Title:
NOVEL OPTICALLY ACTIVE PROPANE DERIVATIVE
Document Type and Number:
Japanese Patent JPH02218624
Kind Code:
A
Abstract:
NEW MATERIAL: (s)-(+)-1-bromo-3-chloro-2-methylpropane.
USE: A compd. for synthesizing a side chain of (R,R,R)-α-tocopherol.
PREPARATION: (R)-(+)-β-chloro-isobutyric acid represented by formula II is reduced by hydrogen boride or its deriv. to form (2R)-(-)-3- chloro-2-methylpropanol represented by formula III and this compd. is brominated by PBr3 or triphenylphosphine and bromine in DMF or triphenylphosphine and CBr4 in methylene chloride to obtain the compd. represented by the formula I.
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Inventors:
HANSUGEORUKU ERUNSUTO
FURIIDORITSUHI FUOOGERU
YOAHIMU PAUSUTO
FURIIDORITSUHI FUOOGERU
YOAHIMU PAUSUTO
Application Number:
JP24088889A
Publication Date:
August 31, 1990
Filing Date:
September 19, 1989
Export Citation:
Assignee:
BASF AG
International Classes:
C07C17/16; B01J27/122; C07B61/00; C07C17/00; C07C17/26; C07C17/263; C07C19/01; C07C19/075; C07C29/147; C07C29/40; C07C51/363; C07C51/487; C07C53/19; C07C67/00; C07D311/72; (IPC1-7): C07C17/16; C07C19/02
Domestic Patent References:
JPS4832884A | 1973-05-02 |
Attorney, Agent or Firm:
Toshio Yano (3 outside)