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Title:
PRODUCTION OF VINYL GROUP-CONTAINING ALICYCLIC ACRYLATE-BASED COMPOUND AND EPOXY GROUP-CONTAINING ALICYCLIC ACRYLATE-BASED COMPOUND
Document Type and Number:
Japanese Patent JPH11209326
Kind Code:
A
Abstract:

To provide a method for producing the subject vinyl-containing compound capable of providing the subject epoxy compound useful as an adhesive or the like, and having an alicyclic skeleton and a (meth)acryloyloxy by reacting a specific vinyl group-containing alicyclic epoxy compound by a specified method.

A vinyl group-containing alicyclic epoxy compound of formula I (R1, R2, R7 to R10, and R13 to R16 are each H, phenyl or a l-8C alkyl, with the proviso that any one of the R13 to R16 is vinyl or l methylvinyl) is reacted with an acrylic acid compound of the formula, CH2=CR11COOH (R11 is H, methyl or ethyl) in an molar ratio of the former to the latter regulated so as to be 1-1.6 to provide the objective compound of formula II [(n) is 1-10] in the method for producing the objective vinyl-containing compound. The compound of formula I is preferably vinylcyclohexene monoepoxide or the like. The reaction temperature is preferably 70-120°C. The epoxy group-containing alicyclic acrylate-based compound is obtained by epoxidizing the compound of formula II. An epoxidizing agent is preferably peracetic acid.


Inventors:
TAKAI HIDEYUKI
Application Number:
JP2048698A
Publication Date:
August 03, 1999
Filing Date:
January 16, 1998
Export Citation:
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Assignee:
DAICEL CHEM
International Classes:
C07D303/16; C07C67/26; C07C69/54; C08F20/32; C09D4/02; C09J4/02; (IPC1-7): C07C69/54; C07C67/26; C07D303/16; C08F20/32
Attorney, Agent or Firm:
Yoshikazu Miura