NEW MATERIAL:A bisphenol compound having a sulfonamide bond of formula I [Ar1 and Ar2 are groups of formula II or III (R1, R3 and R4 are H, 1W5C lower alkyl, halogen, etc.; a, c and d are integers 1W4; b is an integer 1W6; X i -CH2-, -O-, etc.; e is 1 or 0), etc.].
EXAMPLE: N,N'-Bis(p-hydroxyphenyl)diphenyl ether-4,4'-disulfonamide.
USE: A raw material for a polymer and a medicine, and obtainable in high purity and yield.
PROCESS: A compound of formula IV (Y is halogen) is reacted with a 1-hydroxybenzotriazole derivative of formula V (M is H, etc.; R6 is halogen, CN, etc.; n is 0 or an integer 1W4; R6 may be the same or different when n is ≥2), and the resultant product is then reacted with an aromatic aminohydroxy compound of formula VI to afford the compound of formula I.
JP2007204624 | AQUEOUS PHENOLIC RESIN COMPOSITION AND BINDER |
KURITA EISUKE
GUENCHIYOU
TSUBOI HIKOTADA