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Title:
フィッシャー-トロプシュ法テールガス中のオレフィンの縮合
Document Type and Number:
Japanese Patent JP4790987
Kind Code:
B2
Abstract:
Light olefins including LPG contained in unreacted tail gas from a Fischer-Tropsch process are catalytically condensed using an acidic oligomerization/aromatization catalyst to form higher molecular weight C5+ products. Thus, C3-C4 olefins are readily separated from the tail gas and upgraded to more valuable products. In one embodiment, the condensation is conducted on a mixed gas stream of fresh synthesis gas and tail gas from a Fischer-Tropsch process. In another embodiment, the condensation is conducted on a syngas feed to a Fischer-Tropsch reactor and removes a significant portion of catalytically poisonous nitrogen compounds.

Inventors:
Olea, Dennis, Jay.
Mira, Steven, Jay.
Application Number:
JP2003582105A
Publication Date:
October 12, 2011
Filing Date:
March 20, 2003
Export Citation:
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Assignee:
Chevron U.S.A. Inc.
International Classes:
C07C2/12; C07B61/00; C07C1/04; C07C5/41; C07C11/10; C07C11/107; C07C15/04; C07C15/073; C10G2/00; C10G35/095; C10G50/00
Domestic Patent References:
JPS61145127A1986-07-02
JPS63141644A1988-06-14
JPH02229890A1990-09-12
JPH03503064A1991-07-11
JP2004500474A2004-01-08
JP2004532322A2004-10-21
JP2005517080A2005-06-09
JP2005537340A2005-12-08
Foreign References:
US4504693A1985-03-12
Attorney, Agent or Firm:
Hideto Asamura
Hajime Asamura
Katsunori Ando
Yukihiro Ikeda