i2)bicycloalkoxy, (C7-Ci4)tricycloalkoxy, (C*-Cio)aryloxy(C1 -C3)alkyl, (C6-Cio)aiyloxy, (Ce-Cio)thioaiyl, (C1 -C6)alkimoyl(C6-Cio)thioaiyl, (C1 -C6>alkoxy(C6-Cio)aroyl(C1 -C6)alkyl and (C6-Cio)thioaryl(C6-Cio)diarylsulf<mium salt; and d) a photosensitizer.

. The kit according to claim 16, which contains at least two distinct first and second monomers of formula (V), wherein the first monomer is completely soluble in the second monomer, and when said composition is exposed to suitable actinic radiation for a sufficient length of time it forms a substantially transparent film having at least 90 percent of visible light transmission. . The kit according to claim 16, which is selected from the group consisting of:

5-phenethylbicyclo[2.2. l]hept-2-ene, palladium (hexafluoroacetylacetonate)2 tri-cyclohexylphosphine, tolylcumyliodonium-tetrakis pentafluorophenylborate and2- isopropyl-9H-thioxanthen-9-one;

5-phenethylbicyclo[2.2.1 ]hept-2-ene, palladium (hexafluoroacetylacetonate)2 tri-isopropylphosphine; tolylcumyliodonium-tetrakis pmtafluorophenylborate and 2- isopropyl-9H-thioxanthen-9-one;

5-pbenethylbicyclo[2.2. ljhcpt-2-ene, Pd(acac)2PCy3; tolylcumyliodonium-tetrakis pentafluorophmylborate and 2-isqprc¾>yl-9H-thioxanthen-9-one; and

5-decyIbicyclo[2.2.1 ]hept-2-ene, palladium (hexafluoroacetylacetonate): tri-cyclohexylphosphine, iodonium, diphenyl-, 4,4'-di-(Cio-Ci3)alkyl derivatives, tetrakis(2^,4,5,6-pentafluorophenyl)borates and 2-isopropyl-9H-thioxanthen-9-one. . A film formed from the composition of claim 1. . A composition comprising: a) one or more monomers of formula (VA): wherein: m is an integer 0, 1 or 2; at least one of R», RM, RIS and Rie is O-Aryl; and the remaining R13, Ru, Ris and Ris are the same or different and each independently selected from the group consisting of hydrogen, halogen, a hydrocarbyl or halohydrocarbyl group selected from methyl, ethyl, linear or branched (C3-Cie)alkyl, perfluoro(C1 -Ci2)alkyl, (C3-Ci2)cycloalkyl, (C<s-Ci2)bicycloalkyl, (C?-Ci4)tricycloalkyl, (C6-Cio)aryl, (C«-Cio)aryl(C]-C6)alkyl, perfluoro(C<i-Cio)aryl, perfluoro(Ce-Cio)aiyl(C1 -C6)alkyl, methoxy, ethoxy, linear or branched (C3-Ci6)alkoxy, perfluoro(C]-Ci2)alkoxy, (C3-Cn)cycloalkoxy, (C6-Ci2)bicycloalkoxy, (C7-C i4)tricycloalkoxy, (Ci-Cio)aiyloxy> (C¾-Cio)aryl(C1 -C6)alkoxy, perfluoro(Ce-Cio)aryloxy, perfluoro(Ce-Cio)aiyl(C1 -C3)alkoxy, a group of formula (Al): a group of formula (A2): a group of formula (A3): (A3); and a group of formula (A4):

(A4); herein: Aryl is selected from the group consisting of substituted or unsubstituted phenyl, substituted or unsuhstitirted biphenyl and substituted or unsubstituted naphthyl, substituted or imsubstituted terphenyl, substituted or unsubstituted anthracenyl substituted or unsubstituted fluorenyl, herein said substituents are selected from the group consisting of halogen, methyl, ethyl, linear or branched (C3-C$)alkyl, perfluoro(C1 -Ci2)alkyl, (C3-Ci2>cycloalkyl, (C¾-Cio)aryl, (Cd-Cio)aryl(C1 -C6)alkyl, perfluoro(C6-C io)aryl, perfluoro(Ci-C io)aryl(Ci -C6)alkyl, methoxy, ethoxy, linear or branched (Ca-Ci6)alko*y, perfluoro(C1 -Ci2)alkoxy, (C3-C i2>cycloalkoxy, (C6-Cio)aryloxy, (C<-Cio)aiyl(C1 -C6)alkoxy, perfluoro(C6-Cio)aryk)xy and perfluoro(C6-Cio)aryl(C1 -C3)alkoxy; k is an integer from 1 to 12;

R23, Ri4 and R25 are the same or different and each independently selected from the group consisting of hydrogen, methyl, ethyl, linear or branched (C3-Ci2)alkyl, perfluoro(C1 -Ci2)alkyl, methoxy, ethoxy, linear or branched (Ca-Ci2)alkoxy, (C3-Ci2)cycloalkyl, (0-Ci2)bicycloalkyl, (C?-Ci4)tricycloalkyl, (Ce-Cio)aiyl,

(C«-C io)aryl(C i-Cfi)alkyl, perflumoCOCi o)aryl and perfluoro(C6-Cio)aryl(C1 -C6)alkyl; or

R23 and R24 takm together witii tiie intervening carbon atoms to which they are attached to form a substituted or unsubstituted (Cs-Cu)cyclic, (Cs-Ci4)bicyclic or (C5-Ci4)tricyclic ring; and Arylme is substituted or unsubstituted bivalent (C¼-Ci4)aiyl; or one of Ri3 and Ru taken together with one ofRis and R½ and the carbon atoms to which they are attached to form a substituted or unsubstituted (Cj-Cu)cyclic, (Cs-Ci4)bicyclic or (Cs-C i4>tricyclic ring; b) one or more monomers of formula (VB): wherein: p is an integer 0, 1 or 2; Rsi, RS2, R33 and RM are the same or different and each independently of one another is selected from hydrogen, linear or branched alkyl and fluoroalkyl having the formula CqHxFy, where q is an integer from 1 to 16, x and y are integers from 0 to 2q-H, and the sum of x and y is 2q+l, hydroxy(C1 -Ci6)alkyl, (C3-Ci2)cycloalkyl,

(Cfr-C i2)bicy cloalkyl, (C7-C i4)tricycloalkyl, (OCio)aryl, (C¾-Cio)aryl(C1 -C3)alkyl, perfluoro(C6-Cio)aryl, pofluMo(Ce-Cio)aryl(C1 -C6)allyl, di(C1 -C2)alkylinaleimide(C3-C6)alkyl, di(C l -C2)alky lmaleimide(C2-C6)alkoxy(C i -C2)alky 1, hydroxy, (C1 -Ci2)alkoxy,

(C3-C i2>cy cloalkoxy , (Ce-Ci2)bicycloalkoiqr, (C?-Ci4)tricycloalkoxy, ((¾-Cio)aryloxy(C1 -C3)aIkyl, (C5-C1 o)heteroaryloxy(C 1 -C3)alky 1, (Ce-Cio)arylory, (C5-Cio)heteroaiyloxy or (C1 -C6)acyloxy; c) an organopalladium con¾x)und selected frmn the group consisting of a compound of formula (I) and a compound of formula (IA): wherein:

L is a ligand selected from the group consisting of P(R)¾ P(OR)a, 0=P(R)3, RCN and substituted or unsubstituted pyridines, where R is selected from the group consisting of linear or branched alkyl and fluoroalkyl having the formula CqH*Fy, where q is an integer from 1 to 16, x and y are integers from 0 to 2q+l, and the sum of x and y is 2q+l, (C3-Cio)cycloalkyl, (C6-Cio)aryl(C1 -Ci6)alkyl and substituted or unsubstituted (C6-Cio)aryl; each A independently is a bidentate monoanionic ligand of formula (Π): wherein: n is an integer 0, 1 or 2;

X and Y are independently of each other selected from O, N and S;

R1, R¾ Ra, Rt, Rs, ¾ and R? arc the same or different ami each independently selected from the group consisting of hydrogen, linear or branched alkyl and fluoroalkyl having foe formula CqHxFy, where q is an integer from 1 to 16, x and y are integers from 0 to 2qH, and the sum of x and y is 2q+l, (C3-Cio)cycloalkyl, (C$-Cio)aryl(C1 -Ci6)alkyl and substituted OT unsubstituted (C6-Cio)aryl; provided when either X or Y is O or S,

R1 and ¾, respectively, do not exist; d) a photoacid generator selected from the group consisting of: a compound of the formula (ΙΠ): (in); a compound of the formula (IV): wherein: a is an integer from 0 to S; An® is selected ftom the group consisting of tetrakis(penlafluorophenyl)borate, tetrakis(3 ,5-bis(trifluoromethyl)phenyI)borate, tetralds(2-fluorophenyl)borate, tetrakis(3 -fhiorophenyl)boratc, tetrakis(4- fluorophenyI)borale, tetrakis(3 ,5-difluorophenyl)borale, tetrakis(2,3,4,5- tetrafluorophenyl)borales tetrakis(3,4,5,6-tetrafluorophenyl)borate, tetralds(3,4,5- trifluorophenyl)borate, methyltris(perfhx>rophenyl)borate, ethyltris(perfluorophenyl)borate, phenyltris(perfluorophenyl)borate, tetrakis(l,2,2- trifluoroethylenyl)borate, tetrakis(4-tri- 1 -propylsilyltetrafluorophenyI)borate, tetralris(4→Iimethyl-tert-butylsilyltetrafluorophenyl)borate, (triphenylsiloxy)tris(pentafluorophenyl)borate,

(octyloxy)tris(pentafluorophenyl)borate, tetralris[3,5-bis[ 1 -mcthoxy-2^^-trifluoro- 1 - (trifliMromethyl)ethyl]phrayl]borale, tctrakis[3- [1 -methoxy-2,2^-tri£lu(HO- 1 - (trifluoromethyl)ethyl]-5^trifluoromethyl)phenyl]borate, and tetiakis[3'[2,2,2- trifluoro- 1 -(2^,2-trifluoroethoxy)- 1 -{trifluoromethy 1)- cthyl]-5-

(trifluoromelhyl)phmyl]boratc, and

¾, R¾ Rio, R11 and R12 are the same or different and each independently selected from the group consisting of halogen, methyl, ethyl, linear or branched (C3-C2o)alkyl, (C3-Cu)cycloalkyl, (C6-Ci2)bicycloalkyl, (C?-Ci4)tricycIoalkyl, (C$-Cio)aryl, (C6-Cio)aiyl(C1 -C3)alkyl, (C1 -Ci2)alkoxy, (C3-Cn)cycloalkoxy, ((VC i2)bicycloalkoxy, (C7-Ci4)tricycloalkoxy, (CVCio)aiyloxy(C1 -C3)aIkyl, (C6-Cio)aryloxy, (C6-Cio)thioaryl, (C1 -C6)alkanoyl(C6-Cio)tiiioaryl, (C1 -Ce)alkoxy(C6-Cio)aroyl(C1 -C6)alkyl and (C6-Cio)thioaryl-(C6-Cio)diaiylsulfonium salt; and c) a photosensitizer.

Description:
UV ACTIVE DERIVATIVES OF Pd(AcAc)2L CATALYZED POLYCYCLOOLEFIN COMPOSITIONS AS OPTICAL MATERIALS

CROSS REFERENCE TO RELATED APPLICATIONS This application claims the benefit of U. S. Provisional Application No.62/954,922, filed December 30, 2019, which is incorporated herein by reference in its entirety.

BACKGROUND OF THE INVENTION

Field of the Invention

Embodiments in accordance with the present invention relate generally to a single component mass polymerizable polycycloolefin monomer compositions having high optical transparency and exhibiting suitable refractive index that match the refractive index of layers in optical devices, such as optical sensors, light emitting diodes (LEDs), organic light emitting diode (OLED), among other devices. More specifically, this invention relates to single component compositions encompassing norbomene (NB) based olefinic monomers, which undergo mass vinyl addition polymerization in the presence of derivatives of Pd(AcAc) 2 L when photolyzed to form optical layers having utility in a variety of opto-electronic applications including as encapsulants, coatings, and fillers.

Description of the Ait

Organic light emitting diodes (OLEDs) are gaining importance in a variety of applications, including flat panel televisions and other flexible displays, among other applications. However, conventional OLEDs, particularly, bottom emitting OLEDs suffer from a drawback in that only about half of the generated photons are emitted into the glass substrate out of which 25% are extracted into air. The other half of the photons are wave- guided and dissipated in the OLED stack. This loss of photons is primarily attributed to the refractive index (n) mismatch between the organic layers (n=1.7-1.9) and the glass substrate (n*l .5). By matching the refractive index of the substrate (η·1.8) and organic layers and augmenting the distance of the emission zone to the cathode to suppress plasmonic losses light extraction into the substrate can be increased to 80-90%. See, for example, G. Gaertner et al., Proc. OfSPIE, Vol. 6999, 69992T pp 1-12 (2008).

In addition, OLEDs also pose other challenges; in that OLEDs being organic materials, they are generally sensitive to moisture, oxygen, temperature, and other harsh conditions. Thus, it is imperative that OLEDs are protected from such harsh atmospheric conditions. See for example, U. S. Patent Application Publication No. US2012/0009393

Al. In order to address some of the issues faced by the art, U. S. Patent No. 8,263,235 discloses use of a light emitting layer formed from at least one organic light emitting material and an aliphatic compound not having an aromatic ring, and a refractive index of the light emitting from 1.4 to 1.6. The aliphatic compounds described therein are generally a variety of polyalkyl ethos, and the like, which are known to be unstable at high temperatures, see for example, Rodriguez et al., I & EC Product Research and Development, Vol. 1, No. 3, 206-210 (1962).

U. S. Patent No. 9,944,818 and U. S. Patent No. 10,266,720, disclose a two component mass polymerizable composition which is capable of tailoring to the desirable refractive index and is suitable as a filler and a protective coating material, thus potentially useful in the fabrication of a variety of OLED devices.

The co-pending U. S. Patent Application No. 15/861,801, filed January 4, 2018, discloses a single component mass vinyl addition polymerizable composition which is thermally activated and capable of tailoring to the desirable refractive index and is suitable as a filler and a protective coating material, thus potentially useful in the fabrication of a variety of OLED devices.

However, there is still a need for organic filler materials that complement the refractive index of OLEDs and yet exhibit high transparency and good thermal properties, among other desirable properties. In addition, it is desirable that such organic filler materials readily form a permanent protective coatings and are available as a single component composition for dispensing with such OLED layers simply by exposing to suitable actinic radiation at ambient temperature.

Thus, it is an object of this invention to provide organic materials that overcome the gaps faced by the art. More specifically, it is an object of this invention to provide a single component composition that will mass polymerize when exposed to suitable actinic radiation under the conditions of the fabrications of an OLED device. It is further an object of this invention to provide stable single component mass polymerizable composition with no change in viscosity at or below normal storage conditions but which undergoes mass polymerization only when exposed to suitable actinic radiation.

It is further an object of this invention to provide single component composition that can be used in a variety of other applications including for example 3D printing, ink- jettable coatings, sealants, and the like. Other objects and further scope of the applicability of the present invention will become apparent from the detailed description that follows.

SUMMARY OF THE INVENTION

Surprisingly, it has now been found that by employing a single component composition, it is now possible to fabricate a variety of devices including for example an OLED device having a transparent optical layer which features hitherto unachievable properties, i.e., refractive index in the range of 1.4 to 1.6 or higher, high colorless optical transparency, desirable film thickness of the filler layer typically in the range of 10 to 20 μm but can be tailored to lower or higher film thickness depending upon the intended application, compatible with the OLED stack, particularly the cathode layer (a very thin layer on the top of the OLED stack), compatible with polymerization of the formulation on the OLED stack, including fast polymerization time and can be photolytically treated at ambient fabrication conditions, adhesion to both OLED stack and glass cover, and the like. It is also important to note that the compositions of this invention are expected to exhibit good uniform leveling across the OLED layer which typically requires a low viscosity. Further, compositions of this invention are also expected to exhibit low shrinkage due to their rigid polycycloolefinic structure. In addition, as the components of this invention undergo fast mass polymerization upon application they do not leave behind any fugitive small molecules which can damage the OLED stack. Generally, no other small molecule additives need to be employed thus offering additional advantages. Most importantiy, the compositions of this invention are stable (i. e, no change in viscosity) at ambient atmospheric conditions including up to 40 °C for several days to weeks and undergo mass polymerization only when exposed to suitable actinic radiation. The compositions undergo mass vinyl addition polymerization very quickly when subjected to such actinic radiation and generally the compositions become solid objects in few minutes, i.e., within 1-10 minutes and more generally in less than one hour.

Advantageously, the compositions of this invention are also compatible with a “one drop fill" (commonly known as “ODF"). In a typical ODF process, which is commonly used to fabricate a top emission OLED device, a special optical fluid is applied to enhance the transmission of light from the device to the top cover glass, and the fluid is dispensed by an ODF method. Although the method is known as ODF which can be misleading because several drops or lines of material are generally dispensed inside the seal lines. After applying the fluid, the fluid spreads out as the top glass is laminated, analogous to die-attach epoxy. This process is generally carried out under vacuum to prevent air entrapment. The present invention allows for a material of low viscosity which readily and uniformly coats the substrate with rapid flow in a short period of time. Even more advantageously, the present invention overcomes the deficiencies faced by the prior art in that a tingle component composition is much more convenient than employing a two component system especially in an ODF method.

Accordingly, there is provided a single component composition encompassing a) one or more olefinic monomers; b) an organopalladium compound of formula (I) or an organopalladium compound of formula (IA) as described herein; c) a photoacid generator as described herein; and d) a photosensitizer.

In another aspect of this invention there is also provided a kit encompassing the composition of this invention fin· forming a three dimensional object, such as for example, a transparent film.

DETAILED DESCRIPTION The terms as used herein have the following meanings:

As used herein, the articles “a,” “an,” and “the" include plural referents unless otherwise expressly and unequivocally limited to one referent

Since all numbers, values and/or expressions referring to quantities of ingredients, reaction conditions, etc., used herein and in the claims appended hereto, are subject to the various uncertainties of measurement encountered in obtaining such values, unless otherwise indicated, all are to be understood as modified in all instances by the term “about"

Where a numerical range is disclosed herein such range is continuous, inclusive of both the minimum and maximum values of the range as well as every value between such minimum and maximum values. Still further, where a range refers to integers, every integer between the minimum and maximum values of such range is included. In addition, where multiple ranges are provided to describe a feature or characteristic, such ranges can be combined. That is to say that unless otherwise indicated, all ranges disclosed herein are to be understood to encompass any and all sub-ranges subsumed therein. For example, a stated range of from “1 to 10" should be considered to include any and all sub-ranges between the minimum value of 1 and the maximum value of 10. Exemplary sub-ranges of the range 1 to 10 include, but are not limited to, 1 to 6.1, 3.5 to 7.8, and 5.5 to 10, etc.

As used herein, the symbol denotes a position at which the bonding takes place with another repeat unit or another atom or molecule or group or moiety as appropriate with the structure of the group as shown.

As used herein, “hydrocaityl” refers to a group that contains carbon and hydrogen atoms, non-limiting examples being alkyl, cycloalkyl aryl, aralkyl, alkaryl, and alkenyl. The term t hat theocarbyl refers to a hydrocaibyl group where at least one hydrogen has been replaced by a halogen. The term perhalocarbyl refers to a hydrocaibyl group where all hydrogens have been replaced by a halogen.

As used herein, the expression “(C 1 -C 6 alkyl" includes methyl and ethyl groups, and straight-chained or branched propyl, butyl, pentyl and hexyl groups. Particular alkyl groups are methyl, ethyl, n-propyl, isopropyl and tert-butyL Derived expressions such as “(C 1 -C 4 )alkoxy”, “(C 1 -C 4 )thioalkyP ‘XC 1 -C 4 )alkoxy(C 1 -C 4 )alkylq “hydroxy(C 1 -C 4 )alkyl”, “(C 1 -C 4 )alkylcarbonyll “(C 1 -C 4 )alkoxycarbonyl(C 1 -C 4 )alkll, “(C 1 -C 4 )alkoxycarbonyl "

“diphenyl((1C 1 -C 4 )alkyl, “phenylC 1 -C 4 alkyl “phenylcaiboxy(C 1 -C 4 )alkyI” and “phcnoxy(C]1C 4 )alkyr are to be construed accordingly.

As used herein, the expression “cycloalkyl” includes all of the known cyclic groups. Representative examples of “cycloalkyl” indudes without any limitation cyclopropyl, cyclobutyl, cyclopentyl, cyclohexyl, cycloheptyl, cyclooctyl, and the like. Derived expressions such as “cycloalkoxy”, “cycloalky lalkyl”, “cycloalkylaryl" “cycloalky lcarbonyl” are to be construed accordingly .

As used herein, the expression “(C 1 -C4 ) perfiuoroaIkyl meats that all of the hydrogen atoms in said alkyl group are replaced with fluorine atoms. Illustrative examples include trifluoromethyl and pentafluoroethyl, and straight-chained or branched heptafluoropropyl, nonafluorobutyl undecafluoropentyl and tridecafluorohexyl groups. Derived expression, “(C 1 - C 6 )perfluoroalkoxy”, is to be construed accordingly, ft should further be noted dial certain of the alkyl groups as described herein, such as for example, “(C 1 -C 6 )alkyl” may partially be fluorinated, that is, only portions of the hydrogen atoms in said alkyl group are replaced wife fluorine atoms and shall be construed accordingly.

As used herein, the expression “(C 6 -C 10 )aryl means substituted or unsubstituted phenyl or naphthyl. Specific examples of substituted phenyl or naphthyl include o-, p-, m-tolyl, 1,2-, 1,3, 1,4-xylyl, 1-methylnaphthyl, 2-methylnaphthyl, etc. “Substituted phenyl” or “substituted naphthyl” also include any of the possible substituents as further defined herein or one known in the art

As used herein, the expression "(C 6 -C 10 )aryl(C 1 -C4) " means that the (C 6 -C 10 )aryl as defined herein is further attached to (C 1 -C 4 )alky as defined herein. Representative examples include benzyl, phenylethyl, 2-phenylpropyl, 1-naphthylmethyl, 2-naphthylmetihyl and the like. “Halogen” or “halo” means chloro, fluoro, bromo, and iodo. hi a broad sense, the term “substituted" is contemplated to include ail permissible substituents of organic compounds, hi a few of the specific embodiments as disclosed herein, ehe term “substituted” means substituted with one or more substituents independently selected from the group consisting of (C 1 -C 6 )alkyl, (C 2 -C 6 )alkeyn l (C 1 -C 6 )perfluoroalkyl, phenyl, hydroxy, -CO2H, an ester, an amide, (C1 -C 6 )alkoxy, (C 1 -C 6 )thioalkyi and

(C 1 -Ci)perfluoroalkoxy. However, any of the other suitable substituents known to one drilled in the art can also be used in these embodiments.

It should be noted dial any atom with unsatisfied valences in the text, schemes, examples and tables herein is assumed to have the appropriate number of hydrogen atom(s) to satisfy such valences.

By the torn "derived" is meant that the polymeric repeating units are polymerized (formed) from, for example, polycyclic norbornee-type monomers in accordance with formulae (I) to (IV) wherein the resulting polymers are formed by 2,3 enchainment of norbornene-type y monomers as shown below:

Accordingly, in accordance with the practice of this invention there is provided a single component composition encompassing a) one or more olefinic monomers; b) an organopalladium compound selected from the group consisting of a compound of formula (I) and a compound of formula (IA):

L is a ligand selected from the group consisting of P(R) 3 P(OR) 3, O-PR) 3 , RCN and substituted or unsubstituted pyridines, where R is selected from the group consisting of linear or branched alkyl and Ffuoroalkyl having the formula C q H x F y , where q is an integer from 1 to 16, x and y are integers from 0 to 2q+1 and the sum of x and y is 2q+1 (C3-Cio)cycloalkyl, (C6-Cio)aiyl(C 1 -Ci6)alkyl and substituted or unsubstituted (C 6 -C 10 )aryl; each A independentiy isabidentate monoanionic ligand of formula (Π): ; wherein: n is an integer 0, 1 or 2;

X and Y are independently of each other selected from 0, N and S;

R 1 , R 2 R 3 , R 4 , R 5 , R 6 and R 7 are the same or different and each independently selected from the group consisting of hydrogen, linear or branched alkyl and fluoroalkyl having the formula CqH*F y , where q is an integer from 1 to 16, x and y are integers from 0 to 2qH, and the sum of x and y is 2q+l, (C 3 -C 10 )cycloalkyl, (C 6 -C 10 )aryl(C 1 -C 16 )alkyl and substituted or unsubstituted (C 6 -C 10 ) aryl; provided when either X or Y is 0 or S, R 1 and Rs, respectively, do not exist; c) a photoacid generator selected from the group consisting of: a compound of the formula (ΙΠ): (iii) a compoundnd of the formula (IV): wherein: a is an integer from 0 to 5; An Θ is selected from the group consisting of tetrakis(pentafluorophenyl)borate, tetrakis(3,5-bis(trifluoromethyl)phenyl)borate, tetrakis(2- fhiorophenyl)boratc, tetrakis(3-fluorophenyl)borate, tetrakis(4-fluorophenyl)boiate, tetrakis(3,5-diluorophenyI)borate, tetrakis(2,3,4,5, -tetrafluorophenyl)borate, tetrakis(3, 4,5,6- tetrafluorophenyl)borate, tetrakis(3,4,5-trifhiorophenyl)borate, methyltris(perfiluophenyl)boratc, cthyltris(perfluorophcnyI)borate, phenyltris(perfluorophenyl)boratc, tetrakis(l ,2,2-trfluoroethylenyI)borate, tetrakis(4-tri-l- propylsiyhdrafluorophenyl)bofiite, tetrakis(4-dinie1hyl-tert-butylsilyltetrafluarophenyl)borate , (triphenylsiloxy)tris(pentafluorophenyl)borate, (octytoxy)tris(pentafluorophenyl)borate, tetrakis[3,5-bis[l-methoxy-2^2-trifluoro-l-(trifluoromcthyl) ethyI]phenyl]boratc, tetrakis[3- [ 1 -methoxy-2^2-trifluoro- 1 -(trifluoromethyljcthyl}- 5-(trifluoromethyl)phenyl]borate, and tetrakis[3-[2A2-irifluoro- 1 -(2A2-trifluoroedx»cy)-l-(triflu«Omtihyl)- ethylJ-5- (trifluoromethyl)phenyl]borate, and

Rs, R¾ Rio, R11 and R« are the same or different and each independently selected from the group consisting of halogen, methyl, ethyl, linear or branched (C3-Ca))alkyl, (C3-Ci2)cydoalkyl, (C6-Ci2)bicycloalkyl, (C7-Cu)tricycloalkyl, (Ce-Cio)aiyl, (Ce-Cio)aryl(C 1 -C3)alkyl, (C 1 -Cujalkoxy, (C3-Ci2)cycloelkaxy, (C6-Ci2)bicycloalkoxy, (CrCi4)tricycloalkoxy, (Ce-Cio)afyk«y(C 1 -C3)alkyi, (OCio)aryk>xy, (C¾-Cio)thioaiyi, (C 1 -Ce)alkanoyl(C6-Cio)thioaiyl, (Ci^)alkoxy(C6-Cio)aroyl(C 1 -C6)alkyl and (Ce-Cio)thioaiyl-(Ce-Cio)diaiy]sulfi»ium salt; and <0 a photosensitizer.

It should be noted that the ligand, L of the otganopalladium compounds of formulae (I) or (IA) can generally be a Lewis Base, which is coordinately bonded to palladium. That is, the Lewis Base is bonded to palladium by sharing both of its lone pair of electrons. Accordingly, any of the Lewis Base known in the art can be used for fob purpose. Advantageously, it has now been found that a Lewis Base, which can dissociate readily under foe polymerization conditions as described further in detail below generally provides more suitable compounds of formula (0 or (IA) as polymerization catalysts, Le., initiators. Thus, in one aspect of fob invention judicious selection of the Lewis Base (LB) will provide a modulation of foe catalytic activity of the compounds of fob invention.

Accordingly, it has now been found that suitable LBs that can be employed include without any limitation substituted and unsubstituted nitriles, including alkyl nitrile, aryl nitrile or aralkyl nitrile; phosphine oxides, including substituted and unsubstituted trialkyl phosphine oxides, triaiyl phosphine oxides, triaiylalkyl phosphine oxides, and various combinations of alkyl, aryl and aralkyl phosphine oxides; substituted and unsubstituted pyrazines; substituted and unsubstituted pyridines; phosphites, including substituted and unsubstituted trialkyl phosphites, triaryl phosphites, triaiylalkyi phosphites, and various combinations of alkyl, aryl and aralkyl phosphites; phosphines, including substituted and unsubstituted trialkyl phosphines, triaiyl phosphines, triaiylalkyi phosphines, and various combinations of alkyl, aryl and aralkyl phosphines. Various other LBs that may be employed include various ethers, alcohols, ketones, amines and anilines, arsines, stibines, and the like.

In some embodiments of this invention, the LB is selected from acetonitrile, propkxiitrile, n-butyronitrile, tert-butyronitrile, benzonhrile (CeHsCN), 2,4,6-trimethylbezomtrile, phenyl acetonitrile (CsHsCHaCN) » pyridine, 2-methylpyridine, 3-methylpyridine, 4-methylpyridine, 2,3-dimethylpyridine, 2,4-dimethylpyridine, 2,5-dimethylpyridine, 2,6-dimethylpyridine, 3,4-dimethylpyridine, 3,5-dimethylpyridine, 2,6-di-t-butylpyridine, 2,4-di-t-butylpyridine,

2-methoxypyridine, 3-methoxypyridine, 4-methoxypyridine, pyrazine, 2,3,5,6-tetramcthylpyrazine, diethyl ether, di-n-butyl ether, dibenzyl ether, tetrahydrofuran, tetrahydropyran, benzophenone, triphenylphosphine oxide, triphenyl phosphate or phosphines or phosphites of formula PR¾ where R is independently selected from methyl, ethyl, (C3-Ce)alkyl, substituted or unsubstituted (C3-C ? )cycloalkyl, (Ce-Ciojaiyl, (C6-Cio)aralkyl, methoxy, ethoxy, (C3-Ce)alkoxy, substituted or unsubstituted (C3-C?)cycloalkoxy, (C 6 -Cw)aryloxy or (O-C io)arylalkoxy. Representative examples of PRs include without any limitation trimethyl phosphine, tricthyl phosphine, tri-n-propyl phosphine, tri-iso-propyl phosphine, tri-n-butyl phosphine, tri-iso-butyl phosphine, tri-teit-butyl phosphine, tricyctopentylphosphine, triallylphosphine, tricyclohexylphosphine, triphenyl phosphine, trimethyl phosphite, triethyl phosphite, trifluoroethyl phosphite, tii-n-propyl phosphite, tri-iso-propyl phosphite, tri-n-butyl phosphite, tri-iso-butyl phosphite, tri-tert-butyl phosphite, tricyclopentylphosphite, triallylphosphite, tricyclohexylphosphite, triphenyl phosphite, and the like, it should however be noted that various other known LBs which will bring about foe intended activity can also be used in this embodiment of the invention.

Various olefinic monomers which undergo vinyl addition polymerization can be employed in the composition of this invention. Such olefinic monomers include without any limitation alfcyclic olefins, such as ethylene, propylene, butylene, styrene, and the like. Other olefinic monomers include cyclo-olefins and bkyclo-olefins, and soon.

In some embodiments of this invention the olefinic monomers which are suitable in the composition of this invention are of the formula (V): wherein: m is an integer 0, 1 or 2; is a single bond or a double bond;

Ri¾ Ri4, RIS and Ri6 are the same or different and each independently selected from the group consisting of hydrogen, halogen, a hydrocaifayl or halohydrocarbyl group selected from linear or branched alkyl and fluoroalkyl having the formula CqHxFy, where q is an integer from 1 to 20, x and y are integers from 0 to 2q+l , and the sum of x and y is 2q+l , (C3-Cu)cycloaIkyl, (C6-Ci2)bicycloalkyl, (C7-C u)tricycloalkyl, (OCio)aiyl, (C6-Cio)aryl(C 1 -Ce)alkyl, perfluoro(C6-Cio)aryl, perfluoro(Ce-Cio)Biyl(C 1 -Ce)alkyl, methoxy, ethoxy, linear or branched (C3-Ci6)alkoxy, perfluoro(C 1 -Ci2)alkoxy, (C3-Ci2)cycloalkoxy, (OCi2)bicycloeIkoxy, (C ? -Ci4)tricycloalkoxy, (Ce-Cio)aryloxy, (OCio)aiyl(C 1 -C6)alkoxy, perfluoro(C6-C io)aryloxy, pCTfluoro(C6-Cio)aryl(C 1 -C3)alkoxy 1 a group of Simula (A):

-Z-Aiyl (A); a group of Simula (Al): (Al); a groip of formula (A2): a group of Simula (A3): (A3); and a group of Simula (A4): (A4); wherein:

Z is selected from the group consisting of:

0, CO, C(0)0, OC(OX 0C(0)0, S, (CRnRieX 0(CRi7Rie)b, (CRirRisX), C(OXCRnRn)b, (CRi 7 Ri8)bC(OX C(0)0(CRi7Rie)b, (CRi 7 Ri«>C(OX), OC(OXCR, 7 Ris)b, (CRi7Ri8)bOC(OX (CRi 7 Ri«)bOC(0)0, (CRi 7 Rie)b0C(0)0(CRi7Rie)b, 0C(0)0(CRi7Rie)b, S(CRi7R»)b, (CRnRiiJbS, (SiRrcRisK 0(SiRi 7 Ri*)b, (SiRi 7 Rie)bO, where

Ri7 and Rig are the same or different and each independently selected from hydrogen, methyl, ethyl, linear or branched (C3-Cn)alkyl, substituted or unsubstituted (Ce-CuXuyl, methoxy, ethoxy, linear or branched (Ci-CeXdkyknqr, (C2-Ce)acyl, (C2-Ce)acyloxy, and substituted or unsubstituted (Ce-CwXuyloxy; and b is an integer from 0 to 12, inclusive;

Aryl is selected from the group consisting of substituted or unsubstituted phenyl, substituted or unsubstituted biphenyl and substituted or unsubstituted naphthyl, substituted or unsubstituted terphenyl, substituted or unsubstituted anthracenyl substituted or unsubstituted fluorenyl, wherein said substituents are selected from the group consisting of halogen, methyl, ethyl, linear or branched (C3-Ce)alkyl, perfluoro(C 1 -Ci2)alkyl, (C3-Ciz)cycloalkyl, (Ce-Cio)aryl, (Ce-Cio)aiyl(C 1 -C6)alkyl, perfluoro(C6-Cio)aryl, perflutHo(C6-C]o)aryl(C 1 -C6)alkyl, methoxy, ethoxy, linear or branched (C3-Cie)alkoxy, perfluaro(C 1 -Cu)aIkoxy, (C3-Cu)cycloelkoxy, (C6-Cio)aryioxy, (C«-Cio)aryl(C i -C6)alkoxy, perfluoro(Ce-Cio)aiyloxy and perflumx)(C6-Cio)aryKC 1 -C3)alkoxy; k is an integer from 1 to 12;

Raa, R24 and Ras are the same or different and each independently selected from the group consisting of hydrogen, methyl, ethyl, line» or branched (C3-Cu)alkyl, perfluoro(C 1 -Ci2)aIkyl, methoxy, ethoxy, line» or branched (C3-Ci2)alkoxy, (C3-Ci2>cycloalkyi, (Ce-Ci2)bicycloaIkyl, (C7-Ci4)tricycloalkyl, (C6-Cio)aryl, (Ce-Cio)aiyl(C 1 -C6)alkyl, perfluoro(C6-Cio)aryl and perfluoro(Ce-Cio)aiyl(C 1 -C6)atiyl; or

R23 andRat taken together with the intervening carbon atoms to which they are attached to form a substituted or unsubstituted (Cs-CiOcyclic, (Cs-Ci4)bicyclic or (Cs-Cu)tricyclic ring; and Aiylene is substituted or unsubstituted bivalent (Ce-Ci4)aryl; or one of Ri3 and Ru taken together with one of Rn and Ris and the carbon atoms to which they are attached to form a substituted or unsubstituted (Cs-Ci4)cyclic, (Cs-Cujbicyclic or (Cs-Ci4)tricyclic ring.

More specifically, the Aryl as defined herein is substituted or unsubstituted biphenyl of formula: substituted or unsubstituted naphthyl of formula; substituted or unsubstituted terphenyl of formula:

10 substituted or unsubstituted anthracenyl of formula: substituted or unsubstituted fluorenyl of formula: where R* in each occurrence is independently selected from methyl, ethyl, linear or branched (C3-Cu)alkyl or (Ce-Cio)aiyl;

The monomers of formula (V) as described herein are themselves known in the literature or can be prepared by any of the known methods in the art to make such or similar types of monomers.

In addition, the monomers as described herein readily undergo mass vinyl addition polymerization, i.e, in their neat form without use of any solvents by vinyl addition polymerization using transition metal procatalysts, such as for example, oganopalladium compounds as described heron. See for example, U. S. Patent Nos.7,442,800 B2; and 7,759,439 B2; pertinait portions of which are incorporated herein by reference. The tom “mass polymerization” as used herein shall have the generally accepted meaning in the art That is, a polymerization reaction that is generally carried out substantially in the absence of a solvent In some cases, however, a small proportion of solvent is present in the reaction medium. For example, such small amounts of solvent may be used to dissolve the organopalladium compound of formula (I), a photoacid generator or photosensitizer as described herein or convey the same to the reaction medium. Also, some solvent may be used to reduce the viscosity of the monomer. The amount of solvent that can be used in the reaction medium may be in the range of 0 to 5 weight percent based on the total weight of the monomers employed. Any of the suitable solvents that dissolves the organopalladium compound of formula (I), a photoacid generate or photosensitizer and/or monomers can be employed in this invention. Examples of such solvents include alkanes, cycloalkanes, aromatics, such as toluene, ester solvents such as ethyl acetate, THF, dichkxomethane, dichloroethane, and the like.

Advantageously, it has now been found that one or more of the monomers themselves can be used to dissolve the organopalladium compound of formula (I) or a photoacid generate or photosensitizer and thus avoiding the need for the use of solvents. In addition, one monomer can itself serve as a sol vent fix the other monomer and thus eliminating the need for an additional solvent. For example, if a first monomer of fbrmula (V) is a solid at room temperature, then a second monomer of formula (V), which is a liquid a! room temperature can be used as a solvent fix· the first monomer of formula (V) which is a solid or vice versa. Therefore, in such situations more than one monomer can be employed in the composition of this invention.

In some embodiments, the monomers of formula (V) employed in the composition of this invention may serve as high refractive index materials imparting high refractive index to the resulting polymeric film upon mass polymerization. In general, the monomers of fbrmula (V) which are suitable in this invention feature a refractive index of at least 1.5. In some embodiments the refractive index of the monomers of formula (V) is higher than 15. In some other embodiments the refractive index of the monomers of formula (V) is in the range from about 1.5 to 1.6. In yet some other embodiineifts the refractive index of the monomers of formula

(V) is higher than 1.55, higher than 1.6 or higher than 1.65. In some other embodiments it may even be higher than 1.7.

In some other embodiments, ft is generally contemplated that monomer of fbrmula (V) may also be used as a viscosity modifier. Accordingly, in general, such a monomer of fbrmula (V) is a liquid at room temperature and can be used in conjunction with another monomer of formula (V) which is a solid or a high viscosity liquid.

In a further embodiment of this invention the composition of this invention encompasses at least two different monomers of formula (V) and is in a clear liquid state having a viscosity below 100 centipoise. In general, the composition ofthis invention exhibits low viscosity, which can be below 100 centipoise. In some embodiments, the viscosity of the composition of this invention is less than 90 centipoise. In seme other embodiments the viscosity of the composition ofthis invention is in the range from about 10 to 100 centipoise. In yet some other embodiments the viscosity of the composition ofthis invention is lower than 80 cP, lower than 60 cP, lower than 40 cP, lower than 20 cP, . In some other embodiments it may even be lower than 20 cP.

When the composition of this invention contains two monomers, they can be present in any desirable amounts that would bring about the intended benefit, including either refractive index modification or viscosity modification or both or any other desirable property depending upon the intended final application. Accordingly, the molar ratio of first monomer of formula (V)tosecondmonomerofformula(V)canbefrom 0:l()0to l00:0. That is, only one monomer of formula (V) cm be employed in certain applications. In other words, my amount of these two monomers cm be employed, hi sane embodiments, the molar ratio of first monomer of formula (V):second monomer of formula (V) is in the range from 1:99 to 99:1; in sane other embodiments it is from 5:95 to 95:5; it is from 10:90 to 90:10; it is from 20:80 to 8020; it is from 30:70 to 70:30; h is from 60:40 to 40:60; and it is 50:50, and so on.

In general, the compositions in accordance with the present invention encompass the above described one or mot of monomer of formula (V), as it will be seen below, various composition embodiments are selected to provide properties to such embodiments that are appropriate and desirable for the use for which such embodiments are directed, thus such embodiments are tailorable to a variety of specific applications. Accordingly, in some embodiments the composition of this invention contains more than two distinct monomers of formula (V), such as for example three different monomers of formula (V) or four different monomers of formula (V).

For example, as already discussed above, proper combination of different monomers of formula (V) makes it posable to tailor a composition having the desirable refractive index, viscosity and optical transmission properties, among other properties. In addition, it may be desirable to include other polymeric or monomeric materials which are compatible to provide desirable optical properties depending upon the end use application. Accordingly, the compositions of tills invention can also include other high refractive polymeric materials which will bring about such intended benefit Examples of such polymers Include without any limitation, poly(a-methylstyre∞X polyvinyl-toluene), copolymers of a-methybtyrene and vinyl-toluene, and the like.

Advantageously, h has further been found that the compositions of this invention can also contain additional monomers different from the monomer of formula (V). In some embodiments, the composition according to this invention may further contain one or more monomers selected from momma- of formula (VI) or monoma of formula (VII).

The monoma of formula (VI) is: wherein:

0 is an intega from 0 to 2, inclusive;

D is S1R 29 R 30 R 31 or a group selected from:

-(CHaVO-SiRasRaoRsi ®;

-(ClfcVSiRasRaoRai (F); and -(SiRaRsOc-O-SiRaRaoRsi (G); wherein c is an intega from 1 to 10, inclusive, and where one or more ofCHz is optionally substituted with (C 1 -Cio)alkyl or (C 1 -Cio)perfluoroalkyl;

R26, R27 and R28 are the same or different and independently of each otha selected from hydrogen, halogen and hydrocarbyl, where hydrocarbyl is selected from methyl, ethyl, linear or branched (C3-C«)alkyl, (C3-Ci2)cycloalkyl, (C<s-Ci2)bicycloelkyl, (C?-Ci4)tricycloaIkyl, (Ce-Cio)aryl, (Ce-Cio>uyl(C 1 -C3)alkyl, (C 1 -Cujalkoxy, (C3-Ci2)cycloalkoxy, (OCi2)bicycloalkoxy, (C7-Ci4)tricycloalkoxy, (C 6 -Cio)aryloxy(C 1 -C3)alkyl or (Ce-Cio)aiylaxy; and

R29, Rso and R31 are each independently of one anotha methyl, ethyl, linear or branched (C3-C»)alkyl, substituted or unsubstituted (C«-Ci4)aryl, methoxy ethoxy, linea or branched (C3-C9)aIkoxy or substituted or unsubstituted (Ce-Ci4)aiyloxy.

In this aspect of the invention, it has now been found that monomers of formula (VI) provides fintiia advantages. Namely, the monomers of formula (VI) deposing upon the nature of the monoma may impart high or low refractive index to the composition, thus it can be tailored to meet the need. In addition, the monomers of formula (VI) generally improve the adhesion properties and thus can be used as “adhesion modifies.” Finally, the monomers of formula (VI) may exhibit low viscosity and good solubility for the procatalyst and/or activator, among various other advantages.

The monomer of formula (VII) is: m wherein:

Z \ is selected from the group consisting of substituted or unsubstituted (C 1 -Ci 2 )alkylene, -(CH2)dO(CH2)e-, -{CHzMSiRasRjiKOsiR^iMCHaV where d, e and fare independently integers from 0 to 6, inclusive, Ras, R», R«o and R*i are the same or different and independently of each other selected from methyl, ethyl, linear or branched (Ca-Ci2)alkyl, and an arylene selected from the following:

Ra¾ Ra¾ R 34 , R 35 , R 36 and R 37 are the same or different and independently of each other selected from hydrogen, halogen and hydrocarbyl, where hydrocarbyi is selected from methyl, ethyl, linear or branched (Ca-Cu)alkyi, (Ca-Ci2)cycloalkyl, (Ce-C ia)bicycloalkyl,

(C7-Ci4)tricycloalkyl, (Ce-Cio)aiyl, (C«-Cio)aryl(C 1 -C3)alkyl, (C 1 -Cu)alkoxy, (Ca-Ci2)cycloalkoxy, (Ce-Ci2)bicycloalkoxy, (C7-C i<)tricycloelkoxy, (C6-Cio)aiyk)xy(C 1 -C3)alkyl or(C6-Cio)aryloxy.

The monomers of formula (VII) are bifunctional monomers and may exhibit high refractive index eqiecially when Zi is an arylene group. Accordingly, it is contemplated that incorporation of monomers of formula (VII) into composition of this invention generally increases the refractive index of the composition and also increase crosslinkabilhy with other molecules. Thus, by incorporation of monomers of formula (VII) into the composition of this invention it may be possible to increase compatibility with other materials depending upon the intended application thereby enhancing the properties of the composition of the invention. In moth» aspect of this invention it is conceivable that the composition of this invention may contain only one monomer of formula (V) or formula (VI) or formula (VII). That is, any (Me of the monomers of formulae (V) to (VII) may be sufficient to form a composition of this invention. In some other embodiments the composition of this invention encompasses any two monomers of formulae (V) to (VII) and in any desirable proportions. In some other embodiments the composition of this invention encompasses any three monomers of formulae (V) to (VII) in any combinations thereof and in any desirable proportions. All such possible permutations and combinations of monomers of formulae (V) to (VII) are part of this invention.

Accordingly, any of the monomers within the scope of monomer of formula (V) can be employed in the composition of the inventkm. Representative examples of monomer of formula

(V) include the following without any limitations:

2-(bicyclo[22.1 ]hept-5-en-2-ylmethyl)naphthalene; l-<bicyclo[22.1 ]hcpt-5-en-2-yhnethyl)naphthalene;

2-{(3-methyIbicyclo[2.2.1 ]hept-5-en-2-yl)methyl)naphthalene;

2-<bicyclo[22.1 ]hept-5-en-2-ylmetfayl>7-methylnaphtbalene;

5-([ 1 , 1 ’-biphenyl]-3-yImethyl)bicycio[2.2.1 ]hept-2-ene;

5-((2'-metfiyl-[l,l '-biphenyl]-3-yl)metiiyl)bicyclo[2.2.1]hcpt-2-ene;

5-([l , 1 ’-biphenyl]-4-ylniethyI)bicyclo{2.2. l]hqjt-2-ene:

5-([l,r-bipbenyiJ-2-yhnethyl)bicyclop ^.lJbept-2-ene;

5-(2-([l , 1 ’-biphenyI]-4-yl)ediyl)bicyclo[2.2.1 ]hq)t-2-ene (NBEtPhPh);

5-(2-([l , 1 ’-biphenyl]-2-yI)cthyl)bicyclo[22.1 ]hept-2-enc;

5-(2-(4*-etiiyl-[l,l *-biphenyl]-4-yl)dhyl)bicyck>[2.2.1 ]hcpt-2-ene;

5-(3-([l,r-biphenyI]-4-yI)propyl)bicycl o {2.2.1]hept-2-«ie;

5-(2-([l, 1 ’-biphenyl]-4-yI)ethoxy)bicyclo[2.2.1 ]hcpt-2-ene;

5

5-(2-(2 , ,4’-dimcihyl-[ 1 , 1 ’-bii*cnyl]-4-yI)etboxy)bicyck)[22.1 ]hept-2-ene; bicyck)[2.2.1 ]hept-5-en-2-yl 2-([l , 1 ’-biphcnyl]-4-yl)acetale; bicyclo[22.1]hept-5-cn-2-ylmdbyl[l,r-biphenyl]-4-<arboxyl ate;

5-(2-([l , 1 ’-bipheayl]-4-yk>xy)ethyI)bicyclo(22.1 ]hept-2-ene;

5-(2-([l , 1 ’-biphenyl]-2-yk>xy)ediyl)bicyclo[2.2.1 lbept-2-ene (NBEtOPhPh);

[l,r-biphenyl]-4-yl 2-(bicyclo[22.1]hqit-5-€n-2-yi)acctate;

2-((4-(bicyclo[22.1 ]hept-5-en-2-yI)butoxy)methyl)naphthalcnc;

5-(4-([ 1, 1 ’-biphcnyl]-4-yI)butyl)bicyck)[2.2.1 ]hept-2-ene;

(9H-fluoren-9-yl)mdhyl (bkydo[22.1 ]hept-5-en-2-ybnetiiyi) carbonate;

(9R,10S,llR,12S)-9,10-dihydro-9,10-[2]bicyck)andiraceoe;

1 -(4-bicyclo[22.1]hq)t-5-en-2-ylmethyl)-3, 4-dimethyl- 1 H-pyrrole-2,5-dione l-{4-bicyclo[2.2.1 ]hept-5-en-2-yletfayl)-3,4-dimethyl-l H-pyrrok-2^-dioiic

(EiDMMINB);

1 -(4-bicyck>[22.1 ]hcpt-5-en-2-ylpropyl>3, 4-dimethyl- 1 H-pyirole-2,5-dione

(PrDMMINB);

1 -{4-bicyclo[22.1 ]hept-5-cn-2-yIbutyl)-3,4-dimcthyl-l H-pyrrole-2,5-dione

(BuDMMINB);

1 -(4-bicyclo[22.1 ]hept-5-en-2-ylpentyl)-3, 4-dimethyl- 1 H-pyrrolc-2,5-dionc

(PentytDMMINB);

1 -(4-bicyck>[22.1 ]hepl-5-en-2-ylhexyl)-3,4-dimethyl-l H-pyrrole-2^-dkxie

I -(4-bicyclo[22.1 ]hept-5-en-2-ykdiyI) 1 ,4-phcnylcne-3, 4-dimcthyl- 1 H-pynol&-2^- dione (EtPhDMMINB); l-(4-bicyck)[22.1]hept-5-en-2-ylmethyl>3-methyl-lH-pyrrol e-2^-dione

(MeMMINB);

1 -(4-bicyclo[22.1 ]hept-5-cn-2-ylmethyl)- 1 H-pyrrolc-2^-dk)ne (McMINB);

!-(4-bicyclo[2^.1)hept-5-en-2-ylctiiyl)-lH-pyrrolc-2,5-di oiic(EtMINB);

5

NBDHNMI; bicyclo[2.2. l]hcpt-5-cn-2-ylmethyl 4-methoxy-cinnamate (NBMcMeOCmn); bicyck>[2.2.1]hept-5-en-2-ylmdhyI cinnamate (NBMeCinn); bicyclo[22.1 ]hept-S-en-2-ylethyl 4-mcthoxy-cmnamate (NBEtMeOCmn);

7-(bicyck>[22.1 ]h^)t-5-en-2-ylmethoxy)-2H-chrwneo-2-onc (NBMcComn);

7-(2-(bicyclo[22.1]hept-5-tii-2-yI)ctiioxy)-2H-chromen-2- one (NBEtCoum);

5-(4-phenylbutyI)bicyck>p2.1 ]hept-2-ene; hept-2-cne;

5-(3-pbcnylpropyl)bicyclo[22.1 ]hept-2-enc;

5-phenethoxybicyclo[22.1]hept-2-ene;

5-((beozytoxy)m th l)bicyck>[22.1]hept-2-ene;

5-(phenoxymethyl)bicyclo[22.1]hept-2-ene;

5-phenethyIbtcyclo[2.2.1 ]hept-2-cne (PENB);

5-(benzyloxy)bicyclo{2J2. l]hcpt-2-cne;

5-hexylbicyclo[2.2. l]hept-2-ene (HexNB);

5-octylbicyck>[2.2. l]hept-2-ene (OctNB);

5-decyIbicyclo[2.2. l]hept-2-ene (DecNB);

5-dodccylbicyck)[2.2.1]hcpt-2-cnc (DoDecNB);

5-tetradecyIbicyck>[2.2.1 Jhcpt-2-cnc (TctraDecNB); tetracyclododeceae (TD);

2-phenyl-tetracyclododecene (PhTD);

2-benzyl-l,2,3,4,4a,5,8,8a-octahydro-l,4:5,8-dimethanonap hthalene; -phenethyl- 1 ,2,3,4,4a,5,8,8a-octahydro- 1 ,4: 5,8-dimethanonaphthalene (PETD);

2-butyl-l,2,3,4,4a,5,8,8a-octahydro-l,4:5,8-dimethanonaph thalene (ButylTD); 2-hexyl- 1 ,2,3,4,4a,5,8,8a-octahydro- 1 ,4:5,8-dimethanonaphthalene (HexylTD);

2-octyl- 1 ,2,3 ,4,4a,5,8,8a-octahydro- 1 ,4:5,8-dimethanonaphthalene (OctylTD);

2-decyl- 1 ,2,3,4,4a,5,8,8a-octahydro- 1 ,4:5,8-dimethanonaphthalene (DecylTD);

2-cyclohexyl-tetracyclododecene (CyclohexylTD);

2- cyck)hexylmediyl-lA3,4,4a^,8,8e-octahydro-l,4:5,8-dimedianom q*lhalene;

2- <yclohexylethyl-l ,2J,4,4a^,8,8a-octahydro-l ,4:5,8-dimethanonaphthalene; and

(1^3,4,4a,5,8,8a-octahydro-l,4:5,8-dimethanonai*dialcn-2- yl)mediyi acetate

(TDMcOAc).

Turning now to monomer of Simula (VI) to form the composition of tills invention it is contemplated that any monomer within the scope of monomer of formula (VI) can be employed. Exemplaiy monomers of such type include but not limited to those selected from the group consisting ofi

(bicyclop .2. l]hept-5-cn-2-ylmcthoxyXmcthyl)diphcnylsilanc (NBCHzOsiMeHti);

(bicyctop.2.1 ]hept-5-en 2 yhnethoxyXethyl)diphenylsilane;

(bicyck>[2.2.1 ]hept-5-<n-2-ylmethoxyXethylXmctiiylXphcnyl)silaiie;

(bicyclo[22.1 ]hept-5^-2-ylmethoxy)dimcthyl(phcnyl)silane; bicyclo[22.1 ]hept-5-cn-2-yltrimethoxysilane; bicyclo[2J. l]hept-5-en-2-yttriethoxysilane (TESNB, NBSiCOCaHsfo); bicyclo[2.2.1 ]lwpt-5-«n-2-yl(tErt-butoxy)dimcthoxysilanc;

(2-(bicyck)[22.1 ]hept-5-en-2-yI)etiy0trimcthoxysilanc;

(2-(bicyclo[22.1]hcpt-5-cn 2 yl)ediylXractbyl^Upheoylsilane; and l-(bicyclo[2.2. l]hept-5-cn-2-yl>l,l 3,33-pentamethyldisiloxane.

Turning now to monomer of formula (VII) to form the composition of this invention it is contemplated that any monomer within the scope of monomer of formula (VII) can be employed. Exemplary monomers of such type include but not limited to those selected from the group consisting o£ l,4-di(bicyclo[22.1 ]hept-5-en-2-yl)benzene;

4,4’-di(bicyclo[22.1 ]bept-5-en-2-yl)-l , 1 ’-biphenyl;

4,4”-di(bicyclo[22.1]hept-5-en-2-yl)-l,l , :4M”4crphenyl;

UKii(bicyclo[2.2.1]hept-5-en-2-yl)-l,l,3,3-tetramethykiis ik>xane, when x= l and l,5-di(bicyclo[2 J. l]hept-5-en-2-yl)-l , 1^^-hexamcthyltmiloxanc, when x=2;

1 ,4-di(bicyck>p.2.1 ]hept-5-en-2-yl)butane;

5,5’-{oxybis(ethane-2, 1 -diyl))bis(bicyclo[22.1 ]hept-2-ene);

5,5 ’-((propane-¾2-diylbis(oxy))bis(metliylene))bis(bicyclo[2 .2.1 ]hept-2-ene);

1 ,3-bis(noibomenyletiiyI)-l , 1 ,3,3,-tetramethyldisiloxane (BisNBEt-Disiloxane); and

1 ,5-bis(norbomenylethyl)- 1 , 1 ,3,3,5,5,-hexamethyltrisitoxane (BisNBEt-Trisitoxane).

In a fbrther embodiment, the composition of this invention encompasses one or more monomers of formula (V) and at least one monomer of formula (VI).

In another embodiment; the composition of this invention encompasses one or more monomers of formula (VI) and at least one monomer of formula (VII) and optionally one monomer of formula (V).

In yet a further embodiment, the composition of this invention encompasses at least one monomer of formula (V) and at least one monomer of formula (VI), and optionally one monomer of formula (VII).

In yet a further anbodiment, the composition of this invention encompasses one monomer of formula (VI), optionally one or more monomers of formula (V) or monomer of formula (VII).

In yet another embodiment, the composition of this invention may indude one or more monomers selected from the following: dicyclopentadiene (DCPD);

4,4a,4b^,8,8a,9,9a-octahydro-lH-l,4:5,8-dimcthanofluorenc (one of timers of cyclopentadiene, TCPD2);

1 -methoxy-dicyclopcntadiene;

1 -(n-butoxy)-dicyclopentadiene;

10

1 -(n-octyloxy)-dicyclopentadicnc;

3a,4,7,7a-tetrahydro-l H-4,7-methanoinden- 1 -yl acetate;

3a,4,7,7a-tetrahydro-lH-47-mcdianoinden-l-yl benzoate;

3a,4,7,7a-tetrahydro-l H-4,7→ncthanomden-l -yl 2-phenylacetate; and

3a,4,7,7a-tetrahydro-l H-4,7-methanoinden-l -yl 3-phenylpropanoate.

In a further embodiment of this invention, the composition contains any of the organopalladium compounds of formula (I) dial would bring about the mass polymerization as described haem. Generally, such suitable organopalladium compound of formula (I) contains a bidentate monoanionic ligand which is selected from the group consisting of:

,0 Several of the organopalladium compounds of formula (I) that are suitable to be employed in the compositions of this invmtion are known in the literature or can be readily made by any of the known procedures in tiie art. See for example, U. S. Patent Nos. 7,442,800 B2 and 7,759,439 B2, pertinent portions of which are incorporated herein by reference.

Exemplary organopalladium compounds of formula (I) or organopalladium compounds of formula (IA) that can be employed in foe composition of this invention without any limitation include foe following; palladium (acetylacetonateh tri-isopropylphosphine;

10 palladium (hexafluoroacetylacetonate)2 tri-isopropylphosphine (Pd(hfac)zPiPt3, Pd680); palladium (hexafluoroacetylacetonatefc tri-tert-butylphosphine (Pd(hfac)2p(tert-Bu)3, Pd722); palladium (hexafluoroacetylacetonate)2 tri-cyclohexylphosphine (Pd(hfec)2Pcy¾ Pd800); palladium (tetramethylheptenonoate): tri-cyclohexylphosphmc; palladium (trifluoroacetylacetonate)2 (Pd(tfacac)2) tri-isopropylphosphine;

5 palladium (pentafluax¾MOpi<myltifluoioaceteaiale)2 tri-cyclohexylphosphine; palladium (hexafluoroacetylacetonate)} triphenylphosphine (Pd(hfac) 2 PPh3, Pd782); palladium (hexafluoroacetylacetonatefc triethylphosphite; palladium (hcxafluoroacetylacet(Miatc)2 l l l-trifluorocthyli*osphitc; palladium (acdylacetonateh tri-isopropylphosphme (Pd(acac)2PiPh, Pd465); palladium (acetylacetonate)2 tri-cyclohexylphosphinc (Pd(acac)2Pcy3, Pd585); palladium (acetylacetonatefe triphenylphosphine (Pd(acac)2Pi¾3); and palladium (2^,6,6-ttirametfaylheptanc-3,5-dionatc)2 triphcnylphosphinc; palladium (hexafluoroacetylacetonate)21,1,1-trifluoroethylphosphite; and palladium (hcxafluoroacetylacetonatc)2 tridhylphosphite. As noted, the composition of this invention ftrther contains a photoadd generator which when combined with the organopalladium compound of formula (I) and a photosensitizer will cause mass polymerization of the monomers contained therein when exposed to suitable radiation as described herein. Any of the known photoacid generators can be used in the compositions of this invention, such as for example, certain of the hakmium salts.

In some embodiments the photoacid generator of the formula (TV.) are employed in the composition of this invention:

Wherein Aiyli aid Aiyh are the same or different and are independently selected from the group consisting of substituted or unsubstituted phenyl, biphenyl and naphthyl; Hal is iodine or bromine; and An© is a weakly coordinating anion (WCA) which is weakly coordinated to the cation complex. More specifically, the WCA anion functions as a stabilizing anion to the cation complex. The WCA anion is relatively inert in that it is non-oxidative, non-reducing and non- nucleophilic. In general, the WCA can be selected from borates, phosphates, arsenates, antimonates, aluminates, boratobenzenc anions, carbonate, halocarborane anions, sulfonamidate and sulfonates

Representative examples of the compounds of formula (IV.) may be listed as follows:

Wherein Rii and Rn are as defined herein. Similarly various sulfonium salts can be used as photoacid generators, which include broadly compounds of formula (III) as described herein.

Accordingly, non-limiting examples of suitable photoacid generators of formula (ED) that may be employed in the composition of this invention are listed below:

(4-thiophenyl)phmyl-dipheoylsulfomm hexafluorophosphate;

(2-(4-methoxynaphthalen- 1 -yl)-2-oxocthy l)dimediy lsulfimium teiralds(perfliiorophcnyl)borate, commercially available as TAG 382; tris(4^(4-ecetylphenyl)thk>)phenyl)sulfbnium tris((trifluormnethyl)sulfbnyl)mcthanide; bis-(triphenylsulfbnium) sulfide bis- hexafluorophosphate; triphcnylsulfonium chloride; tris(4-teit-butylpheiiyl)sulfbnium perfluoro- 1 -butanesulfbnate; tris(4-tert-butylphenyl)sulfbniimi triflate;

(4-phenoxyphenyl)diphenylsulfonium triflate; and tris(4-((4-acetylphenyl)thio)phenyl)sulfonium tetralds-pentafluorophenylboratc (Irgacure

PAG290).

Non-limiting examples of suitable photoacid generators of formula (IV) that may be employed in the composition of this invention are listed below: tolylcumyliodoniiHn-tetrakis pcntafluorophenylborate, commercially available under the tradename Bluesil PI 2074* from Elkem Silicones;

[4-(octyk>xy)phenyl]-phenylkxlaiium (hexafluoro)phosphate (OPPI PFe);

[4-(octyloxy)phcnyl]-pheiiyliodonium (hexafluoro)antimonate (OPPI SbFe);

(4<thylphenylX4-isopropyiphenyI)iodonium lebricis(perfluorophenyl)b<M , atc; di-(p-t-butyl { *cnyl)iodomum tris(trifluoromcthanesulfbnyl)methanide; bis(44et-butylphenyl)kxlonium pcrfluoro- 1 -butancsulfonalc; bis(4-tert-butylphenyI)iodonium p-toluenesulfonate; bis(44ati>utylphenyl)iodonium triflate; where R42 and R43 are the same or different and each independently selected fiom linear or branched (Cio-Ci3)alkyi, for example iodonium, diphenyl-, 4,4’-di-(Cio-Ci3)aJkyl derivatives, tetrakis(2,3,43,6-pentafluor<qAenyl)borates are commercially available under the tradename SILCOLEASE UV CATA 243; and diphcnyliodonium chloride.

Other exemplaiy PAGs that may be suitable in the composition of this invention include the following: triphenylsulfbnium 4 l 4,5^,6,6-hexafluoro-l^ > 2-dithiazinan-2-ide 1,1,33-tetraoxkie; tris(4-(tert-butyl)phenyl)sulfotiium 4,4,53,6,6-hexafluoro-133-dithiazinen-2-ide 1,133- tetraoxidc;

1 -(4-(tert-¼tyI)pheny0hexahydrothiopyrylium 4,4,5,5,6,6-hexafluoro- 1 ,3,2-dithiazinan-2-ide l,U,3-tctraoxide; 1 -(4-(tert4)utyl)pheayI)tetrahydro- 1 H-thiophen- 1 -ium 4,4,5,5,6,6-hexafluoro- 1 ,3,2- dhhiazinan-2-ide 1,1,3,3-tetraoxide; and

2,4,6-triisopropylbenzenesulfonyl azide.

However, any of the other known photoacid generators which can activate the organopalladium compounds of formula (I) as employed herein when exposed to suitable radiation can also be used in the composition of this invention. All such compounds are part of tills invention.

As noted, the composition of this invention additionally contains a photosensitizer compound which Anther facilitates the formation of the active catalyst when the composition is exposed to suitable radiation in the presence of the photoacid generator as employed herein. For this purpose, any suitable sensitizer compound can be employed in the compositions of the present invention, which activates the photoacid generator and/or the organopalladium compound of formula (I). Such suitable sensitizer compounds include, anthracenes, phenanthrenes, chrysenes, benzpyrenes, fluoranthenes, rubrenes, pyrenes, xanthones, indanthrenes, thioxanthen-9-ones, and mixtures thereof. In some exemplary embodiments, suitable sensitizer components include a compound of formula (Vni) or a compound of formula

(IX): herein

R44, Ris and Ru are the same or different and independently of each other selected from the group consisting of hydrogen, halogen, hydroxy, NQ¾ NH¾ methyl, ethyl, linear or branched (C3-Ci2)alkyl, (C3-Ci2)cycloaIkyl, (C6-Ci2)bicycloalkyl, (C7-C u)tricycloalky 1, (C6-Cio)aryl, (Ce-Cio)aryl(C 1 -C3)alkyl, (C 1 -Cujalkoxy, (C 3 -Ci2)cycloalkoxy, (Ci-Ci2)bicycloelkoxy, (C7-C lOtricycloalkoxy, (C6-Cm)aryloxy(Ci -C3)alkyl, (C6-Cio)aryloxy, C(OXC 1 -C6)alkyl, COOH, C(0)0(C 1 -C6)alkyl, aid S(fe(C*-Cio)aiyI;

R47 and R41 are the same or different and independently of each other selected from the group consisting of methyl, ethyl, linear or branched (C3-Ci2>alkyl, (C3-Ci2)cycloalkyl, (C6-Ci2)bicycloalkyl, (CT-C I 4)tricycloalkyl, (Ce-Cio)aiyl and (C6-Cio)aiyl(C 1 -C3)alkyl.

Representative examples of the compounds of formula (VIII) or the compounds of formula (IX) without any limitation may be listed as follows:

1 K*toro-4-mcthoxy-9H4hMxanthen-9-one;

1 -chloro-4-etboxy-9H-tfaioxanthen-9-one;

1 -cfal(XO-4-propoxy-9H-tiiioxanthen-9-(Hi€ (commercially sold under the name CPTX fiom

Lambson);

1 -chkxx>-2-pr(¾x)xy-9H-tiiioximtben-9-one;

1 -chloro-2-ethoxy-9H-thk)xantiicn-9-one;

1 -chloro-2-methoxy-9H-thk)xanthciH9-one;

1 -diloro-4-methy l-9H-tiiioxantheii-9-<Hie;

1 -chk>ro-4-etiiyl-9H-tiik)xmthen-9-one;

1 -chk)TO-4-phcnoxy-9H-tiiioxanthen-9-(mc;

2-chlorothk)xanthen-9-one (CTX);

2-isopropyl-9H-thk>xanthen-9-one (ΓΓΧ);

4-isopfOpyl-9H-thioxanthen-9-one;

10 9, 1 O-dimcthoxyanthracenc (DMA);

9, 10-dietfioxyanthracene (DBA) ; and

9,10-di-n-butaxyanforacene (DBA).

Other suitable photosensitizer compounds include various substituted and unsubstituted phenothiazine derivatives, such as for example: phenothiazine.

Generally, photosensitizers absorb energy from foe radiated light source and transfers that energy to foe desirable substrate/reactant, which in foe present invention is the photoacid generator employed in the composition of this invention. In some embodiments the compounds of formula (ΙΠ) or the compounds of formula (IV) can be activated at certain wavelength of the electromagnetic radiation which can generally range from about 240 nm to 410 nm. Accordingly, any of foe compounds which are active in this electromagnetic radiation can be employed in the compositions of this invention which are stable to various fabrications methods where the compositions of this invention can be used including for example OLED or the 3D fabrication methods. In sane embodiments foe wavelength of the radiation to activate the compounds of formulae (III) or (IV) is 260 nm. In some other embodiments the wavelength of the radiation to activate the compounds of formula (V) is 310 nm. In sane other embodiments the wavelength of the radiation to activate the compounds of formula (V) is 365 nm. In yet sane other embodiments the wavelength of the radiation to activate foe compounds of formula (V) is 395 nm.

Any amount of organopaUadium compound of formula (I), the photoadd generator of formulae (III) or (IV) and the photosensitizer of formulae (VIII) or (IX) can be employed in foe composition of this invention which will bring about the intended result Generally, foe molar ratio of monomer of formula (V):compound of formula (I) is in the range of 25,000: 1 to 5,000: 1 or lower. In some other embodiments such monomer of formula (V)xompound of formula (I) is 10,000:1, 15,000:1, 20,000:1 or higher than 30,000:1. It should be noted that monomer of formula (V) as mentioned herein may include one or more monomers of formula (V) distinct from each other and may additionally contain one or more monomers of formulae (VI) or (VII), and therefore, the above ratio represents combined molar amounts of all such monomers employed. Similarly, the molar ratio of organopalladium compound of formula (I).1he photoecid generator of formulae (DO) or (IV):fte photosensitizer of formulae (VIII) or (IX) is in foe range ofhliOJ to 1:2:2 or 1:2:1 or 1:4:1, 1:2:4, 1:1:2, 1:43 or such ranges which will bring about the intended benefit

Advantageously, it has further been found that foe composition according to ft is invention forms a substantially transparent film when exposed to a suitable actinic radiation (UV irradiation). That is to say that when foe composition of this invention is exposed to certain actinic radiation, foe monomers undergo mass polymerization to form films which are substantially transparent to visible light That is, most of the visible light is transmitted through the film. In some embodiments such film formed from the composition of this invention exhibits a transmission of equal to or higher than 90 percent of the visible light In sane other embodiments such film formed from foe composition of this invention exhibits a transmission of equal to or higher than 95 percent of foe visible light It should be further noted that any actinic radiation that is suitable to cany out this mass polymerization can be employed, such as for example, exposure to any actinic radiation in the wavelength of 200 nm to 400 nm. However, any radiation higher than 400 nm can also be employed. In some embodiments the wave length of the actinic radiation employed is 250 nm, 295 nm, 360 nm, 395 nm or higher than 400 nm.

In some other embodiments the composition of this invention undergoes mass polymerization when exposed to suitable actinic radiation and heat to form a substantially transparent film. In yet other embodiments foe composition of this invention undergoes mass polymerization when exposed to suitable UV irradiation at a temperature from 50 °C to 100 °C to form a substantially transparent film.

Accordingly, exemplary compositions of this invention without any limitation may be enumerated as follows:

5-phenethylbicyclo[2.2.1]hept-2-ene (PENBX palladium (hexafluoroacetylacetonate)2 tri-cyclohexylphosphine (PdSOOX tolylcumyliodonium-tetrakis pentafluorophenylborate (Bluesil PI 2074) and 2-isopropyl-9H-thioxanthen-9-one (FIX);

S-phenethylbicyclop.2. ljhcpt-2-ene (PENBX palladium (hexafluoroacetytacetonateb tri-isopropylphosphine (Pd680); tolylcumyliodonium-tetrakis pentafluorophenylborate (Bluesil PI 2074) and 2-isopropyl-9H-thioxanthen-9*one (TTX); 5-phenethylbicyck>[2.2.1 ]hept-2-ene (PENB), Pd(acac)2Pcy3 (Pd585); tolylcumyliodonium-tetrakis pentafluorophenylborate (Bluesil PI 2074) and 2- isopropyl-9H-thk)xanthen-9-one (ITX); and 5-decylbicyclo[2.2.1]hept-2-ene (DecNB), palladium (hexafhioroacetylacetonate)2 tri-cyclohexylphosphine (PdSOOX iodonium, diphenyl-, 4,4’-di-(Cio-Ci3)alkyl derivatives, tctrakis(2^,4,5,6-pentafluorophenyl)borates (SILCOLEASE UV CATA 243) and 2-isopropyl-9H-thiaxantheii-9-one (ITX).

In a further aspect of this invention there is provided a kit fix· faming a substantially transparent film. There is dispensed in this kit a composition of this invention. Accordingly, in some embodiments there is provided a kit in which there is dispensed one or more olefinic monomers; an organopalladium compound of formula (I) or an organopalladium compound of formula (IA) as described herein; a photoacid generator of formulae (ΠΙ) or (IV) as described herein and a photosensitizer of formulae (VIE) or (IX). In some embodiments the kit of this invention contains one or more monomers of formula (V) optionally in combination with one or more monomers of formulae (VI) or (VII) so as to obtain a desirable result and/or for intended purpose.

In some embodiments, the aforementioned kit encompasses one or more monomers of formula (V) and one or more monomers of formulae (VI) or (VII). In some other embodiments the kit of this invention encompasses at least two monomers wherein first monomer serves as a solvent for the second monomer. Any of the monomers of formulae (V) to (VII) as described herein can be used in this embodiment The molar ratio of such two monomers contained in these embodiments can vary and may range from 1:99 to 99:1, or 10:90 to 90: 10, 20:80 to 80:20, 30:70 to 70:30, 60:40 to 40:60 or 50:50, and so on. In some other embodiments the kit may encompass a composition wherein dispensed two monomers which could be one monomer of formula (V) and another monomer of formula (VI). Further, the monomer of formula (VI) is completely soluble in monomer of formula (V) to form a clear solution at room temperature. In some embodiments the monomer mixture may become a clear solution at slightly elevated temperature, such as for example, 30 °C or 40 °C or 50 °C, before they undergo mass polymerization. In another aspect of this embodiment of this invention the kit of this invention undergoes mass polymerization when exposed to suitable actinic radiation for a sufficient length of time to form a polymeric film. That is to say that the composition of this invention is poured onto a surface or onto a substrate which needs to be encapsulated and exposed to suitable radiation in order for the monomers to undergo polymerization to form a solid trmsparent polymer which could be in the form of a transparent film. Generally, as already noted above, such polymerization can take place at various wavelengths of actinic radiation, such as for example, at 265 nm 315 nm 365 nm or 395 nm and so on. The mass polymerization may further be accelerated by heating, which can also be to stages, fix· example heating to 40 0 C or 50 °C or 60 °C for 5 minutes each, and if necessary further heating to 70 °C for various lengths of time such as from 5 minutes to 15 minutes and so on. By practice of this invention h is now possible to obtain polymeric films on such substrates which are substantially transparent film. The “substantially transparent film” as used herein means that the films formed from tire composition of this invention are optically clear to the visible light Accordingly, in some embodiments of this invention such films are having at least 90 percent of visible light transmission, in some other embodiments the films formed from the composition of this invention exhibit at least 95 percent of visible light transmission.

In some embodiments of this invention the kit as described herein encompasses a composition which further contains one or more monomers selected from monomer of formula (ΙΠ) or monomer of formula (IV) as described hereinabove. Again, any of the monomers of formula (III) or (TV) as described hereto can be used to this embodiment, and in any desirable amounts dependmg on the nature of the intended use.

In some embodiments, the kit as described herein encompasses various exemplary compositions as described hereinabove.

In yet another aspect of this invention there is further provided a method of forming a substantially transparent film for the fabrication of a variety of optoelectronic device comprising: forming a homogeneous clear composition comprising one or more monomers of formula (V); an organopalladium compound of formula (I) or an organopalladium compound of formula (IA); a photoacid generator of formulae (III) or (IV); and a photosensitizer of formulae (VIII) or

(ix); coating a suitable substrate with the composition or pouring the composition onto a suitable substrate to form a film; and exposing the film to a suitable actinic radiation to cause polymerization of the monomers.

The coating of the desired substrate to form a film with the composition of this invention can be performed by any of the coating procedures as described herein and/or known to one skilled to the art, such as by spin coating. Other suitable coating methods include without any limitation spraying, doctor blading, meniscus coating, ink jet coating and slot coating. The mature can also be poured onto a substrate to form a film. Suitable substrate includes any appropriate substrate as is, or may be used fix- electrical, electronic or optoelectronic devices, fix- example, a semiconductor substrate, a ceramic substrate, a glass substrate.

Next, the coated substrate is bated, i A, heated to facilitate the mass polymerization, for example to a temperature from 50°C to 100°C fix· about 1 to 60 minutes, although other appropriate temperatures and times can be used. In some embodiments the substrate is bated at a temperature of from about 60°C to about 90°C fix 2 minutes to 10 minutes. In some other embodiments the substrate is bated at a temperature of from about 60°C to about 90°C fix 5 minutes to 20 minutes.

The films thus formed are then evaluated for their optical properties using any of the methods known in the at For example, the refractive index of the film across the visible spectrum can be measured by ellipsometry. The optical quality of the film can be determined by visual observation. Quantitatively foe percent transparency can be measured by visible spectroscopy. Generally, the films framed according to this invention exhibit excellent optical transparent properties and can be tailored to desirable refractive index as described herein.

Accordingly, in some of the embodiments of this invention there is also provided an optically transparent film obtained by the mass polymerization of the composition as described herein. In another embodiment there is also provided an optoelectronic device comprising the transparent film of this invention as described herein.

In yet some other embodiments the composition of this invention can also be used in a variety of photo induced nanoimprint lithography (NIL), such as for example, UV-NIL. Fix- instance, tiie compositions of this invention can be used in a variety of photocurable imprint technology. Typically in such applications, the composition of this invention is suitably placed <xi a substrate (fix example by coating or similar means), which is then covered by a suitable stamp and exposed to radiation so as to allow foe composition of this invention to cure to a solid. The stamp is then released to obtain the nano-imprinted film. Such substrates can include for example a master digital video disk (DVD).

In yet another aspect of this invention there is further provided a composition comprising: a) one or more monomers of formula (VA): wherein: m is an integer 0, 1 or 2; at least one of Ria, R14, Ris and Rie is O-Aiyl; and the remaining Ri¾ R14, Ris and Rie are the same or different and each independently selected from the group consisting of hydrogen, halogen, a hydrocarbyl or halohydrocarbyl group selected from methyl, ethyl, linear or branched (CyCieXdkyl, perfluoro(C 1 -Ci2)aIkyl, (C3-Ci2)cycloalkyl, (Ce-Ci2)bicycloalkyl, (CT-C i4>tricycloalkyl, (C6-Cm)aiyl, (Ce-Cio)aiyl(C 1 -C6)alkyl, perfluoro(C 6 -Cio)aiyl, perfluoro(C 6 -Cio)eiyl(C 1 -C 6 )alkyl, methoxy, ethoxy, linear or branched (Cs-Ciejalkoxy, perfluoro(C 1 -Ci2)alkoxy, (Ca-CuXycloalkoxy, (Ce-C 12)bicycloalkoxy, (C7-Cu)tricycloalkoxy, (C6-Cio)aiyloxy, (C6-Cm)aiyl(C 1 -C6)aIkoxy, pofluoro(C6-Cio)aiyloxy, perfluoro(C6-Cio)aryl(C 1 -C3)alkoxy, a group of formula (Al): a group of formula (A2):

(A2); a group of formula (A3): (A3); and a group of formula (A4): (A4); wherein: Aryl is selected from the group consisting of substituted or unsubstituted phenyl, substituted or unsubstituted biphenyl and substituted or unsubstituted naphthyl, substituted or unsubstituted terphenyl, substituted or unsubstituted anthracenyl substituted or unsubstituted fluorenyl, wherein said substituents are selected from the group consisting of halogen, methyl, ethyl, linear or branched (C3-Ce)alkyl, perfluoro(C 1 -Ci2)alkyl, (C3-Ci2)cycloaIkyl, (Ce-CioXuyl, (C6-Cio)aryl(C 1 -C6)alkyl, perfluoro(C6-Cio)aryl, perfluoro(C6-C io)aryl(C 1 -Cejalkyl, methoxy, ethoxy, linear or branched (C3-Cie)alkoxy, perfluoro(C 1 -Ci2)aIkoxy, (C3-Ci2)cycloalkoxy, (C6-Cio)aryloxy, (Ce-C io)aiy 1(C 1 -Ci)aDmxy, perfluoro(C6-C io)aiyloxy and pcrfluoro(C6-Cio)aiyl(C 1 -C3)alkoxy; k is an inl¾cr from 1 to 12;

R23, *24 and R25 are the same or different and each independently selected from the group consisting of hydrogen, methyl, ethyl, linear or branched (C3-Cn)alkyl, perfluoro(C 1 -Ci2)alkyl, methoxy, ethoxy, linear or branched (C3-Cu)alkaxy, (Cs-Ci2)cycloeIkyl, (Ce-Ci2)bicycloaIkyl, (C?-Ci4)tricycloelkyl, (C¾-Cio)aiyl, (C6-Cio)aryl(C 1 -C6)alkyl, perfluoro(C6-Cio)atyl and perfluoro(C6-Cio)aryl(C 1 -C6)alkyl; or

R23 and R24 taken together with the intervening carbon atoms to which they are attached to form a substituted or imsubstituted (Cs-Ci4)cyclic, (Cs-Ci4)bicyclic or (Cs-Ci4)tricyclic ring; and Aiylene is substituted or imsubstituted bivalent (C6-Ci4)aiyl; or one of Ri3 and Ru taken together with one of Ris and Rie and the carbon atoms to which they are attached to form a substituted or imsubstituted (Cs-Cujcyclic, (Cs-Ci4)bicyclic or (C5-Ci4)tricyclic ring; a) cme or more monomers of formula (VB): wherein: p is an integer 0, 1 or 2;

Rsi, R52, Rj3 and R54 are the same or different and each independently of one another is selected from hydrogen, linear or branched alkyl and fluoroalkyl having the formula CqH*F y , where q is an integer from 1 to 16, x and y are integers from 0 to 2qH , and the sum of x and y is 2q+l, hydroxy(C 1 -Ci6>¾l, (C3-Ci2)cycloelkyl, (C6-Ci2)bicycloaIkyl, (Cr-Ci4)tricycloalkyl, (Ce-CioXnyl, (OCio)aiyl(C 1 -C3)alkyl, perfluoro(C6-Cio)aiyl, perfluoro(Ce-Cio)aiyl(Ci<C 6 )alkyl, di(C 1 -C2)alkylmalcimide(C3-C6)alkyl, di(C l -C2)alky lmaleimide(C2-C 6 )alkoxy(C 1 -C2)all^l, hydroxy, (C 1 -Ci2)alkoxy,

(C3-C i2)cycloalkoxy, (C6-Ci2)bicycloalkoxy, (C?<li4)tricycloalkoxy, (Ce-Cio)aiylaxy(C 1 -C3)alkyl, (C5-Cio)heteroaiyloxy(C 1 -C3)alkyl, (C 6 -Cio)aryloxy, (C$-C l o)heteroary loxy or (C 1 -C 6 )acyk)xy; b) an organopalladium compound selected from the group consisting of a compound of formula (I) and a compound of formula (IA): wherein:

L is a ligand selected from the group consisting ofP Θ ¾ P(OR)¾ 0=P¾>¾ RCN and substituted or imsubstituted pyridines, where R is selected from the group consisting of linear or branched alkyl and fluoroalkyl having the formula CqHxFy, where q is an integer from 1 to 16, x and y are integers from 0 to 2q+l, and ihe sum of x and y is 2qfl, (C3-Cio)cyck>alkyl, (Ce-Cio)aiyl(C 1 -Ci6)alkyl and substituted or unsubstituted (Cr€io)aiyl; each A independently is a bidentate monoanionic ligand of formula (Π): wherein: n is an integer 0, 1 or 2;

X and Y are independently of each other selected from 0, N and S;

R 1 , R¾ R¾ Ra, Rs, Re and R? are the same or dif&rent and each independently selected from the group consisting of hydrogen, linear or branched alkyl and fluoroalkyl having the formula CqHxFy, where q is an integer from 1 to 16, x and y are integers from 0 to 2qH, and the sum of x and y is 2qH, (C3-C 1 o)cycloalkyl, (C*-Cio)aiyl(Ci<€i6)alkyl and substituted or unsubstituted (Ce-Cio)aryl; provided when either X or Y is 0 or S, R 1 and R5, reflectively, do not exist; d) a photoacid generator selected from the group consisting oft a compound of the formula (ΙΠ): (in); a compound of the formula (IV): wherein: a is an integer from 0 to 5;

An 0 is selected from the group consisting of C tetrakis(pentafhiorophenyl)borate, tetrakis(3,5-bis(trifluoromethyl)phenyl)borate, tetrakis(2- fluorophenyI)borate, tetrakis(3-fluoro|*enyl)borate» tetrakis(4-fluorophenyl)boiate, tetrakis(3>difluorophenyl)bMat¾ tetrakis(2,3A54etrafluorophenyl)borate, tetraltis(3, 4,5,6- tetrafluorophenyl)borate, tetrakis(3,4,5-trifluorophenyl)borate, metfiyhris(pcrfluorophcnyl)boratc, cthyhris(perfluorophcnyI)borate, phenyltris(perfluorophenyI)boratc, tetralds( 1 ,2^-trifluoroethylenyl)borate, tctrakis(4-tri-l- propylsUyhetrafo»n¾)henyl)borate l tetrakis(4-dimethyl-tert-butylsilyltetrafluorophenyI)boTate, (triphenylsitoxy)tris(pentafluorophenyl)borate, (octytoxy)tris(pentafluorophenyl)borate, tetrakis[3,5-bis[ 1 -methoxy-2^,2-trifluoro- 1 -(trifluoromethyl)ethyl]phenyI]borate, tetrakis[3- [1 -metix)xy-2^2-trifluoro- 1 -(trifhioromethyl)ethyl]-5-{trifluoromethyI)phenyl]borate, and tetrakis[3-[2^2-trifluoro-l -(2A2-trifluoroethoxy)- 1 -(trifluoromethyl)- ethyi]-5-

(trifluoromethyl)phenyl]borate, and

R¾ R¾ Rio, Rii and Ri2 are the same or different and each independently selected from the group consisting of halogen, methyl, ethyl, linear or branched (C3-C»)alkyl,

(C3-C i2)cycloaIkyl, (C6-Ci2)bicycloalkyi, (C C )tricycloalkyl, (Ce-Cio)aiyl, ((¼-Cio)aiyl(C 1 -C3)alkyl, (C 1 -Cu)alkoxy, (C3-Ci2)cycloalkoxy, (C«-Ci2)bicycloaIkoxy, (C?-Ci4)tricycloalkoxy, (Ce-Cio)aryloxy(C 1 -C3)aIkyl, (OCio)aiyloxy, (OCiojthioaryl, (C 1 -C6)alkanoyl(C6-Cio)thioa>d, (C 1 -C«)alkoxy(C6-Cio)aroyl(C 1 -C6)alkyl and (C<s-Cio)thioaryl-(C6-Cio)diaiylsulfbnium salt; and e) a photosensitizer.

Suiprisingly, in this aspect of the invention it has now been found that by judicious selection of monomers of formulae (VA) and (VB), organopalladium compounds of formulae (I) or (IAX photoacid generators as described heron and the photosensitizers it now possible to form compositions in accordance with this aspect of the invention which feature unique properties. Accordingly, in some embodiments of this aspect of the invention the compositions thus formed exhibit longer storage stabilities, which can extend up to four months at ambient temperatures or temperatures up to 40 °C. The compositions of this aspect of the invention are more readily ink jettable as well as spreadable on suitable substrates using any of the known procedures including ink jetting, among other coating methods.

In some embodiments the composition in accordance with this aspect of foe invention include monomers of formulae (VA) which include foe following without any limitations;

5-(2-([l , 1 ’-biphenyl]-4-yk)xy)ediyl)bicyclop.2.1 ]hept-2-ene;

5-(2-([l,r-biphenyl]-2-yloxy)ethyI)bicyclo|Z2.1]hept-2-en e (NBEtOPhPh);

[l,l’-biphenyl]-4-yl 2-(bicyclo[22. l]hept-5-en-2-yl)acctatc;

5-(2-ph«K)xyethyl)bicyclo(22.1 ]hept-2-ene; and

5-{phenoxymethyl)bicyck>[2.2.1]hept-2-ene.

The following examples are detailed descriptions of methods of preparation and use of certain compounds/monomers, polymers and compositions of the present invention. The detailed preparations fall within the scope of, and serve to exemplify, the more generally described methods of preparation set forth above. The examples are presented for illustrative purposes only, and are not intended as a restriction on the scope of the invention. As used in the examples and throughout the specification the ratio of monomer to catalyst is based on a mole to mole basis.

Examples

The following abbreviations have beat used hereinbefore and hereafter in describing some of the compounds, instruments and/m methods employed to illustrate certain of the embodiments of tills invention;

NBEtOPhPh - 5-(2-([l , 1 ’-triphenyl]-2-yloxy)ethyl)bicyclo[2.2.1 ]hept-2-ene; PENB - 5- phenethylbicyclo[22.1]hept-2-aie; DecNB - 5-decylbicyclo[2.2.1]hept-2-ene; HexNB-5- hexylbicyclo[22.1 ]hept-2-ene; TD - tctracyclododecene; DCPD - dicyclopentadiene; Pd304 - palladium acctylacetonatc; Pd520 - palladium hexafluoroacetylacetonate; Pd465 - palladium (acetylacetonate)] tri-isopropylphosphine; Pd585 - Pd(acac)2Pcy3; Pd680 - palladium (hexafluoroacetylacetonate)! tri-isopropylphosphine; Pd722 - palladium (hexafluoroacetylacetonate)! tri-tert-butylphosphine; Pd782 - palladium (hexafluoroacetylacetonate)! triphenylphosphine; Pd800 - palladium

(hexafluoroacetylacetonate)! tri-cydohexylphosphine; Bluesil PI 2074 - tolylcumyliodonhim- tetralds pentafluorophenylborate; SILCOLEASE UV CATA 243 - 4,4’-di-(Cio-Ci 3 )alkyl derivatives, tctrakis(2^,4,5,6-pcntafIuorophcnyl)borates; ΓΓΧ - 4-isopropylthioxanthone; GPC - gel permeation chromatography; M w - weight average molecular weight; PDI - polydispersity index; cP - centipoise; DSC - differential scanning calorimetry; TGA - thermogravimetric analysis.

Various monomers as used hereto are either commercially available or can be readily prepared following the procedures as described to the co-pending U. S. Patent No.9,944,818.

Various organopalladrum compounds of formula (I) or (IA) are known in the literature and can be readily prepared following the procedures as described in the literature. Examples A - F illustrate preparation of a few of the organopalladium compounds of formulae (I) or (IA) as described herein.

Example A Synthesis of Pd680

To an orange solution of palladium hexafhiofoacetylacetonate (025 & 0.48 mmol) dissolved in toluene (1 mL) was added a solution of tri-isopropylphospme (0.079 g, 0.49 mmol) dissolved in toluene (6 mL). The mixture was stirred for 2 h at ambient temperature. Tie solvent was removed under vacuo. To the residue was added cold hexane to obtain a solid. The solid was collected by filtration, washed with cold hexane and dried in vacuo to produce an orange solid. Yield 024g. *H NMR (CDClj, 500 MHz): 81.42 (m, 18H), 229 (br, 3H), 5.99 (s, 2H); 31 P NMR (CDCb, 202 MHz): 856.63.

Example B Synthesis of Pd800

To an orange solution of Palladium hexafluoroacetylacetonate (025 g, 0.48 mmol) dissolved to toluene (5 mL) was added a solution of tri-cyclohexylphosphine (0.137 g, 0.49 mmol) dissolved in toluene (3 mL). The mixture was stirred for 2 hat ambient temperature. The solvent was removed under vacuo. To the residue was added cold pentane to obtain a solid. The solid was collected by filtration, washed with cold pentane and dried in vacuo to produce an orange solid. Yield 0.16g. ‘H NMR (CDCb, 500 MHz): 8 1.19-133(m, 12H), 1.66-226 (m, 21H), 5.95 (s, 2H); 31 P NMR (CDCb, 202 MHz): 84520.

Example C Synthesis of Pd465

Tri-isopropylphosphtoe (0.16 g, 1 mmol) and palladium acetylacetonate (0.3 g, 1 mmol) were dissolved in toluene (5 mL) and stirred for 2 hours at room temperature under nitrogen. The orange solution was concentrated and recrystallized from petroleum ether to obtain pale yellowish crystal. The final product (Pd465) was dried in vacuum at room temperature. Yield: 65%. *H NMR (CD2CI2, 500 MHz): 65.41 (s, 1H), 3.45 (s, 1H), 2.62-2.63 (m, 3H), 2.29 (s, 6H), 2.00 (s, 3H), 1.91 (s, 3H), 1.2- 1.4 (m, 18H).

Example D

Synthesis of Pd585

To a yellow suspension of palladium acetylacetonate (025 g, 0.82 mmol) dissolved in toluene (5 mL) was added a solution of tri-cyclohexylphosphine (0235 g, 0.84 mmol) dissolved in toluene (3 mL). The mixture was stirred for 2 h at ambient temperature. The solvent was removed under vacuo. To the residue was added cold hexane to obtain a solid. The solid was collected by filtration, washed with cold hexane and dried in vacuo to produce an orange solid. Yield 0 J2 g. *H NMR (CDCb, 500 MHz): 6125(s, 12H), 139-2.0 (m, 27H), 227 (s, 6H), 334 (s, 1H), 532 (s, 1H).

Example E Synthesis of Pd782

Triphenyl phosphine (0.26 g, 1 mmol) and palladium hexafluoroacetylacetonate (0.52 g, 1 mmol) were dissolved in toluene (5 mL) and stirred for 2 hours at room temperature under nitrogen. The orange solution was concentrated and recrystallized from pentane to obtain orange crystals. The final product (Pd782) was dried in vacuum at room temperature. Yield: 70%. ‘H NMR (CD2CI2, 500 MHz): 56.3-6.S (m, 15H), 5.36 (s, 2H); l9 F NMR (CD2CI2, 470 MHz): δ (s, -73.6).

Example F Synthesis of Pd722

To an orange solution of palladium hexafluoroacetylacetonate (0.2 g, 0J8 mmol) dissolved in toluene (3 mL) was added a solution of tri-tert-butylphosphine (0.082 g, 0.4 mmol) dissolved in toluene (1 mL). The mixture was stirred fix 1 2 hat ambient temperature. The solvent was removed under vacuo. To tile residue was added cold hexane to obtain a solid. The solid was collected by filtration, washed with cold hexane and dried in vacuo to produce an orange solid (Pd722). Yield: 34%. Ή NMR (CD2CI2, 500 MHz): δ 1.62 (d, 9H), 6.07 (s, 2H); 31 P NMR (CDzCh, 202 MHz): 673.85.

The following Examples 1-5 demonstrate that the composition of this invention is quite stable at room temperature for at least up to two months and can very readily be mass polymerized when exposed to UV radiation. Examples 2-5 further illustrate that the mass polymerization occurs when exposed to radiation only in the presence of organopalladium compound of formula (I) or(IA), a photoacid generator of formula (III) and a photosensitize· of formula (V).

Example 1

Mass Polymerization ofPENB witii Pd800 In a glass bottle, Pd800(l molar part), Bluesil PI 2074 (2 molar parts), ΓΓΧ (1 molar part) were dissolved in PENB (5000 molar parts) under sonication to form a clear solution. This solution was then UV light exposed for 4 sec (4J/cm 2 , 395nm) at room temperature. The solution turned to a hard solid in 5 minutes indicating the monomer was polymerized, as confirmed by TGA and UV-DSC. The residue percentage of solids from isothermal TGA (Ih at 100 ® C) after UV exposure was >99 %. Based on dynamic TGA (20 °C/min), Tds (5% wt. loss) was 363 °C and the amount remaining at 300 °C was ~ 98%. The unexposed solution was free flowing even after 4 months at room temperature.

Examples 2 - 5

The procedures of Example 1 were substantially followed in these Examples 2-5 except that Example 3 contained no photosensitizer; Example 4 contained no photoacid generator, and Example 5 contained no organopalladium compound, as summarized in Table 1. All of the compositions were prepared in a glass bottle, and UV light exposed for 4 sec (4J/cm 2 , 395nm) at room temperature. It is quite evident from the results presented in Table 1 , only the composition ofExample 2 turned to a hard solid in a minute indicating the monomers were polymerized. This clearly demonstrates that it is necessary to employ all three components of the composition of this invention in order to bring about the mass polymerization of the olefinic monomers of this invention.

Table ! Example s Pot Life study

In a glass bottle, Pd800(l molar part), Bluesil PI 2074 (2 molar parts), ITX (1 molar part) were dissolved in monomer PENB (5000 molar parts) under sonication to form a clear solution. The solution was then taken in parts in several bottles and stored at room temperature. The viscosity of the solution was measured on different days and the solution was also exposed to UV irradiation (4J/cm 2 , 395nm) at room temperature to check the reactivity. The results are summarized in Table 2. It is evident from this data that the viscosity of the solution remained constant at 8 cP even after 120 days. After UV exposure, the solution turned into a hard solid indicating that the monomers were active during tins period and readily polymerized with no change in enthalpic value, i.e., heat of polymerization, as measured by UV DSC (4J/cm 2 , 400 run, 30 °C). The TGA isothermal analysis of these solids after UV exposure (lh at 100 °C) showed residues >98%. These measurements clearly show the long shelf life stability of the composition of this invention which is generally longer than four months at ambient storage conditions.

Table 2

Example 7

Mass Polymerization ofPENB with Pd680 In a glass bottle, Pd680 (1 molar part), Bluesil PI 2074 (2 molar parts), ΓΓΧ (1 molar part) were dissolved in PENB (5000 molar parts) under sonication to form a clear solution. The solution was then UV light exposed for 4 sec (4J/CH1 2 , 395nm) at room temperature. The solution turned to a hard solid in 5 minutes indicating the monomer was polymerized, as confirmed by TGA and UV-DSC. The residue percentage of solids from isothermal TGA (lh at 100 °C) after UV exposure was > 99%. Based on dynamic TGA (20 °C/min), Tas (5% wt loss) was 378 °C, the amount remaining at 300 °C was ~ 98%.

The unexposed solution was free flowing even after 4 months at room temperature and the measured viscosity of the compositions respectively at 0, 14, 28, 70 and 120 days remained same at 8 cP as in Example 6. The compositions stored at each of these intervals were also tested their reactivity by UV-DSC, and the measured heat of polymerization was again same during this time intervals at around 360-380 J/g and the composition turned solid within minutes upon UV exposure.

Example s

Mass Polymerization ofPENB with Pd585 In a glass bottle, Pd 585(1 molar part), Bluesil PI 2074 (2 molar parts), ITX (1 molar part) were dissolved in monomer PENB (5000 molar parts) under sonication to form a clear solution. The solution was then UV light exposed for 4 sec (4J/cm 2 , 395nm) at room temperature. The solution turned to a hard solid in 5 minutes indicating the monomer was polymerized, as confirmed by TGA and UV-DSC. The residue percentage of solids from isothermal TGA (lh at 100 e C) after UV exposure was > 98%. Based on dynamic TGA (20 e C/min), T<n (5% wt. loss) was 370 e C, the amount remaining at 300 e C was ~ 97%. The unexposed solution was free flowing even after one month at room temperature.

Example 9

In a glass bottle, Pd680 (1 molar part), Bluesil PI 2074 (2 molar parts), ITX (2 molar part) were dissolved in PENB (5000 molar part) to form a clear solution. The solution was then exposed to UV irradiation for 4s (4J/cm2, 395 nm) at room temperature. The solution gelled immediately after UV exposure and became a hard solid in a minute indicating a fast polymerization.

Example 10

In glass bottle A, Pd680 (1 molar part), ΓΓΧ (1 molar part) were dissolved in PENB (2500 molar part) to form a clear solution. In another glass bottle B, Bluesil PI 2074 (2 molar part), ΓΓΧ (1 molar part) were dissolved in PENB (2500 molar part) to form a clear solution. Both bottles were exposed to UV irradiation for 4s (4J/cm2, 395 nm) at room temperature. The solutions were then mixed together. After mixing, it slowly increased viscosity and gelled within 30 minutes.

Example 11

The procedures of Example 10 were substantially repeated in this Example 11, except that the glass bottle A was not exposed to UV irradiation as follows. In glass bottle A, Pd680 (1 molar part), ITX (1 molar part) were dissolved in PENB (2500 molar part) to form a clear solution. In glass bottle B, Bluesil PI 2074 (2 molar part) and ΓΓΧ (1 molar part) were dissolved in PENB (2500 molar part) to form a clear solution. Only bottle B was exposed to UV irradiation for 4s (4J/cm2, 395 nm) at room temperature. The solutions of both glass bottles A and B were then mixed together. After mixing, it remained as free liquid fin several minutes (more than 30 minutes). The solution was stored overnight during which time it became a solid, indicating a slow reaction.

Example 12

In glass bottle, Pd800 ( 1 molar part), UV CATA 243 (2 molar parts), ΓΓΧ ( 1 molar part) were dissolved in DecNB (5000 molar part) to form a clear solution. The solution was then exposed to UV irradiation fix- 4s (4J/cm2, 395 nm) at room temperature. The solution gelled immediately after UV exposure and became a hard solid within minutes indicating polymerization.

Example 13

Stability/reactivity of DecNB/NBEtOPhPh/Pd680 Composition In a brown glass bottle, ITX (2 molar parts) and Pd680 (1 molar part) were dissolved in DecNB (9,000 molar parts) via sonication at 40 °C for 1 hour to form a clear solution. In a separate brown glass bottle, Bluesil PI 2074 (2 molar part) was dissolved in NBEtOPhPh (1,000 molar parts) via sonication at 40 e C for 1 hour to form a clear solution. Both solutions were mixed together thoroughly to form a clear solution, which was then stored at 40 °C for several days. The viscosity (at 25 °C) and the reactivity of this composition were monitored at regular intervals and the results are summarized in Table 3. The reactivity was measured by UV-DSC as heat of polymerization and by UV light exposure (250 mW/cm 2 ) at 400nm for 4 secs, in each interval the composition became solid within minutes upon UV exposure.

Table 3

Example 13 Day 0 Day 6 Day 10 Day 28

Enthalpy 387 J/g 376 J/g 337 J/g 356 J/g

Viscosity 9.75 cP 9.8 cP 9.93 cP 9.9 cP

Example 14

Stability/reactivity of DecNB/NBEtOPhPh/PdSOO Composition The procedures of Example 13 were substantially repeated in this Example 14 except that Pd800 was used as a catalyst The results are summarized in Table 4.

Table 4

Example 14 Day 0 Day 6 Day 10 Day 28

Enthalpy 370 J/g 350 J/g 325 J/g 359 J/g

Viscosity 9.9 cP 9.9 cP 9.7 cP 10.1 cP Examples 15 - 18

Mass Polymerization of PENB with Various Organopalladium Compounds (Pd465, Pd585, Pd782, Pd722)

In three separate glass bottles, Pd465, Pd585, and Pd782 (1 molar part) were each mixed with Bluesil PI 2074 (2 molar parts), ITX (1 molar part), and dissolved in PENB (5000 molar parts) under sonication to form a clear solution. Each of these solutions were then UV light exposed separately for 4 sec (4J/cm 2 , 395 nm) at room temperature. In Example 18, in a glass bottle, Pd722 (1 molar part), UV CATA 243 (4 molar parts), ΓΓΧ (2 molar parts) were dissolved in PENB (5000 molar parts) under sonication to form a clear solution. This solution was then UV light exposed for 4 sec (lJ/cm 2 , 395nm) at room temperature. In each of these Examples 15 to 18, TGA was run at least 1 hour after UV exposure. The residue percentage of solids from isothermal TGA (lh at 100 °C) for all compositions were >98%. The UV-DSC (4J/cm 2 , 400 nm, 30 °C) studies showed that all of the compositions exhibited an exothermic peak after UV exposure for 4 secs. The results are summarized in Table 5.

Table 5.

Example No. Catalyst Enthalpy Residue change in 5 (TGA, lh, 100"Q

15 Pd465 330 99%

16 Pd585 200 98%

17 Pd782 370 99%

18 Pd722 340 98%

Examples 19 -24

Mass Polymerization of PENB with UV CATA 243 and Pd680 In each of Examples 19 - 24, in a separate glass bottle, Pd680 (1 molar part), UV CATA 243 and ITX (various molar parts as summarized in Table 6) were dissolved in PENB (10000 molar parts) under sonication to form a clear solution. Each of these compositions was then UV light exposed for 4 sec (lJ/cm 2 , 395nm) at room temperature. The solution turned to a hard solid in 5 minutes in each case indicating the monomer was polymerized, as also confirmed by TGA which was run at least 1 hour after UV exposure. The residue percentage of solids from isothermal TGA (lh at 100 *C) after UV exposure was > 98%. The UV-DSC was used to check the reactivity under UV irradiation (lJ/cm 2 , 400 nm, 30°C) in five minutes, and the results are summarized in Table 6. Table 6

Example 25

In glass bottle, Pd680 (1 molar part), UV CATA 243 (2 molar parts), ΓΓΧ (1 molar part) were dissolved in HexNB (5000 molar parts) to form a clear solution. The solution was then exposed to UV irradiation for 4 secs (4J/cm 2 , 395 nm) at room temperature. The solution gelled immediately after UV exposure and became a hard solid within minutes indicating polymerization.

Example 26

In glass bottle, Pd680(l molar part), UV CATA243 (3 molar partsX ITX(1J molar part) were dissolved in TD (2500 molar parts) to form a clear solution. The solution was then exposed to UV irradiation for 4 secs (4J/cm 2 , 395 nm) at roan temperature. The solution gelled within a min after UV exposure and became a hard solid within minutes indicating polymerization.

Example 27

Mass Polymerization of DCPD with UV CATA 243 and Pd-680 In a glass bottle, Pd-680(1 molar part), UV CATA 243 (4 molar parts), ITX (2 molar parts) were dissolved in DCPD (10000 molar parts) under sonication to form a clear solution. This solution was then UV light exposed for 4 sec (4J/cm 2 , 395nm) at 80 ® C. The solution turned to a hard solid in a few minutes indicating the monomer was polymerized. After 1 hours later, the solid was sent out for TGA isothermal test The residue percentage of solids from isothermal TGA (lh at 100 e C) after UV exposure was -92 %.

Comparative Examples 1-2

The following Comparative Examples 1-2 clearly demonstrate that the shelf life stability of the compositions of this invention are surprisingly much superior to those of other organopalladium compounds. In a glass bottle, organopalladium compound (Pd catalyst, 1 molar part), Bluesil PI 2074 (2 molar parts), ITX (1 molar part) were dissolved in PENS (5000 molar parts) under sonication to form a clear solution. The solution was then stored at room temperature and the gelling time was recorded to compare the shelf life. The results are summarized in Table 7. It is evident that the shelf life of the compositions of this invention are dramatically enhanced by imparting the Pcy3 ligands into the starting otganopalladium compounds.

Table 7

Although the invention has been illustrated by certain of the preceding examples, it is not to be construed as being limited thereby; but rather, the invention encompasses the generic area as hereinbefore disclosed. Various modifications and embodiments can be made without departing from the spirit and scope thereof.