PRODUCTION OF ARYL C-GLYCOSYL COMPOUND AND REAGENT THEREFOR

Title:

PRODUCTION OF ARYL C-GLYCOSYL COMPOUND AND REAGENT THEREFOR

Document Type and Number:

Japanese Patent JPH09143190

Kind Code:

A

Abstract:

To obtain a reaction reagent giving an aryl C-glycosyl compound in high yield and excellent β-configuration selectivity by compounding a Lewis acid with a silver or mercury salt of trifluoromethanesulfonic acid or trifluoroacetic acid.

The objective aryl C-glycosylating reaction reagent gives an aryl C-glycosyl compound in high yield and excellent β-configuration selectivity by reacting with a sugar and an aryl compound. The reagent can be produced by compounding one or more kinds of Lewis acids (e.g. tin tetrachloride) with one or more kinds of a silver or mercury salt of trifluoromethanesulfonic acid or trifluoroacetic acid at a ratio (Lewis acid : silver or mercury salt of trifluoromethanesulfonic acid or trifluoroacetic acid) of 1:3 to 3:1. The reagent is preferably used in an amount of 1-3 equivalent based on 1 equivalent of the sugar and/or aryl compound.

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Inventors:

SATO SUSUMU
KURIBAYASHI TAKESHI
OKAWA NOBUYUKI

Application Number:

JP23604496A

Publication Date:

June 03, 1997

Filing Date:

September 06, 1996

Export Citation:

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Assignee:

SANKYO CO

International Classes:

C07H1/00; B01J31/02; B01J31/04; C07B61/00; C07H7/04; (IPC1-7): C07H1/00; B01J31/02; B01J31/04; C07H7/04

Attorney, Agent or Firm:

Akio Ohno (2 outside)

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