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Title:
DERIVATIVES OF POLYETHER AND OF PENTACYCLIC HETEROCYCLE, THEIR POLYMERS, AND THEIR APPLICATION, PARTICULARLY TO COMPLEXING OF METAL IONS
Document Type and Number:
Japanese Patent JPH07215932
Kind Code:
A
Abstract:

PURPOSE: To provide a novel monomer which is more easily accessible than an aromatic polyether and polymerizable at a low oxidation potential.

CONSTITUTION: A monomer having at least three ether units and pyrrole or thiophene units and characterized by that respective heterocyclic compds. are connected to the terminal part of a polyether chain through the C-atoms at the 3,3'-positions of these heterocycles or, especially, through N-atoms in the pyrrole groups and many 2,2'-positions of these heterocycles are substituted with easily removable groups (e.g. protective groups) free to all of substitutions is a compd. for example, represented by formula I (m; 3-5) and formula II (wherein X is NH or S; and q' and q'' are each 1 or 2). A polymer is formed on a support material based on carbon being in contact with the anode of an electrolytic cell electrically by the electrical precipitation from an electrolyte containing salts forming non-oxidative anions along with the monomer. The polymer is used in the separation or recovery of transition metal, zinc, cadmium or silver ions contained in a soln. in contact therewith.


Inventors:
REKURERUKU ORIBUIE
Application Number:
JP16562994A
Publication Date:
August 15, 1995
Filing Date:
July 18, 1994
Export Citation:
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Assignee:
ELECTRICITE DE FRANCE
International Classes:
B01J45/00; B01J47/08; C07D207/325; C07D207/333; C07D333/34; C07D333/38; C07D498/22; C08G61/12; C07D333/16; C08G65/32; C08G65/333; C08L71/02; C25B3/00; C07D207/32; C08L79/04; (IPC1-7): C07D207/325; C07D207/333; C07D333/16; C07D333/34; C07D333/38; C07D498/22; C08G65/32; C08L71/02; C25B3/00
Attorney, Agent or Firm:
Muneharu Sasaki (3 outside)