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Title:
PROCESS FOR HYDRODEAROMATIZATION OF HYDROCARBON OIL USING NOVEL 'PHOSPHORUS TREATED CARBON' SUPPROTED METAL SULFIDE CATALYST
Document Type and Number:
Japanese Patent JPH08176559
Kind Code:
A
Abstract:

To provide a process for treating fuel hydrocarbon oils containing undesired aromatic components, sulfur and nitrogen compounds.

A process for treating a charge hydrocarbon oil comprises using a catalytic weight amount of a sulfided metal catalyst comprising 0.1-15 wt.% at least one metal selected from iron, cobalt and nickel; 1-50 wt.% tungsten; and 1-20 wt.% at least one metal selected from molybdenum and chromium on a 'phosphorus treated carbon' support formed by (1) the heat treatment of active carbon and a phosphorus compound at 450°C or higher (2) to bind phosphorus to the carbon surface as polyphosphoric acid having peaks between -5 and -30 ppm in the solid state magic angle spinning 31PNMR and having (3) a BET surface area of 100-2,000 m2/g, a nitrogen content of at least 0.3 ml/g of the total pore volume and an average pore diameter of 12-100 (1.2-10 nm).


Inventors:
CHIYATSUKA SUDOHATSUKAA
FURANKU DORUFUINGAA JIYUNIA
MATSUKUSU RAFUAERU SHIIZAA
MAHENDORA SOMABUHAI PATERU
POORU OTSUTOO FURITSUTSU
Application Number:
JP20204195A
Publication Date:
July 09, 1996
Filing Date:
August 08, 1995
Export Citation:
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Assignee:
TEXACO DEVELOPMENT CORP
International Classes:
B01J21/18; B01J23/85; B01J27/188; C10G45/08; C10G45/50; (IPC1-7): C10G45/08; B01J21/18; B01J23/85; C10G45/50
Attorney, Agent or Firm:
Hajime Tsukuni (1 person outside)