触媒、及び反応方法

Japanese Patent JP5299974

B2

Disclosed is a technology for enabling an efficient asymmetric Michael addition reaction which does not require a large amount of a malonic ester, while having a short reaction time. Specifically disclosed is a catalyst which is composed of MX 2 (wherein M is Be, Mg, Ca, Sr, Ba or Ra and X is an arbitrary group) and a compound represented by general formula [I]. [In the formula, R 7 , R 8 , R 9 and R 10 each represents a substituted cyclic group or an unsubstituted cyclic group.]

JPH0627096	INDUSTRIAL APPLICABILITY: A method for hydrocarboxylating an acetylene-based unsaturated compound.
WO/2011/143975	METHOD FOR SYNTHESIZING POLYMETHOXY DIMETHYL ETHERS BY IONIC LIQUID CATALYSIS
JP6061399	Carboxylic acid by hydrolysis of ester, and a manufacturing method of alcohol

Osamu Kobayashi
Agostigno Magno
Schneider Uwe
Yamaguchi Miyuki

JP2009551529A

September 25, 2013

January 28, 2009

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Japan Science and Technology Agency

B01J31/02; C07C67/347; C07C69/738; C07C201/12; C07C205/56; C07B53/00; C07B61/00

JP2001253844A	2001-09-18
JP2004269481A	2004-09-30
JP2001253844A	2001-09-18
JP2004269481A	2004-09-30

JPN6013012624; Ｄａｖｉｄ　Ａ．　ＥＶＡＮＳ　ｅｔ　ａｌ．: 'Ｃｈｉｒａｌ　Ｍａｇｎｅｓｉｕｍ　Ｂｉｓ（ｓｕｌｆｏｎａｍｉｄｅ）　Ｃｏｍｐｌｅｘｅｓ　ａｓ　Ｃａｔａｌｙｓｔｓ　ｆｏｒ　ｔｈｅ　Ｍｅｒｇｅｄ　Ｅｎｏｌｉｚａｔｉｏｎ　ａｎｄ　Ｅｎａｎｔｉｏｓｅｌｅｃ' Ｊ．　Ａｍ．　Ｃｈｅｍ．　Ｓｏｃ． Ｖｏｌ．１１９，　Ｎｏ．２７, 19970709, ｐ．６４５２-６４５３
JPN6013012625; Ｈｉｒｏａｋｉ　ＳＡＳＡＩ　ｅｔ　ａｌ．: 'Ｔｈｅ　Ｆｉｒｓｔ　Ｈｅｔｅｒｏｂｉｍｅｔａｌｌｉｃ　Ｍｕｌｔｉｆｕｎｃｔｉｏｎａｌ　Ａｓｙｍｍｅｔｒｉｃ　Ｃａｔａｌｙｓｔ' Ｊ．　Ａｍ．　Ｃｈｅｍ．　Ｓｏｃ． Ｖｏｌ．１１７，　Ｎｏ．２３, 1995, ｐ．６１９４-６１９８
JPN6013012624; Ｄａｖｉｄ　Ａ．　ＥＶＡＮＳ　ｅｔ　ａｌ．: 'Ｃｈｉｒａｌ　Ｍａｇｎｅｓｉｕｍ　Ｂｉｓ（ｓｕｌｆｏｎａｍｉｄｅ）　Ｃｏｍｐｌｅｘｅｓ　ａｓ　Ｃａｔａｌｙｓｔｓ　ｆｏｒ　ｔｈｅ　Ｍｅｒｇｅｄ　Ｅｎｏｌｉｚａｔｉｏｎ　ａｎｄ　Ｅｎａｎｔｉｏｓｅｌｅｃ' Ｊ．　Ａｍ．　Ｃｈｅｍ．　Ｓｏｃ． Ｖｏｌ．１１９，　Ｎｏ．２７, 19970709, ｐ．６４５２-６４５３
JPN6013012625; Ｈｉｒｏａｋｉ　ＳＡＳＡＩ　ｅｔ　ａｌ．: 'Ｔｈｅ　Ｆｉｒｓｔ　Ｈｅｔｅｒｏｂｉｍｅｔａｌｌｉｃ　Ｍｕｌｔｉｆｕｎｃｔｉｏｎａｌ　Ａｓｙｍｍｅｔｒｉｃ　Ｃａｔａｌｙｓｔ' Ｊ．　Ａｍ．　Ｃｈｅｍ．　Ｓｏｃ． Ｖｏｌ．１１７，　Ｎｏ．２３, 1995, ｐ．６１９４-６１９８

Katsumi Utaka

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