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Title:
NEW INTERMEDIATE USEFUL FOR SYNTHESIS OF 1-ARYLPYRROLE AGROCHEMICAL
Document Type and Number:
Japanese Patent JP3939374
Kind Code:
B2
Abstract:

PROBLEM TO BE SOLVED: To provide a new intermediate which is shown by a specific formula, can be easily produced, is inexpensive, and is useful as an intermediate for the production of a compound useful for the control of insects, acarids, and nematodes.
SOLUTION: This intermediate shown by formula I [W is cyano, CO2H, CO2R3, CONH2, or the like; R is a (halo)alkyl, cyano, C(NH2)(=NH), or the like; R1 and R2 are each H, a halogen, a (halo)alkyl, a (halo)alkoxy, or the like; R3 is a (halo)alkyl, a hydroxyalkyl, an alkoxyalkyl; (n) is 0, 1, or 2] (e.g. 2-chloro-3-cyano-4-thiocyanato-5-methylpyrrole) is obtained, preferably, by the reaction of a compound shown by formula II with an alkyl halide or a haloalkyl thiohalide and so on. It is preferable in its production to obtain the objective compound by the reaction of a compound shown by formula II with an activated bisulfur compound.


Inventors:
Alan Cien
Scott Kevin Hoover
Application Number:
JP26039995A
Publication Date:
July 04, 2007
Filing Date:
October 06, 1995
Export Citation:
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Assignee:
Rhone-Poulin Agrossimi
International Classes:
C07D207/34; C07D207/36; C07D207/42; (IPC1-7): C07D207/36; C07D207/42
Domestic Patent References:
JP50105832A
Foreign References:
US5187185
Other References:
HARRIS Roger L. N.,The oxidation of thioureas and related compounds in the presence of pyrroles. The synthesis of s-pyrrolylisothiouronium salts,Australian Journal of Chemistry,1970年,Vol.23, No.6,p.1199-1207
Attorney, Agent or Firm:
Yoshio Kawaguchi
Toru Nakamura
Takeshi Funayama