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Title:
PRODUCTION OF UNSATURATED ETHER AND CATALYST FOR PRODUCING UNSATURATED ETHER
Document Type and Number:
Japanese Patent JP2740479
Kind Code:
B2
Abstract:

PURPOSE: To simply and safely produce an unsaturated ether compound by a direct one step reaction from an inexpensive and easily available glycol ether compound in the presence of a specific catalyst without using an auxiliary raw material and a solvent.
CONSTITUTION: (B) A glycol ether compound is subjected to an intramolecular dehydration reaction in a gaseous phase in the presence of a catalyst especially preferably comprising an oxide of formula: MaSibXcOd (M is alkali metal element; X is at least one of Ti, Zr, V, Nb, Ta, Cr, Mo, W, B, Al, Ga, In, Tl, Ge, Sn, Pb, P and Sb; when a is 1, b is 1-500, c is 0-1, d is a number determining by the values of a-c and by the binding states of various constituting elements) to obtain (C) the converted unsaturated ether compound. For example, a vinylic ether compound of formula II is obtained from a glycol ether compound of formula I (R is 1-7C hydrocarbon, etc.; R' is independently H, methyl, etc.; n is 1, 2).


Inventors:
Ariyoshi Kimio
Yuji Shimazaki
Application Number:
JP23897495A
Publication Date:
April 15, 1998
Filing Date:
August 25, 1995
Export Citation:
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Assignee:
Nippon Shokubai Co., Ltd.
International Classes:
B01J23/04; B01J23/08; B01J23/18; B01J23/20; B01J23/24; B01J27/182; C07B61/00; C07C41/18; C07C43/15; C07C43/16; (IPC1-7): C07C43/15; B01J23/04; B01J23/08; B01J23/18; B01J23/20; B01J23/24; B01J27/182; C07C41/18; C07C43/16
Attorney, Agent or Firm:
Heiyoshi Odashima (1 person outside)